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United States Patent | 6,255,372 |
Lin ,   et al. | July 3, 2001 |
A tire having improved tear strength including at least one component comprising a vulcanized elastomer from about 5 to about 50 parts by weight polypropylene per one hundred parts by weight elastomer, and from about 0.05 to about 2.0 parts by weight of an anhydride compatibilizing agent per one hundred parts by weight elastomer.
Inventors: | Lin; Chen-Chy (Hudson, OH); Tatsuro; Hamada (Copley, OH) |
Assignee: | Bridgestone Corporation (Tokyo, JP) |
Appl. No.: | 227927 |
Filed: | January 8, 1999 |
Current U.S. Class: | 524/112; 525/193; 525/285 |
Intern'l Class: | C08K 005/04 |
Field of Search: | 524/112 525/193,285 |
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4883837 | Nov., 1989 | Zabrocki | 525/66. |
5238997 | Aug., 1993 | Bauer et al. | 525/179. |
5292590 | Mar., 1994 | Lin et al. | 428/494. |
5341863 | Aug., 1994 | Sandstrom et al. | 152/209. |
5597866 | Jan., 1997 | White et al. | 525/240. |
5621045 | Apr., 1997 | Patel et al. | 525/237. |
Foreign Patent Documents | |||
0 445 486 A2 | Sep., 1991 | EP. | |
0 867 471 A1 | Sep., 1998 | EP. | |
1092174 | Nov., 1967 | GB. |
"Improved Durability in OTR Mining Tires" by Walker et al., Katschuk--Gummi, Kunslatolle 38, Johrgang, Nr, Jun., 1985. "Improving Cutting, Chipping Resistance of Tire Treads" by Engelhardt et al., ITEC '96 Select, pp. 12-19, 1996. "The Anhydride content of Some Commercial PP-g-MA: FTIR and Titration" by Sclavons, Journal of Applied Polymer Science, vol. 62, pp. 1205-1210, 1996. "Blends of Elastomers and Thermoplastics--A Review" by J.R. Dunn, Rubber Chemical Technology, vol. 49, pp. 978-991, 1976. "Modification of Rubbers with Solid Polymers" by Zelenev et al., Sov. Rubber Tech. vol. 29, pp. 21-23, 1970. "Associations Eolastomeres-Plastomeres Etude de Quelques Properietes" by Blondel, Rev. Gen Caoutch Plast., vol. 44, No. 9, pp. 1011-1017, 1967. "Properties of Tread Vulcanizates Containing Polyethylene and Copolymers of Ethylene with Other Monomers" by Tyurina et al., Sov. Rubber Tech., vol. 30, pp. 15-16, 1971. "Features of the Change in the Properties of Rubber Mixes and Vulcanizates on the Addition of Plastics" by Tyurina et al., Sov. Rubber Tech. vol. 31, pp. 14-17, 1972. "Properties of Carcass Vulcanizates for Radial-Ply Tyres" by Priklonskaya et al., Sov. Rubber Tech., vol. 28, pp. 11-13, 1969. "OREVAC.RTM. Coextrusion Adhesives", Elf Atochem North America, Inc., Technical Brochure, Mar., 1997. "Modification of Polyolefins with Maleic Anhydride" by Andre H. Hogt, COMPALLOY '90, pp. 181-193, 1990. "The Maleic Anhydride Grafting of Polypropylene with Organic Peroxides" by Callais, COMPALLOY '90, pp. 359-369. EXXELOR, Exxelor PO 1015, Exxon Chemical, Technical Brochure, undated. |
CARBON BLACKS ASTM Surface Area Designation (m.sup.2 /g) (D-1765-82a) (D-3765) N-110 126 N-220 111 N-339 95 N-330 83 N-550 42 N-660 35
TABLE I Rubber Stock Recipe Parts by Ingredient Weight Natural Rubber 100 Carbon Black (SAF) 45 Zinc Oxide 3.5 Retardor 0.1 Antioxidant 2.3 Optional ingredients Isotactic polypropylene 0-20 Maleic Anhydride 0-0.6 Masterbatch 148.9- 169.5 Sulfur 1.3 Accelerator 1.25 Hardened Fatty Acid 2 Total 152.75- 174.05
TABLE II Stock 1 2 3 4 5 Additive Polypropylene pbw/phr -- 20 20 20 20 Maleic Anhydride pbw/phr -- -- 0.08 0.2 0.6 Properties Tensile Strength at Break @ 100.degree. C. (psi) 3035 1886 2469 2160 2377 Tensile Toughness @ 100.degree. C. 8366 4690 6987 5482 6738 Maximum Elongation @ 100.degree. C. (%) 691 462 553 484 555 50% Modulus @ 100.degree. C. (psi) 124 251 263 263 250 300% Modulus @ 100.degree. C. (psi) 844 1289 1367 1394 1310 Tear Strength @ 100.degree. C. (lb/in) 490 555 506 602 620 Travel at Tear (%) 589 419 400 448 513
TABLE III Stock 1 2 3 4 5 Properties Tensile Strength at Break @ 100.degree. C. 2396 2136 2057 1916 2325 (psi) Tensile Toughness @ 100.degree. C. 5539 4539 4633 3907 5753 Maximum Elongation @ 100.degree. C. (%) 541 394 416 377 465 50 % Modulus @ 100.degree. C. (psi) 139 309 286 278 274 300% Modulus @ 100.degree. C. (psi) 1062 1710 1554 1582 1601