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| United States Patent |
6,227,654
|
|
Silverbrook
|
May 8, 2001
|
Ink jet printing mechanism
Abstract
A fluid ejection apparatus is disclosed including a trough having side
walls and an exposed roof the trough being substantially filled with
fluid; a paddle vane located within the trough and offset from one wall
when the paddle vane is in a quiescent position; an actuation mechanism
attached to the paddle vane such that, upon activation of the actuation
mechanism, the paddle vane is caused to move towards the one wall,
resulting in an increase in pressure in the fluid between the one wall and
the paddle vane, resulting in a consequential ejection of fluid via the
exposed roof. Ideally, the present invention can be utilized in an ink jet
printing system. The actuation mechanism can be interconnected to the
paddle vane via an arm extending over one edge of the exposed roof and the
actuation mechanism can comprise a coiled thermal actuator having a first
conductive arm and a second substantially non-conductive arm, the
conductive arm expanding upon electrical resistive heating to thereby
cause the actuation of the thermal actuator. The first conductive arm can
comprise substantially titanium diboride and the second non-conductive arm
can comprise substantially silicon nitride. The actuation mechanism can
operate in the ambient atmosphere.
| Inventors:
|
Silverbrook; Kia (Balmain, AU)
|
| Assignee:
|
Silverbrook Research Pty Ltd (Balmain, AU)
|
| Appl. No.:
|
112812 |
| Filed:
|
July 10, 1998 |
Foreign Application Priority Data
| Jul 15, 1997[AU] | PO7991 |
| Dec 12, 1997[AU] | PP0890 |
| Current U.S. Class: |
347/54; 347/20; 347/44 |
| Intern'l Class: |
B41J 002/015; B41J 002/135; B41J 002/04 |
| Field of Search: |
347/44,54,20
|
References Cited
U.S. Patent Documents
| 5903380 | May., 1999 | Motamedi et al. | 359/224.
|
| Foreign Patent Documents |
| 404001051 | Jan., 1992 | JP | 347/54.
|
Primary Examiner: Barlow; John
Assistant Examiner: Do; An H.
Parent Case Text
CROSS REFERENCES TO RELATED APPLICATIONS
The following Australian provisional patent applications are hereby
incorporated cross-reference. For the purposes of location and
identification, U.S. patent applications identified by their U.S. patent
application serial numbers (USSN) are listed alongside the Australian
applications from which the U.S. patent applications claim the right of
priority.
U.S. PAT./PATENT APPLI-
CATION (CLAIMING RIGHT
CROSS-REFERENCED OF PRIORITY FROM
AUSTRALIAN AUSTRALIAN
PROVISIONAL PATENT PROVISIONAL DOCKET
APPLICATION NO. APPLICATION) NO.
PO7991 09/113,060 ART01
PO8505 09/113,070 ART02
PO7988 09/113,073 ART03
PO9395 09/112,748 ART04
PO8017 09/112,747 ART06
PO8014 09/112,776 ART07
PO8025 09/112,750 ART08
PO8032 09/112,746 ART09
PO7999 09/112,743 ART10
PO7998 09/112,742 ART11
PO8031 09/112,741 ART12
PO8030 09/112,740 ART13
PO7997 09/112,739 ART15
PO7979 09/113,053 ART16
PO8015 09/112,738 ART17
PO7978 09/113,067 ART18
PO7982 09/113,063 ART19
PO7989 09/113,069 ART20
PO8019 09/112,744 ART21
PO7980 09/113,058 ART22
PO8018 09/112,777 ART24
PO7938 09/113,224 ART25
PO8016 09/112,804 ART26
PO8024 09/112,805 ART27
PO7940 09/113,072 ART28
PO7939 09/112,785 ART29
PO8501 09/112,797 ART30
PO8500 09/112,796 ART31
PO7987 09/113,071 ART32
PO8022 09/112,824 ART33
PO8497 09/113,090 ART34
PO8020 09/112,823 ART38
PO8023 09/113,222 ART39
PO8504 09/112,786 ART42
PO8000 09/113,051 ART43
PO7977 09/112,782 ART44
PO7934 09/113,056 ART45
PO7990 09/113,059 ART46
PO8499 09/113,091 ART47
PO8502 09/112,753 ART48
PO7981 09/113,055 ART50
PO7986 09/113,057 ART51
PO7983 09/113,054 ART52
PO8026 09/112,752 ART53
PO8027 09/112,759 ART54
PO8028 09/112,757 ART56
PO9394 09/112,758 ART57
PO9396 09/113,107 ART58
PO9397 09/112,829 ART59
PO9398 09/112,792 ART60
PO9399 6,106,147 ART61
PO9400 09/112,790 ART62
PO9401 09/112,789 ART63
PO9402 09/112,788 ART64
PO9403 09/112,795 ART65
PO9405 09/112,749 ART66
PP0959 09/112,784 ART68
PP1397 09/112,783 ART69
PP2370 09/112,781 DOT01
PP2371 09/113,052 DOT02
PO8003 09/112,834 Fluid01
PO8005 09/113,103 Fluid02
PO9404 09/113,101 Fluid03
PO8066 09/112,751 IJ01
PO8072 09/112,787 IJ02
PO8040 09/112,802 IJ03
PO8071 09/112,803 IJ04
PO8047 09/113,097 IJ05
PO8035 09/113,099 IJ06
PO8044 09/113,084 IJ07
PO8063 09/113,066 IJ08
PO8057 09/112,778 IJ09
PO8056 09/112,779 IJ10
PO8069 09/113,077 IJ11
PO8049 09/113,061 IJ12
PO8036 09/112,818 IJ13
PO8048 09/112,816 IJ14
PO8070 09/112,772 IJ15
PO8067 09/112,819 IJ16
PO8001 09/112,815 IJ17
PO8038 09/113,096 IJ18
PO8033 09/113,068 IJ19
PO8002 09/113,095 IJ20
PO8068 09/112,808 IJ21
PO8062 09/112,809 IJ22
PO8034 09/112,780 IJ23
PO8039 09/113,083 IJ24
PO8041 09/113,121 IJ25
PO8004 09/113,122 IJ26
PO8037 09/112,793 IJ27
PO8043 09/112,794 IJ28
PO8042 09/113,128 IJ29
PO8064 09/113,127 IJ30
PO9389 09/112,756 IJ31
PO9391 09/112,755 IJ32
PP0888 09/112,754 IJ33
PP0891 09/112,811 IJ34
PP0890 09/112,812 IJ35
PP0873 09/112,813 IJ36
PP0993 09/112,814 IJ37
PP0890 09/112,764 IJ38
PP1398 09/112,765 IJ39
PP2592 09/112,767 IJ40
PP2593 09/112,768 IJ41
PP3991 09/112,807 IJ42
PP3987 09/112,806 IJ43
PP3985 09/112,820 IJ44
PP3983 09/112,821 1J45
PO7935 09/112,822 IJM01
PO7936 09/112,825 IJM02
PO7937 09/112,826 IJM03
PO8061 09/112,827 IJM04
PO8054 09/112,828 IJM05
PO8065 6,071,750 IJM06
PO8055 09/113,108 IJM07
PO8053 09/113,109 IJM08
PO8078 09/113,123 IJM09
PO7933 09/113,114 IJM10
PO7950 09/113,115 IJM11
PO7949 09/113,129 IJM12
PO8060 09/113,124 IJM13
PO8059 09/113,125 IJM14
PO8073 09/113,126 IJM15
PO8076 09/113,119 IJM16
PO8075 09/113,120 IJM17
PO8079 09/113,221 IJM18
PO8050 09/113,116 IJM19
PO8052 09/113,118 IJM20
PO7948 09/113,117 IJM21
PO7951 09/113,113 IJM22
PO8074 09/113,130 IJM23
PO7941 09/113,110 IJM24
PO8077 09/113,112 IJM25
PO8058 09/113,087 IJM26
PO8051 09/113,074 IJM27
PO8045 6,111,754 IJM28
PO7952 09/113,088 IJM29
PO8046 09/112,771 IJM30
PO9390 09/112,769 IJM31
PO9392 09/112,770 IJM32
PP0889 09/112,798 IJM35
PP0887 09/112,801 IJM36
PP0882 09/112,800 IJM37
PP0874 09/112,799 IJM38
PP1396 09/113,098 IJM39
PP3989 09/112,833 IJM40
PP2591 09/112,832 IJM41
PP3990 09/112,831 IJM42
PP3986 09/112,830 IJM43
PP3984 09/112,836 IJM44
PP3982 09/112,835 IJM45
PP0895 09/113,102 IR01
PP0870 09/113,106 IR02
PP0869 09/113,105 IR04
PP0887 09/113,104 IR05
PP0885 09/112,810 IR06
PP0884 09/112,766 IR10
PP0886 09/113,085 IR12
PP0871 09/113,086 IR13
PP0876 09/113,094 IR14
PP0877 09/112,760 IR16
PP0878 09/112,773 IR17
PP0879 09/112,774 IR18
PP0883 09/112,775 IR19
PP0880 09/112,745 IR20
PP0881 09/113,092 IR21
PO8006 6,087,638 MEMS02
PO8007 09/113,093 MEMS03
PO8008 09/113,062 MEMS04
PO8010 6,041,600 MEMS05
PO8011 09/113,082 MEMS06
PO7947 6,067,797 MEMS07
PO7944 09/113,080 MEMS09
PO7946 6,044,646 MEMS10
PO9393 09/113,065 MEMS11
PP0875 09/113,078 MEMS12
PP0894 09/113,075 MEMS13
Claims
What is claimed is:
1. An ink ejection arrangement which comprises
a wafer substrate which defines an ink supply channel and which
incorporates drive circuitry;
side walls which are arranged on the wafer substrate and which define an
ink chamber, the ink supply channel being in fluid communication with the
ink chamber;
a paddle which is located in the ink chamber and which is displaceable
between the side walls to eject ink from the ink chamber; and
an actuator which is connected to the paddle and to the drive circuitry and
which is configured so that, upon activation of the actuator by the drive
circuitry, the paddle is displaced towards one of the side walls, the ink
chamber and the paddle being configured so that, when the paddle is so
displaced towards one of the side walls, ink is ejected from the ink
chamber.
2. An ink jet arrangement as claimed in claim 1, wherein the side walls
defining the ink chamber are defined by an etching and deposition process
carried out on the wafer substrate.
3. An ink jet arrangement as claimed in claim 1, wherein the paddle is
shaped to have edges which correspond generally with a transverse profile
of the ink chamber.
4. An ink jet arrangement as claimed in claim 1, wherein the actuator has a
resiliently flexible coiled structure, one end of the coiled structure
being connected to the paddle and an opposed end of the coiled structure
being connected to the drive circuitry, the actuator being configured so
that, upon activation by the drive circuitry, the coiled structure
partially uncoils to an extent necessary to displace the paddle towards
said one of the walls, resulting in said ejection of ink.
5. An ink jet arrangement as claimed in claim 4, wherein the coiled
structure includes an electrical conductor which is connected to the drive
circuitry and which is configured to expand upon conductive heating,
thereby partially uncoiling to said necessary extent.
6. An ink jet arrangement as claimed in claim 5, wherein the coiled
structure includes a coiled member on which the electrical conductor is
positioned, the electrical conductor being positioned to act on the coiled
member partially to uncoil the coiled member, so that the paddle is
displaced to said necessary extent.
7. An ink jet arrangement as claimed in claim 6, wherein the electrical
conductor comprises substantially titanium diboride and the coiled member
comprises substantially silicon nitride.
8. An ink jet arrangement as claimed in claim 6, wherein the coiled member
and the electrical conductor are defined by an etching and deposition
process carried out on the wafer substrate.
9. An ink jet printhead which comprises a plurality of ink jet arrangements
as claimed in claim 1.
Description
STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH OR DEVELOPMENT
Not applicable.
FIELD OF THE INVENTION
The present invention relates to the field of ink jet printing and in
particular, discloses an ink jet printing mechanism.
BACKGROUND OF THE INVENTION
Many different types of printing have been invented, a large number of
which are presently in use. The known forms of print have a variety of
methods for marking the print media with a relevant marking media.
Commonly used forms of printing include offset printing, laser printing
and copying devices, dot matrix type impact printers, thermal paper
printers, film recorders, thermal wax printers, dye sublimation printers
and ink jet printers both of the drop-on-demand and continuous flow type.
Each type of printer has its own advantages and problems when considering
cost, speed, quality, reliability, simplicity of construction and
operation etc.
In recent years, the field of ink jet printing, wherein each individual
pixel of ink is derived from one or more ink nozzles has become
increasingly popular primarily due to its inexpensive and versatile
nature.
Many different techniques of ink jet printing have been invented. For a
survey of the field, reference is made to an article by J Moore,
"Non-Impact Printing: Introduction and Historical Perspective", Output
Hard Copy Devices, Editors R Dubeck and S Sherr, pages 207-220 (1988).
Ink Jet printers themselves come in many different forms. The utilization
of a continuous stream of ink in ink jet printing appears to date back to
at least 1929 wherein U.S. Pat. No. 1,941,001 by Hansell discloses a
simple form of continuous stream electro-static ink jet printing.
U.S. Pat. No. 3,596,275 by Sweet also discloses a continuous ink jet
printing process including a step wherein the ink jet stream is modulated
by a high frequency electro-static field so as to cause drop separation.
This technique is still utilized by several manufacturers including Elmjet
and Scitex (see also U.S. Pat. No. 3,373,437 by Sweet et al).
Piezoelectric ink jet printers are also one form of commonly utilized ink
jet printing device. Piezoelectric systems are disclosed by Kyser et. al.
in U.S. Pat. No. 3,946,398 (1970) which utilizes a diaphragm mode of
operation, by Zolten in U.S. Pat. No. 3,683,212 (1970) which discloses a
squeeze mode of operation of a piezoelectric crystal, Stemme in U.S. Pat.
No. 3,747,120 (1972) discloses a bend mode of piezoelectric operation,
Howkins in U.S. Pat. No. 4,459,601 discloses a piezoelectric push mode
actuation of the ink jet stream and Fischbeck in U.S. Pat. No. 4,584,590
which discloses a shear mode type of piezoelectric transducer element.
Recently, thermal ink jet printing has become an extremely popular form of
ink jet printing. The ink jet printing techniques include those disclosed
by Endo et al in GB 2007162 (1979) and Vaught et al in U.S. Pat. No.
4,490,728. Both the aforementioned references disclose ink jet printing
techniques which rely upon the activation of an electrothermal actuator
which results in the creation of a bubble in a constricted space, such as
a nozzle, resulting in the ejection of ink from an aperture connected to
the confined space onto a relevant print media. Printing devices utilizing
the electro-thermal actuator are manufactured by manufacturers such as
Canon and Hewlett Packard.
As can be seen from the foregoing, many different types of printing
technologies are available. Ideally, a printing technology should have a
number of desirable attributes. These include inexpensive construction and
operation, high speed operation, safe and continuous long term operation
etc. Each technology may have its own advantages and disadvantages in the
areas of cost, speed, quality, reliability, power usage, simplicity of
construction, operation, durability and consumables.
SUMMARY OF THE INVENTION
It is an object of the present invention to provide an ink ejection
arrangement which does not require a nozzle.
In accordance with a first aspect of the present invention, there is
provided an ink ejection arrangement which includes a wafer substrate.
Side walls are arranged on the wafer substrate. The side walls define an
ink chamber. A paddle is positioned in the ink chamber and is displaceable
towards one of the side walls. An actuator is attached to the paddle such
that, upon activation of the actuator, the paddle is displaced towards the
one wall, resulting in an increase in pressure on the ink between the one
wall and the paddle and an ejection of ink from the chamber.
Ideally, the present invention can be utilized in an ink jet printing
system.
The actuator may be interconnected to the paddle via an arm extending over
one edge of the ink chamber. The actuator may comprise a coiled thermal
actuator having a first conductive arm and a second substantially
non-conductive arm, the conductive arm expanding upon electrical resistive
heating to thereby cause the activation of the thermal actuator. The first
conductive arm can comprise substantially titanium diboride and the second
non-conductive arm can comprise substantially silicon nitride. The
actuator can operate in ambient atmosphere.
Preferably, the ink chamber is formed within a silicon wafer and the
arrangement further comprises an ink supply channel etched through the
wafer and in fluid communication with the ink chamber for the supply of
ink to the ink chamber.
BRIEF DESCRIPTION OF THE DRAWINGS
Notwithstanding any other forms which may fall within the scope of the
present invention, preferred forms of the invention will now be described,
by way of example only, with reference to the accompanying drawings in
which:
FIG. 1 is a descriptive view of an ink ejection arrangement when in a
quiescent state;
FIG. 2 is a descriptive view of an ejection arrangement when in an
activated state;
FIG. 3 is an exploded perspective view of the different components of an
ink ejection arrangement;
FIG. 4 illustrates a cross section through the line IV--IV of FIG. 1;
FIGS. 5 to 24 illustrate the various manufacturing steps in the
construction of the preferred embodiment;
FIG. 25 illustrates a portion of an array of ink ejection arrangements as
constructed in accordance with the preferred embodiment.
FIG. 26 provides a legend of the materials indicated in FIGS. 27 to 38; and
FIGS. 27 to 38 illustrate sectional views of manufacturing steps of one
form of construction of the ink ejection arrangement.
DESCRIPTION OF PREFERRED AND OTHER EMBODIMENTS
In the preferred embodiment, there is provided an inkjet printing
arrangement arranged on a silicon wafer. The ink is supplied to a first
surface of the silicon wafer by means of channels etched through the back
of the wafer to an ink ejection chamber located along the surface of the
wafer. The ink ejection chamber is filled with ink and includes a paddle
attached to an external actuator which is activated so as to compress a
portion of the ink within the chamber against a sidewall resulting in the
corresponding ejection of ink from the chamber.
FIG. 1 illustrates an ink ejection arrangement 1 of the invention in the
quiescent position with FIG. 2 illustrating the view arrangement 1 after
activation of a thermal actuator 7 and FIG. 3 illustrates an exploded
perspective view of the ink ejection arrangement 1.
Ink is supplied to an ink ejection chamber 2 from an ink supply channel 3
which is etched through the wafer 4. A paddle 6 is located in the ink
ejection chamber 2 and attached to a thermal actuator 7. When the actuator
7 is activated, the paddle 6 is moved as illustrated in FIG. 2 thereby
displacing ink within the ink ejection chamber 2 resulting in the ejection
of the ink from the chamber 2. The actuator 7 comprises a coiled arm which
is in turn made up of three sub-arm components.
Turning to FIG. 4, there is illustrated a section through the line IV--IV
of FIG. 1 illustrating the structure of the arm which includes an upper
conductive arm 10 and a lower conductive arm 11. The two arms can be made
from conductive titanium diboride which has a high Young's modulus in
addition to a suitably high coefficient of thermal expansion. The two arms
10, 11 are encased in a silicon nitride portion 12 of the arm. The two
arms 10, 11 are conductively interconnected at one end 13 (FIG. 1) of the
actuator 7 and, at the other end, they are electrically interconnected at
14, 15, respectively, to control circuitry to a lower CMOS layer 17 which
includes the drive circuitry for activating the actuator 7.
The conductive heating of the arms 10, 11 results in a general expansion of
these two arms 10, 11. The expansion works against the nitride portion 12
of the arm resulting in a partial "uncoiling" of the actuator 7 which in
turn results in a corresponding movement of the paddle 6 resulting in the
ejection of ink from the nozzle chamber 2. The nozzle chamber 2 can
include a rim 18 which, for convenience, can also be constructed from
titanium diboride. The rim 18 has an arcuate profile shown at 19 which is
shaped to guide the paddle 6 on an arcuate path. Walls defining the ink
ejection chamber 2 are similarly profiled. Upon the ejection of a drop,
the paddle 6 returns to its quiescent position.
In FIGS. 5-24, there is shown manufacturing processing steps involved in
the fabrication of the preferred embodiment.
1. Starting initially with FIG. 5, a starting point for manufacture is a
silicon wafer having a CMOS layer 17 which can comprise the normal CMOS
processes including multi-level metal layers etc. and which provide the
electrical circuitry for the operation of the preferred embodiment which
can be formed as part of a multiple series or array of nozzles at a single
time on a single wafer.
2. The next step in the construction of the preferred embodiment is to form
an etched pit 21 as illustrated in FIG. 6. The etched pit 21 can be formed
utilizing a highly anisotropic trench etcher such as that available from
Silicon Technology Systems of the United Kingdom. The pit 21 is preferably
etched to have steep sidewalls. A dry etch system capable of high aspect
ratio deep silicon trench etching is that known as the Advance Silicon
Etch System available from Surface Technology Systems of the United
Kingdom.
3. Next, as illustrated in FIG. 7, a 1 .mu.m layer of aluminium 22 is
deposited over the surface of the wafer.
4. Next, as illustrated in FIG. 8 a five micron glass layer 23 is deposited
on top of the aluminium layer 22.
5. Next, the glass layer 23 is chemically and/or mechanically planarized to
provide a 1 .mu.m thick layer of glass over the aluminium layer 22 as
illustrated in FIG. 9.
6. A triple masked etch process is then utilized to etch the deposited
layer as illustrated in FIG. 10. The etch includes a 1.5 .mu.m etch of the
glass layer 23. The etch defines the via 25, a trench for rim portions 26,
27 and a paddle portion 28.
7. Next, as illustrated in FIG. 11, a 0.9 .mu.m layer 60 of titanium
diboride is deposited.
8. The titanium diboride layer 60 is subsequently masked and etched to
leave those portions as illustrated in FIG. 12.
9. A 1 .mu.m layer of silicon dioxide (SiO.sub.2) is then deposited and
chemically and/or mechanically planarized as illustrated in FIG. 13 to a
level of the titanium diboride.
10. As illustrated in FIG. 14 the silicon dioxide layer 61 is then etched
to form a spiral pattern where a nitride layer will later be deposited.
The spiral pattern includes etched portions 30-32.
11. Next, as illustrated in FIG. 15, a 0.2 .mu.m layer 62 of the silicon
nitride is deposited.
12. The silicon nitride layer 62 is then etched in areas 34-36 to provide
for electrical interconnection in areas 34, 35, in addition to a
mechanical interconnection, as will become more apparent hereinafter, in
the area 36 as shown in FIG. 16.
13. As shown in FIG. 17, a 0.9 .mu.m layer 63 of titanium diboride is then
deposited.
14. The titanium diboride is then etched to leave the via structure 14 the
spiral structure 10 and the paddle arm 6, as shown in FIG. 18.
15. A 1 .mu.m layer 64 of silicon nitride is then deposited as illustrated
in FIG. 19.
16. The nitride layer 64 is then chemically and mechanically planarized to
the level of the titanium diboride layer 63 as shown in FIG. 20.
17. The silicon nitride layer 64 is then etched so as to form the silicon
nitride portions of a spiral arm 42, 43 with a thin portion of silicon
nitride also remaining under the paddle arm as shown in FIG. 21.
18. As shown in FIG. 22 an ink supply channel 45 can be etched from a back
of the wafer 4. Again, an STS deep silicon trench etcher can be utilized.
19. The next step is a wet etch of all exposed glass (SiO.sub.2) surfaces
of the wafer 4 which results in a substantial release of the paddle
structure as illustrated in FIG. 23.
20. Finally, as illustrated in FIG. 24, the exposed aluminium surfaces are
then wet etched away resulting in a release of the paddle structure which
springs back to its quiescent or return position ready for operation.
The wafer can then be separated into printhead units and interconnected to
an ink supply along the back surface of the wafer for the supply of ink to
the nozzle arrangement.
In FIG. 25, there is illustrated a portion 49 of an array of nozzles which
can include a three colour output including a first colour series 50,
second colour series 51 and third colour series 52. Each colour series is
further divided into two rows 54 of ink ejection units with each unit
providing for the ejection ink drops corresponding to a single pixel of a
line. Hence, a page width array of nozzles can be formed including
appropriate bond pads 55 for providing electrical interconnection. The
page width printhead can be formed with a silicon wafer with multiple
printheads being formed simultaneously using the aforementioned steps.
Subsequently, the printheads can be separated and joined to an ink supply
mechanism for supplying ink via the back of the wafer to each ink ejection
arrangement, the supply being suitably arranged for providing separate
colours.
The presently disclosed ink jet printing technology is potentially suited
to a wide range of printing system including: colour and monochrome office
printers, short run digital printers, high speed digital printers, offset
press supplemental printers, low cost scanning printers high speed
pagewidth printers, notebook computers with inbuilt pagewidth printers,
portable colour and monochrome printers, colour and monochrome copiers,
colour and monochrome facsimile machines, combined printer, facsimile and
copying machines, label printers, large format plotters, photograph
copiers, printers for digital photographic "minilabs", video printers,
PHOTO CD (PHOTO CD is a registered trade mark of the Eastman Kodak
Company) printers, portable printers for PDAs, wallpaper printers, indoor
sign printers, billboard printers, fabric printers, camera printers and
fault tolerant commercial printer arrays.
One form of detailed manufacturing process which can be used to fabricate
monolithic ink jet printheads operating in accordance with the principles
taught by the present embodiment can proceed utilizing the following
steps:
1. Using a double-sided polished wafer 4, complete drive transistors, data
distribution, and timing circuits using a 0.5 micron, one poly, 2 metal
CMOS process layer 17. Relevant features of the wafer 4 at this step are
shown in FIG. 27. For clarity, these diagrams may not be to scale, and may
not represent a cross section though any single plane of the nozzle. FIG.
26 is a key to representations of various materials in these manufacturing
diagrams, and those of other cross referenced ink jet configurations.
2. Etch oxide down to silicon or aluminum using Mask 1. This mask defines
the ink inlet, the heater contact vias, and the edges of the printhead
chips. This step is shown in FIG. 28.
3. Etch silicon to a depth of 10 microns using the etched oxide as a mask.
This step is shown in FIG. 29.
4. Deposit 1 micron of sacrificial material 22 (e.g. aluminum). This step
is shown in FIG. 30.
5. Deposit 10 microns of a second sacrificial material 70 (e.g. polyimide).
This fills the etched silicon hole.
6. Planarize using CMP to the level of the first sacrificial material 22.
This step is shown in FIG. 31.
7. Etch the first sacrificial layer 22 using Mask 2, defining the nozzle
chamber wall and the actuator anchor point 25. This step is shown in FIG.
32.
8. Deposit 1 micron of glass 71.
9. Etch the glass 71 and second sacrificial layer 70 using Mask 3. This
mask defines the lower layer of the actuator loop, the nozzle chamber
wall, and the lower section of the paddle.
10. Deposit 1 micron of heater material 72, for example titanium nitride
(TiN) or titanium diboride (TiB2). Planarize using CMP. Steps 8 to 10 form
a `damascene` process. This step is shown in FIG. 33.
11. Deposit 0.1 micron of silicon nitride 73.
12. Deposit 1 micron of glass 74.
13. Etch the glass 74 using Mask 4, which defines the upper layer of the
actuator loop, the arm to the paddle, and the upper section of the paddle.
14. Etch the silicon nitride 73 using Mask 5, which defines the vias
connecting the upper layer of the actuator loop to the lower layer of the
actuator loop, as well as the arm to the paddle, and the upper section of
the paddle.
15. Deposit 1 micron of the same heater material 75 as in step 10.
Planarize using CMP. Steps 11 to 15 form a `dual damascene` process. This
step is shown in FIG. 34.
16. Etch the glass and nitride down to the sacrificial layer 22 using Mask
6, which defines the actuator. This step is shown in FIG. 35.
17. Wafer probe. All electrical connections are complete at this point,
bond pads are accessible, and the chips are not yet separated.
18. Back-etch completely through the silicon wafer (with, for example, an
ASE Advanced Silicon Etcher from Surface Technology Systems) using Mask 7.
This mask defines the ink inlets 3 which are etched through the wafer 4.
The wafer 4 is also diced by this etch. This step is shown in FIG. 36.
19. Etch both sacrificial materials 22, 70. The nozzle chambers are
cleared, the actuators freed, and the chips are separated by this etch.
This step is shown in FIG. 37.
20. Mount the chips in their packaging, which may be a molded plastic
former incorporating ink channels which supply the appropriate color ink
to the ink inlets 3 at the back of the wafer.
21. Connect the chips to their interconnect systems. For a low profile
connection with minimum disruption of airflow, TAB may be used. Wire
bonding may also be used if the printer is to be operated with sufficient
clearance to the paper.
22. Fill the printhead with water. Hydrophobize the exposed portions of the
printhead by exposing the printhead to a vapor of a perfluorinated alkyl
trichlorosilane. Drain the water and dry the printhead.
23. Fill the completed printhead with ink 76 and test it. A filled nozzle
is shown in FIG. 38. It would be appreciated by a person skilled in the
art that numerous variations and/or modifications may be made to the
present invention as shown in the specific embodiments without departing
from the spirit or scope of the invention as broadly described. The
present embodiments are, therefore, to be considered in all respects to be
illustrative and not restrictive.
Ink Jet Technologies
The embodiments of the invention use an ink jet printer type device. Of
course many different devices could be used. However presently popular ink
jet printing technologies are unlikely to be suitable.
The most significant problem with thermal ink jet is power consumption.
This is approximately 100 times that required for high speed, and stems
from the energy-inefficient means of drop ejection. This involves the
rapid boiling of water to produce a vapor bubble which expels the ink.
Water has a very high heat capacity, and must be superheated in thermal
ink jet applications. This leads to an efficiency of around 0.02%, from
electricity input to drop momentum (and increased surface area) out.
The most significant problem with piezoelectric ink jet is size and cost.
Piezoelectric crystals have a very small deflection at reasonable drive
voltages, and therefore require a large area for each nozzle. Also, each
piezoelectric actuator must be connected to its drive circuit on a
separate substrate. This is not a significant problem at the current limit
of around 300 nozzles per print head, but is a major impediment to the
fabrication of pagewidth printheads with 19,200 nozzles.
Ideally, the ink jet technologies used meet the stringent requirements of
in-camera digital color printing and other high quality, high speed, low
cost printing applications. To meet the requirements of digital
photography, new ink jet technologies have been created. The target
features include:
low power (less than 10 Watts)
high resolution capability (1,600 dpi or more)
photographic quality output
low manufacturing cost
small size (pagewidth times minimum cross section)
high speed (>2 seconds per page).
All of these features can be met or exceeded by the ink jet systems
described below with differing levels of difficulty. Forty-five different
ink jet technologies have been developed by the Assignee to give a wide
range of choices for high volume manufacture. These technologies form part
of separate applications assigned to the present Assignee as set out in
the table under the heading Cross References to Related Applications.
The ink jet designs shown here are suitable for a wide range of digital
printing systems, from battery powered one-time use digital cameras,
through to desktop and network printers, and through to commercial
printing systems.
For ease of manufacture using standard process equipment, the printhead is
designed to be a monolithic 0.5 micron CMOS chip with MEMS post
processing. For color photographic applications, the printhead is 100 mm
long, with a width which depends upon the ink jet type. The smallest
printhead designed is IJ38, which is 0.35 mm wide, giving a chip area of
35 square mm. The printheads each contain 19,200 nozzles plus data and
control circuitry.
Ink is supplied to the back of the printhead by injection molded plastic
ink channels. The molding requires 50 micron features, which can be
created using a lithographically micromachined insert in a standard
injection molding tool. Ink flows through holes etched through the wafer
to the nozzle chambers fabricated on the front surface of the wafer. The
printhead is connected to the camera circuitry by tape automated bonding.
Tables of Drop-on-Demand Ink Jets
Eleven important characteristics of the fundamental operation of individual
ink jet nozzles have been identified. These characteristics are largely
orthogonal, and so can be elucidated as an eleven dimensional matrix. Most
of the eleven axes of this matrix include entries developed by the present
assignee.
The following tables form the axes of an eleven dimensional table of ink
jet types.
Actuator mechanism (18 types)
Basic operation mode (7 types)
Auxiliary mechanism (8 types)
Actuator amplification or modification method (17 types)
Actuator motion (19 types)
Nozzle refill method (4 types)
Method of restricting back-flow through inlet (10 types)
Nozzle clearing method (9 types)
Nozzle plate construction (9 types)
Drop ejection direction (5 types)
Ink type (7 types)
The complete eleven dimensional table represented by these axes contains
36.9 billion possible configurations of ink jet nozzle. While not all of
the possible combinations result in a viable ink jet technology, many
million configurations are viable. It is clearly impractical to elucidate
all of the possible configurations. Instead, certain ink jet types have
been investigated in detail. These are designated IJ01 to IJ45 above which
matches the docket numbers in the tables under the heading Cross
References to Related Applications.
Other ink jet configurations can readily be derived from these forty-five
examples by substituting alternative configurations along one or more of
the 11 axes. Most of the IJ01 to IJ45 examples can be made into ink jet
printheads with characteristics superior to any currently available ink
jet technology.
Where there are prior art examples known to the inventor, one or more of
these examples are listed in the examples column of the tables below. The
IJ01 to IJ45 series are also listed in the examples column. In some cases,
print technology may be listed more than once in a table, where it shares
characteristics with more than one entry.
Suitable applications for the ink jet technologies include: Home printers,
Office network printers, Short run digital printers, Commercial print
systems, Fabric printers, Pocket printers, Internet WWW printers, Video
printers, Medical imaging, Wide format printers, Notebook PC printers, Fax
machines, Industrial printing systems, Photocopiers, Photographic minilabs
etc.
The information associated with the aforementioned 11 dimensional matrix
are set out in the following tables.
ACTUATOR MECHANISM (APPLIED ONLY TO SELECTED INK DROPS)
Description Advantages Disadvantages
Examples
Thermal An electrothermal .diamond-solid. Large force
.diamond-solid. High power .diamond-solid. Canon Bubblejet
bubble heater heats the ink to generated .diamond-solid.
Ink carrier 1979 Endo et al GB
above boiling point, .diamond-solid. Simple limited to
water patent 2,007,162
transferring significant construction .diamond-solid.
Low efficiency .diamond-solid. Xerox heater-in-
heat to the aqueous .diamond-solid. No moving parts
.diamond-solid. High pit 1990 Hawkins et al
ink. A bubble .diamond-solid. Fast operation
temperatures U.S. Pat. No. 4,899,181
nucleates and quickly .diamond-solid. Small chip area required
.diamond-solid. Hewlett-Packard
forms, expelling the required for actuator .diamond-solid. High
mechanical TIJ 1982 Vaught et al
ink. stress
U.S. Pat. No. 4,490,728
The efficiency of the .diamond-solid.
Unusual
process is low, with materials required
typically less than .diamond-solid. Large
drive
0.05% of the electrical transistors
energy being .diamond-solid.
Cavitation causes
transformed into actuator failure
kinetic energy of the .diamond-solid.
Kogation reduces
drop. bubble formation
.diamond-solid. Large
print heads
are difficult to
fabricate
Piezo- A piezoelectric crystal .diamond-solid. Low power
.diamond-solid. Very large area .diamond-solid. Kyser et al
electric such as lead consumption required for actuator
U.S. Pat. No. 3,946,398
lanthanum zirconate .diamond-solid. Many ink types
.diamond-solid. Difficult to .diamond-solid. Zoltan
(PZT) is electrically can be used integrate with
U.S. Pat. No. 3,683,212
activated, and either .diamond-solid. Fast operation
electronics .diamond-solid. 1973 Stemme
expands, shears, or .diamond-solid. High efficiency
.diamond-solid. High voltage U.S. Pat. No. 3,747,120
bends to apply drive transistors
.diamond-solid. Epson Stylus
pressure to the ink, required
.diamond-solid. Tektronix
ejecting drops. .diamond-solid. Full
pagewidth .diamond-solid. IJ04
print heads
impractical due to
actuator size
.diamond-solid.
Requires
electrical poling in
high field strengths
during manufacture
Electro- An electric field is .diamond-solid. Low power
.diamond-solid. Low maximum .diamond-solid. Seiko Epson,
strictive used to activate consumption strain (approx.
Usui et all JP
electrostriction in .diamond-solid. Many ink types 0.01%)
253401/96
relaxor materials such can be used .diamond-solid.
Large area .diamond-solid. IJ04
as lead lanthanum .diamond-solid. Low thermal required for
actuator
zirconate titanate expansion due to low strain
(PLZT) or lead .diamond-solid. Electric field
.diamond-solid. Response speed
magnesium niobate strength required is marginal
(.about.10 .mu.s)
(PMN). (approx. 3.5 V/.mu.m) .diamond-solid. High
voltage
can be generated drive transistors
without difficulty required
.diamond-solid. Does not require
.diamond-solid. Full pagewidth
electrical poling print heads
impractical due to
actuator size
Ferro- An electric field is .diamond-solid. Low power
.diamond-solid. Difficult to .diamond-solid. IJ04
electric used to induce a phase consumption integrate with
transition between the .diamond-solid. Many ink types
electronics
antiferroelectric (AFE) can be used .diamond-solid.
Unusual
and ferroelectric (FE) .diamond-solid. Fast operation materials
such as
phase. Perovskite (<1 .mu.s) PLZSnT are
materials such as tin .diamond-solid. Relatively high required
modified lead longitudinal strain .diamond-solid.
Actuators require
lanthanum zirconate .diamond-solid. High efficiency a large
area
titanate (PLZSnT) .diamond-solid. Electric field
exhibit large strains of strength of around 3
up to 1% associated V/.mu.m can be readily
with the AFE to FE provided
phase transition.
Electro- Conductive plates are .diamond-solid. Low power
.diamond-solid. Difficult to .diamond-solid. IJ02, IJ04
static plates separated by a consumption operate
electrostatic
compressible or fluid .diamond-solid. Many ink types devices in
an
dielectric (usually air). can be used aqueous
Upon application of a .diamond-solid. Fast operation
environment
voltage, the plates .diamond-solid. The
electrostatic
attract each other and actuator will
displace ink, causing normally need to be
drop ejection. The separated from the
conductive plates may ink
be in a comb or .diamond-solid. Very
large area
honeycomb structure, required to achieve
or stacked to increase high forces
the surface area and .diamond-solid. High
voltage
therefore the force. drive transistors
may be required
.diamond-solid. Full
pagewidth
print heads are not
competitive due to
actuator size
Electro- A strong electric field .diamond-solid. Low current
.diamond-solid. High voltage .diamond-solid. 1989 Saito et al,
static pull is applied to the ink, consumption required
U.S. Pat. No. 4,799,068
on ink whereupon .diamond-solid. Low temperature
.diamond-solid. May be damaged .diamond-solid. 1989 Miura et al,
electrostatic attraction by sparks due to
air U.S. Pat. No. 4,810,954
accelerates the ink breakdown
.diamond-solid. Tone-jet
towards the print .diamond-solid.
Required field
medium. strength increases as
the drop size
decreases
.diamond-solid. High
voltage
drive transistors
required
.diamond-solid.
Electrostatic field
attracts dust
Permanent An electromagnet .diamond-solid. Low power
.diamond-solid. Complex .diamond-solid. IJ07, IJ10
magnet directly attracts a consumption fabrication
electro- permanent magnet, .diamond-solid. Many ink types
.diamond-solid. Permanent
magnetic displacing ink and can be used magnetic material
causing drop ejection. .diamond-solid. Fast operation such as
Neodymium
Rare earth magnets .diamond-solid. High efficiency Iron Boron
(NdFeB)
with a field strength .diamond-solid. Easy extension required.
around 1 Tesla can be from single nozzles .diamond-solid. High
local
used. Examples are: to pagewidth print currents required
Samarium Cobalt heads .diamond-solid.
Copper
(SaCo) and magnetic metalization should
materials in the be used for long
neodymium iron boron electromigration
family (NdFeB, lifetime and low
NdDyFeBNb, resistivity
NdDyFeB, etc) .diamond-solid.
Pigmented inks
are usually
infeasible
.diamond-solid.
Operating
temperature limited
to the Curie
temperature (around
540K)
Soft A solenoid induced a .diamond-solid. Low power
.diamond-solid. Complex .diamond-solid. IJ01, IJ05, IJ08,
magnetic magnetic field in a soft consumption fabrication
IJ10, IJ12, IJ14,
core electro- magnetic core or yoke .diamond-solid. Many ink types
.diamond-solid. Materials not IJ15, IJ17
magnetic fabricated from a can be used usually present in a
ferrous material such .diamond-solid. Fast operation CMOS fab
such as
as electroplated iron .diamond-solid. High efficiency NiFe,
CoNiFe, or
alloys such as CoNiFe .diamond-solid. Easy extension CoFe are
required
[1], CoFe, or NiFe from single nozzles .diamond-solid. High
local
alloys. Typically, the to pagewidth print currents required
soft magnetic material heads .diamond-solid.
Copper
is in two parts, which metalization should
are normally held be used for long
apart by a spring. electromigration
When the solenoid is lifetime and low
actuated, the two parts resistivity
attract, displacing the .diamond-solid.
Electroplating is
ink. required
.diamond-solid. High
saturation
flux density is
required (2.0-2.1 T
is achievable with
CoNiFe [1])
Lorenz The Lorenz force .diamond-solid. Low power
.diamond-solid. Force acts as a .diamond-solid. IJ06, IJ11, IJ13,
force acting on a current consumption twisting motion
IJ16
carrying wire in a .diamond-solid. Many ink types
.diamond-solid. Typically, only a
magnetic field is can be used quarter of the
utilized. .diamond-solid. Fast operation solenoid
length
This allows the .diamond-solid. High efficiency provides
force in a
magnetic field to be .diamond-solid. Easy extension useful
direction
supplied externally to from single nozzles .diamond-solid.
High local
the print head, for to pagewidth print currents required
example with rare heads .diamond-solid.
Copper
earth permanent metalization should
magnets. be used for long
Only the current electromigration
carrying wire need be lifetime and low
fabricated on the print- resistivity
head, simplifying .diamond-solid.
Pigmented inks
materials are usually
requirements. infeasible
Magneto- The actuator uses the .diamond-solid. Many ink types
.diamond-solid. Force acts as a .diamond-solid. Fischenbeck,
striction giant magnetostrictive can be used twisting motion
U.S. Pat. No. 4,032,929
effect of materials .diamond-solid. Fast operation
.diamond-solid. Unusual .diamond-solid. IJ25
such as Terfenol-D (an .diamond-solid. Easy extension materials
such as
alloy of terbium, from single nozzles Terfenol-D are
dysprosium and iron to pagewidth print required
developed at the Naval heads .diamond-solid.
High local
Ordnance Laboratory, .diamond-solid. High force is currents
required
hence Ter-Fe-NOL). available .diamond-solid.
Copper
For best efficiency, the metalization
should
actuator should be pre- be used for long
stressed to approx. 8 electromigration
MPa. lifetime and low
resistivity
.diamond-solid.
Pre-stressing
may be required
Surface Ink under positive .diamond-solid. Low power
.diamond-solid. Requires .diamond-solid. Silverbrook, EP
tension pressure is held in a consumption supplementary force
0771 658 A2 and
reduction nozzle by surface .diamond-solid. Simple to effect
drop related patent
tension. The surface construction separation
applications
tension of the ink is .diamond-solid. No unusual
.diamond-solid. Requires special
reduced below the materials required in ink surfactants
bubble threshold, fabrication .diamond-solid. Speed
may be
causing the ink to .diamond-solid. High efficiency limited by
surfactant
egress from the .diamond-solid. Easy extension properties
nozzle. from single nozzles
to pagewidth print
heads
Viscosity The ink viscosity is .diamond-solid. Simple
.diamond-solid. Requires .diamond-solid. Silverbrook, EP
reduction locally reduced to construction supplementary force
0771 658 A2 and
select which drops are .diamond-solid. No unusual to effect
drop related patent
to be ejected. A materials required in separation
applications
viscosity reduction can fabrication .diamond-solid.
Requires special
be achieved .diamond-solid. Easy extension ink
viscosity
electrothermally with from single nozzles properties
most inks, but special to pagewidth print .diamond-solid.
High speed is
inks can be engineered heads difficult to
achieve
for a 100:1 viscosity .diamond-solid.
Requires
reduction. oscillating ink
pressure
.diamond-solid. A
high
temperature
difference (typically
80 degrees) is
required
Acoustic An acoustic wave is .diamond-solid. Can operate
.diamond-solid. Complex drive .diamond-solid. 1993 Hadimioglu
generated and without a nozzle circuitry
et al, EUP 550,192
focussed upon the plate .diamond-solid.
Complex .diamond-solid. 1993 Elrod et al,
drop ejection region. fabrication
EUP 572,220
.diamond-solid. Low
efficiency
.diamond-solid. Poor
control of
drop position
.diamond-solid. Poor
control of
drop volume
Thermo- An actuator which .diamond-solid. Low power
.diamond-solid. Efficient aqueous .diamond-solid. IJ03, IJ09, IJ17,
elastic bend relies upon differential consumption operation
requires a IJ18, IJ19, IJ20,
actuator thermal expansion .diamond-solid. Many ink types thermal
insulator on IJ21, IJ22, IJ23,
upon Joule heating is can be used the hot side
IJ24, IJ27, IJ28,
used. .diamond-solid.
Simple planar
.diamond-solid. Corrosion IJ29, IJ30, IJ31,
fabrication prevention can be
IJ32, IJ33, IJ34,
.diamond-solid. Small chip area difficult
IJ35, IJ36, IJ37,
required for each .diamond-solid.
Pigmented inks IJ38, IJ39, IJ40,
actuator may be infeasible,
IJ41
.diamond-solid. Fast operation as pigment
particles
.diamond-solid. High efficiency may jam
the bend
.diamond-solid. CMOS actuator
compatible voltages
and currents
.diamond-solid. Standard MEMS
processes can be
used
.diamond-solid. Easy extension
from single nozzles
to pagewidth print
heads
High CTE A material with a very .diamond-solid. High force can
.diamond-solid. Requires special .diamond-solid. IJ09, IJ17, IJ18,
thermo- high coefficient of be generated material (e.g. PTFE)
IJ20, IJ21, IJ22,
elastic thermal expansion .diamond-solid. Three methods of
.diamond-solid. Requires a PTFE IJ23, IJ24, IJ27,
actuator (CTE) such as PTFE deposition are deposition process,
IJ28, IJ29, IJ30,
polytetrafluoroethylene under development: which is not yet
IJ31, IJ42, IJ43,
(PTFE) is used. As chemical vapor standard in ULSI
IJ44
high CTE materials deposition (CVD), fabs
are usually non- spin coating, and .diamond-solid. PTFE
deposition
conductive, a heater evaporation cannot be followed
fabricated from a .diamond-solid. PTFE is a with high
conductive material is candidate for low temperature (above
incorporated. A 50 .mu.m dielectric constant 350.degree. C.)
processing
long PTFE bend insulation in ULSI .diamond-solid.
Pigmented inks
actuator with .diamond-solid. Very low power may be
infeasible,
polysilicon heater and consumption as pigment
particles
15 mW power input .diamond-solid. Many ink types may jam the
bend
can provide 180 .mu.N can be used actuator
force and 10 .mu.m .diamond-solid. Simple planar
deflection. Actuator fabrication
motions include: .diamond-solid. Small chip area
Bend required for each
Push actuator
Buckle .diamond-solid. Fast operation
Rotate .diamond-solid. High efficiency
.diamond-solid. CMOS
compatible voltages
and currents
.diamond-solid. Easy extension
from single nozzles
to pagewidth print
heads
Conductive A polymer with a high .diamond-solid. High force can
.diamond-solid. Requires special .diamond-solid. IJ24
polymer coefficient of thermal be generated materials
thermo- expansion (such as .diamond-solid. Very low power development
(High
elastic PTFE) is doped with consumption CTE conductive
actuator conducting substances .diamond-solid. Many ink types polymer)
to increase its can be used .diamond-solid.
Requires a PTFE
conductivity to about 3 .diamond-solid. Simple planar
deposition process,
orders of magnitude fabrication which is not yet
below that of copper. .diamond-solid. Small chip area standard
in ULSI
The conducting required for each fabs
polymer expands actuator .diamond-solid. PTFE
deposition
when resistively .diamond-solid. Fast operation cannot be
followed
heated. .diamond-solid. High efficiency with high
Examples of .diamond-solid. CMOS temperature
(above
conducting dopants compatible voltages 350.degree. C.)
processing
include: and currents .diamond-solid.
Evaporation and
Carbon nanotubes .diamond-solid. Easy extension CVD
deposition
Metal fibers from single nozzles techniques cannot
Conductive polymers to pagewidth print be used
such as doped heads .diamond-solid.
Pigmented inks
polythiophene may be infeasible,
Carbon granules as pigment particles
may jam the bend
actuator
Shape A shape memory alloy .diamond-solid. High force is
.diamond-solid. Fatigue limits .diamond-solid. IJ26
memory such as TiNi (also available (stresses maximum number
alloy known as Nitinol - of hundreds of MPa) of cycles
Nickel Titanium alloy .diamond-solid. Large strain is
.diamond-solid. Low strain (1%)
developed at the Naval available (more than is required to
extend
Ordnance Laboratory) 3%) fatigue resistance
is thermally switched .diamond-solid. High corrosion
.diamond-solid. Cycle rate
between its weak resistance limited by heat
martensitic state and .diamond-solid. Simple removal
its high stiffness construction .diamond-solid.
Requires unusual
austenic state. The .diamond-solid. Easy extension materials
(TiNi)
shape of the actuator from single nozzles .diamond-solid. The
latent heat of
in its martensitic state to pagewidth print transformation
must
is deformed relative to heads be provided
the austenic shape. .diamond-solid. Low voltage
.diamond-solid. High current
The shape change operation operation
causes ejection of a .diamond-solid.
Requires pre-
drop. stressing to distort
the martensitic state
Linear Linear magnetic .diamond-solid. Linear Magnetic
.diamond-solid. Requires unusual .diamond-solid. IJ12
Magnetic actuators include the actuators can be semiconductor
Actuator Linear Induction constructed with materials such as
Actuator (LIA), Linear high thrust, long soft magnetic
alloys
Permanent Magnet travel, and high (e.g. CoNiFe)
Synchronous Actuator efficiency using .diamond-solid. Some
varieties
(LPMSA), Linear planar also require
Reluctance semiconductor permanent magnetic
Synchronous Actuator fabrication materials such as
(LRSA), Linear techniques Neodymium iron
Switched Reluctance .diamond-solid. Long actuator boron
(NdFeB)
Actuator (LSRA), and travel is available .diamond-solid.
Requires
the Linear Stepper .diamond-solid. Medium force is complex
multi-
Actuator (LSA). available phase drive circuitry
.diamond-solid. Low voltage
.diamond-solid. High current
operation operation
BASIC OPERATION MODE
Description Advantages Disadvantages
Examples
Actuator This is the simplest .diamond-solid. Simple operation
.diamond-solid. Drop repetition .diamond-solid. Thermal ink jet
directly mode of operation: the .diamond-solid. No external rate is
usually .diamond-solid. Piezoelectric ink
pushes ink actuator directly fields required limited to around 10
jet
supplies sufficient .diamond-solid. Satellite drops kHz.
However, this .diamond-solid. IJ01, IJ02, IJ03,
kinetic energy to expel can be avoided if is not fundamental
IJ04, IJ05, IJ06,
the drop. The drop drop velocity is less to the method, but
is IJ07, IJ09, IJ11,
must have a sufficient than 4 m/s related to the
refill IJ12, IJ14, IJ16,
velocity to overcome .diamond-solid. Can be efficient, method
normally IJ20, IJ22, IJ23,
the surface tension. depending upon the used
IJ24, IJ25, IJ26,
actuator used .diamond-solid. All
of the drop IJ27, IJ28, IJ29,
kinetic energy must
IJ30, IJ31, IJ32,
be provided by the
IJ33, IJ34, IJ35,
actuator
IJ36, IJ37, IJ38,
.diamond-solid.
Satellite drops IJ39, IJ40, IJ41,
usually form if drop
IJ42, IJ43, IJ44
velocity is greater
than 4.5 m/s
Proximity The drops to be .diamond-solid. Very simple print
.diamond-solid. Requires close .diamond-solid. Silverbrook, EP
printed are selected by head fabrication can proximity between
0771 658 A2 and
some manner (e.g. be used the print head and
related patent
thermally induced .diamond-solid. The drop the print
media or applications
surface tension selection means transfer roller
reduction of does not need to .diamond-solid. May
require two
pressurized ink). provide the energy print heads printing
Selected drops are required to separate alternate rows of the
separated from the ink the drop from the image
in the nozzle by nozzle .diamond-solid.
Monolithic color
contact with the print print heads are
medium or a transfer difficult
roller.
Electro- The drops to be .diamond-solid. Very simple print
.diamond-solid. Requires very .diamond-solid. Silverbrook, EP
static pull printed are selected by head fabrication can high electrostatic
0771 658 A2 and
on ink some manner (e.g. be used field
related patent
thermally induced .diamond-solid. The drop
.diamond-solid. Electrostatic field applications
surface tension selection means for small nozzle
.diamond-solid. Tone-Jet
reduction of does not need to sizes is above air
pressurized ink). provide the energy breakdown
Selected drops are required to separate .diamond-solid.
Electrostatic field
separated from the ink the drop from the may attract dust
in the nozzle by a nozzle
strong electric field.
Magnetic The drops to be .diamond-solid. Very simple print
.diamond-solid. Requires .diamond-solid. Silverbrook, EP
pull on ink printed are selected by head fabrication can magnetic ink
0771 658 A2 and
some manner (e.g. be used .diamond-solid. Ink
colors other related patent
thermally induced .diamond-solid. The drop than black
are applications
surface tension selection means difficult
reduction of does not need to .diamond-solid.
Requires very
pressurized ink). provide the energy high magnetic fields
Selected drops are required to separate
separated from the ink the drop from the
in the nozzle by a nozzle
strong magnetic field
acting on the magnetic
ink.
Shutter The actuator moves a .diamond-solid. High speed (>50
.diamond-solid. Moving parts are .diamond-solid. IJ13, IJ17, IJ21
shutter to block ink kHz) operation can required
flow to the nozzle. The be achieved due to .diamond-solid.
Requires ink
ink pressure is pulsed reduced refill time pressure modulator
at a multiple of the .diamond-solid. Drop timing can
.diamond-solid. Friction and wear
drop ejection be very accurate must be considered
frequency. .diamond-solid. The actuator energy
.diamond-solid. Stiction is
can be very low possible
Shuttered The actuator moves a .diamond-solid. Actuators with
.diamond-solid. Moving parts are .diamond-solid. IJ08, IJ15, IJ18,
grill shutter to block ink small travel can be required
IJ19
flow through a grill to used .diamond-solid.
Requires ink
the nozzle. The shutter .diamond-solid. Actuators with pressure
modulator
movement need only small force can be .diamond-solid.
Friction and wear
be equal to the width used must be considered
of the grill holes. .diamond-solid. High speed (>50
.diamond-solid. Stiction is
kHz) operation can possible
be achieved
Pulsed A pulsed magnetic .diamond-solid. Extremely low
.diamond-solid. Requires an .diamond-solid. IJ10
magnetic field attracts an `ink energy operation is external pulsed
pull on ink pusher` at the drop possible magnetic field
pusher ejection frequency. An .diamond-solid. No heat
.diamond-solid. Requires special
actuator controls a dissipation materials for both
catch, which prevents problems the actuator and the
the ink pusher from ink pusher
moving when a drop is .diamond-solid.
Complex
not to be ejected. construction
AUXILIARY MECHANISM (APPLIED TO ALL NOZZLES)
Description Advantages Disadvantages
Examples
None The actuator directly .diamond-solid. Simplicity of
.diamond-solid. Drop ejection .diamond-solid. Most ink jets,
fires the ink drop, and construction energy must be
including
there is no external .diamond-solid. Simplicity of supplied by
piezoelectric and
field or other operation individual nozzle
thermal bubble.
mechanism required. .diamond-solid. Small physical actuator
.diamond-solid. IJ01, IJ02, IJ03,
size
IJ04, IJ05, IJ07,
IJ09, IJ11, IJ12,
IJ14, IJ20, IJ22,
IJ23, IJ24, IJ25,
IJ26, IJ27, IJ28,
IJ29, IJ30, IJ31,
IJ32, IJ33, IJ34,
IJ35, IJ36, IJ37,
IJ38, IJ39, IJ40,
IJ41, IJ42, IJ43,
IJ44
Oscillating The ink pressure .diamond-solid. Oscillating ink
.diamond-solid. Requires external .diamond-solid. Silverbrook, EP
ink pressure oscillates, providing pressure can provide ink pressure
0771 658 A2 and
(including much of the drop a refill pulse, oscillator
related patent
acoustic ejection energy. The allowing higher .diamond-solid. Ink
pressure applications
stimul- actuator selects which operating speed phase and amplitude
.diamond-solid. IJ08, IJ13, IJ15,
ation) drops are to be fired .diamond-solid. The actuators must be
carefully IJ17, IJ18, IJ19,
by selectively may operate with controlled
IJ21
blocking or enabling much lower energy .diamond-solid.
Acoustic
nozzles. The ink .diamond-solid. Acoustic lenses
reflections in the ink
pressure oscillation can be used to focus chamber must be
may be achieved by the sound on the designed for
vibrating the print nozzles
head, or preferably by
an actuator in the ink
supply.
Media The print head is .diamond-solid. Low power
.diamond-solid. Precision .diamond-solid. Silverbrook, EP
proximity placed in close .diamond-solid. High accuracy assembly
required 0771 658 A2 and
proximity to the print .diamond-solid. Simple print head
.diamond-solid. Paper fibers may related patent
medium. Selected construction cause problems
applications
drops protrude from .diamond-solid.
Cannot print on
the print head further rough substrates
than unselected drops,
and contact the print
medium. The drop
soaks into the medium
fast enough to cause
drop separation.
Transfer Drops are printed to a .diamond-solid. High accuracy
.diamond-solid. Bulky .diamond-solid. Silverbrook, EP
roller transfer roller instead .diamond-solid. Wide range of
.diamond-solid. Expensive 0771 658 A2 and
of straight to the print print substrates can .diamond-solid.
Complex related patent
medium. A transfer be used construction
applications
roller can also be used .diamond-solid. Ink can be dried
.diamond-solid. Tektronix hot
for proximity drop on the transfer roller
melt piezoelectric
separation.
ink jet
.diamond-solid. Any of the IJ
series
Electro- An electric field is .diamond-solid. Low power
.diamond-solid. Field strength .diamond-solid. Silverbrook, EP
static used to accelerate .diamond-solid. Simple print head required
for 0771 658 A2 and
selected drops towards construction separation of small
related patent
the print medium. drops is near or
applications
above air
.diamond-solid. Tone-Jet
breakdown
Direct A magnetic field is .diamond-solid. Low power
.diamond-solid. Requires .diamond-solid. Silverbrook, EP
magnetic used to accelerate .diamond-solid. Simple print head magnetic
ink 0771 658 A2 and
field selected drops of construction .diamond-solid.
Requires strong related patent
magnetic ink towards magnetic field
applications
the print medium.
Cross The print head is .diamond-solid. Does not require
.diamond-solid. Requires external .diamond-solid. IJ06, IJ16
magnetic placed in a constant magnetic materials magnet
field magnetic fleld. The to be integrated in .diamond-solid.
Current densities
Lorenz force in a the print head may be high,
current carrying wire manufacturing resulting in
is used to move the process electromigration
actuator. problems
Pulsed A pulsed magnetic .diamond-solid. Very low power
.diamond-solid. Complex print .diamond-solid. IJ10
magnetic field is used to operation is possible head construction
field cyclically attract a .diamond-solid. Small print head
.diamond-solid. Magnetic
paddle, which pushes size materials required in
on the ink. A small print head
actuator moves a
catch, which
selectively prevents
the paddle from
moving.
ACTUATOR AMPLIFICATION OR MODIFICATION METHOD
Description Advantages Disadvantages
Examples
None No actuator .diamond-solid. Operational
.diamond-solid. Many actuator .diamond-solid. Thermal Bubble
mechanical simplicity mechanisms have
Ink jet
amplification is used. insufficient
travel, .diamond-solid. IJ01, IJ02, IJ06,
The actuator directly or
insufficient force, IJ07, IJ16, IJ25,
drives the drop to efficiently
drive IJ26
ejection process. the drop ejection
process
Differential An actuator material .diamond-solid. Provides greater
.diamond-solid. High stresses are .diamond-solid. Piezoelectric
expansion expands more on one travel in a reduced involved
.diamond-solid. IJ03, IJ9, IJ17,
actuator The expansion may be taken that the
IJ21, IJ22, IJ23,
thermal, piezoelectric, materials do
not IJ24, IJ27, IJ29,
magnetostrictive, or delaminate
IJ30, IJ31, IJ32,
other mechanism. The Residual bend
IJ33, IJ34, IJ35,
bend actuator converts resulting
from high IJ36, IJ37, IJ38,
a high force low travel temperature
or high IJ39, IJ42, IJ43,
actuator mechanism to stress during
IJ44
high travel, lower formation
force mechanism.
Transient A trilayer bend .diamond-solid. Very good
.diamond-solid. High stresses are .diamond-solid. IJ40, IJ41
bend actuator where the two temperature stability involved
actuator outside layers are .diamond-solid. High speed, as a
.diamond-solid. Care must be
identical. This cancels new drop can be taken that
the
bend due to ambient fired before heat materials do
not
temperature and dissipates delaminate
residual stress. The .diamond-solid. Cancels residual
actuator only responds stress of formation
to transient heating of
one side or the other.
Reverse The actuator loads a .diamond-solid. Better coupling
.diamond-solid. Fabrication .diamond-solid. IJ05, IJ11
spring spring. When the to the ink complexity
actuator is turned off, .diamond-solid.
High stress in the
the spring releases. spring
This can reverse the
force/distance curve of
the actuator to make it
compatible with the
force/time
requirements of the
drop ejection.
Actuator A series of thin .diamond-solid. Increased travel
.diamond-solid. Increased .diamond-solid. Some
stack actuators are stacked. .diamond-solid. Reduced drive
fabrication piezoelectric inkjets
This can be voltage complexity
.diamond-solid. IJ04
appropriate where .diamond-solid.
Increased
actuators require high possibility
of short
electric field strength, circuits
due to
such as electrostatic pinholes
and piezoelectric
actuators.
Multiple Multiple smaller .diamond-solid. Increases the
.diamond-solid. Actuator forces .diamond-solid. IJ12, IJ13, IJ18,
actuators actuators are used force availabte from may not add
IJ20, IJ22, IJ28,
simultaneously to an actuator linearly,
reducing IJ42, IJ43
move the ink. Each .diamond-solid. Multiple
efficiency
actuator need provide actuators can be
only a portion of the positioned to control
force required. ink flow accuratety
Linear A linear spring is used .diamond-solid. Matches low
.diamond-solid. Requires print .diamond-solid. IJ15
Spring to transform a motion travel actuator with head area
for the
with small travel and higher travel spring
high force into a requirements
longer travel, lower .diamond-solid. Non-contact
force motion. method of motion
transformation
Coiled A bend actuator is .diamond-solid. Increases travel
.diamond-solid. Generally .diamond-solid. IJ17, IJ21, IJ34,
actuator coiled to provide .diamond-solid. Reduces chip
restricted to planar IJ35
greater travel in a area implementations
reduced chip area. .diamond-solid. Planar due to
extreme
implementations are fabrication
difficulty
relatively easy to in other
orientations.
fabricate.
Flexure A bend actuator has a .diamond-solid. Simple means of
.diamond-solid. Care must be .diamond-solid. IJ10, IJ19, IJ33
bend small region near the increasing travel of taken not
to exceed
actuator fixture point, which a bend actuator the etastic
limit in
flexes much more the flexure area
ready than the .diamond-solid. Stress
remainder of the distribution is
very
actuator. The actuator uneven
flexing is effectively .diamond-solid.
Difficult to
converted from an accurately model
even coiling to an with finite
element
angular bend, resulting analysis
in greater travel of the
actuator tip.
Catch The actuator controts a .diamond-solid. Very low
.diamond-solid. Complex .diamond-solid. IJ10
small catch. The catch actuator energy construction
either enables or .diamond-solid. Very small
.diamond-solid. Requires external
disables movement of actuator size force
an ink pusher that is .diamond-solid.
Unsuitable for
controlled in a bulk pigmented inks
manner.
Gears Gears can be used to .diamond-solid. Low force, low
.diamond-solid. Moving parts are .diamond-solid. IJ13
increase travel at the travel actuators can required
expense of duration. be used .diamond-solid.
Several actuator
Circular gears, rack .diamond-solid. Can be fabricated
cycles are required
and pinion, ratchets, using standard .diamond-solid.
More complex
and other gearing surface MEMS drive electronics
methods can be used. processes .diamond-solid.
Complex
construction
.diamond-solid.
Friction, friction,
and wear are
possible
Buckle plate A buckle plate can be .diamond-solid. Very fast
.diamond-solid. Must stay within .diamond-solid. S. Hirata et al,
used to change a slow movement elastic limits
of the "An Ink-jet Head
actuator into a fast achievable materials for
long Using Diaphragm
motion. It can also device life
Microactuator",
convert a high force, .diamond-solid.
High stresses Proc. IEEE MEMS,
low travel actuator involved
Feb. 1996, pp 418-
into a high travel, .diamond-solid.
Generally high 423.
medium force motion. power
requirement .diamond-solid. IJ18, IJ27
Tapered A tapered magnetic .diamond-solid. Linearizes the
.diamond-solid. Complex .diamond-solid. IJ14
magnetic pole can increase magnetic construction
pole travel at the expense force/distance curve
of force.
Lever A, lever and fulcrum is .diamond-solid. Matches low
.diamond-solid. High stress .diamond-solid.
IJ32, IJ36, IJ37
used to transform a travel actuator with around the
fulcrum
motion with small higher travei
travel and high force requirements
into a motion with .diamond-solid. Fulcrum area has
longer travel and no linear movement,
lower force. The lever and can be used for
can also reverse the a fluid seal
direction of travel.
Rotary The actuator is .diamond-solid. High mechanical
.diamond-solid. Complex .diamond-solid. IJ28
impeller connected to a rotary advantage construction
impeller. A small .diamond-solid. The ratio of force
.diamond-solid. Unsuitable for
angular deflection of to travel of the pigmented inks
the actuator results in actuator can be
a rotation of the matched to the
impeller vanes, which nozzle requirements
push the ink against by varying the
stationary vanes and numher of impeller
out of the nozzle. vanes
Acoustic A refractive or .diamond-solid. No moving parts
.diamond-solid. Large area .diamond-solid. 1993 Hadimioglu
lens diffractive (e.g. zone required
et al, EUP 550,192
plate) acoustic lens is .diamond-solid.
Only relevant for .diamond-solid. 1993 Elrod et al,
used to concentrate acoustic ink
jets EUP 572,220
sound waves.
Sharp A sharp point is used .diamond-solid. Simple
.diamond-solid. Difficult to .diamond-solid. Tone-jet
conductive to concentrate an construction fabricate using
point electrostatic field. standard VLSI
processes for a
surface ejecting
ink-
jet
.diamond-solid. Only
relevant for
electrostatic ink
jets
ACTUATOR MOTION
Description Advantages Disadvantages
Examples
Volume The volume of the .diamond-solid. Simple
.diamond-solid. High energy is .diamond-solid. Hewlett-Packard
expansion actuator changes, construction in the typically
required to Thermal Ink jet
pushing the ink in all case of thermal ink achieve
volume .diamond-solid. Canon Bubblejet
directions. jet expansion. This
leads to thermal
stress,
cavitation,
and kogation in
thermal ink jet
implementations
Linear, The actuator moves in .diamond-solid. Efficient
.diamond-solid. High fabrication .diamond-solid. IJ01, IJ02, IJ04,
normal to a direction normal to coupling to ink complexity may
be IJ07, IJ11, IJ14
chip surface the print head surface. drops ejected required to
achieve
The nozzle is typically normal to the
perpendicular
in the line of surface motion
movement.
ParalleI to The actuator moves .diamond-solid. Suitable for
.diamond-solid. Fabrication .diamond-solid. IJ12, IJ13, IJ15,
chip surface parallel to the print planar fabrication complexity
IJ33, IJ34, IJ35,
head surface. Drop .diamond-solid.
Friction IJ36
ejection may still be .diamond-solid.
Stiction
normal to the surface.
Membrane An actuator with a .diamond-solid. The effective
.diamond-solid. Fabrication .diamond-solid. 1982 Howkins
push high force but small area of the actuator complexity
U.S. Pat. No. 4,459,601
area is used to push a becomes the .diamond-solid.
Actuator size
stiff membrane that is membrane area .diamond-solid.
Difficulty of
in contact with the ink. integration
in a
VLSI process
Rotary The actuator causes .diamond-solid. Rotary levers
.diamond-solid. Device .diamond-solid. IJ05, IJ08, IJ13,
the rotation of some may be used to complexity
IJ28
element, such a grill or increase travel May have
impeller .diamond-solid. Small chip area
friction at a pivot
requirements. point
Bend The actuator bends .diamond-solid. A very small
.diamond-solid. Requires the .diamond-solid. 1970 Kyser et al
when energized. This change in actuator to be
made U.S. Pat. No. 3,946,398
may be due to dimensions can be from at least
two .diamond-solid. 1973 Stemme
differential thermal converted to a large distinct
layers, or to U.S. Pat. No. 3,747,120
expansion, motion. have a thermal
.diamond-solid. IJ03, IJ09, IJ10,
piezoelectric difference across
the IJ19, IJ23, IJ24,
expansion, actuator
IJ25, IJ29, IJ30,
magnetostriction, or
IJ31, IJ33, IJ34,
other form of relative
IJ35
dimensional change.
Swivel The actuator swivels .diamond-solid. Allows operation
.diamond-solid. Inefficient .diamond-solid. IJ06
around a central pivot. where the net linear coupling
to the ink
This motion is suitable force on the paddle motion
where there are is zero
opposite forces .diamond-solid. Small chip area
applied to opposite requirements
sides of the paddle,
e.g. Lorenz force.
Straighten The actuator is .diamond-solid. Can be used with
.diamond-solid. Requires careful .diamond-solid. IJ26, IJ32
normally bent, and shape memory balance of
stresses
straightens when alloys where the to ensure that
the
energized. austenic phase is quiescent bend
is
planar accurate
Double The actuator bends in .diamond-solid. One actuator can
.diamond-solid. Difficult to make .diamond-solid. IJ36, IJ37, IJ38
bend one direction when be used to power the drops ejected
by
one element is two nozzles. both bend
directions
energized, and bends .diamond-solid. Reduced chip
identical.
the other way when size. .diamond-solid. A
small
another element is .diamond-solid. Not sensitive to
efficiency 1055
energized. ambient temperature compared to
equivalent single
bend actuators.
Shear Energizing the .diamond-solid. Can increase the
.diamond-solid. Not readily .diamond-solid. 1985 Fishbeck
actuator causes a shear effective travel of
applicable to other U.S. Pat. No. 4,584,590
motion in the actuator piezoelectric actuator
material. actuators mechanisms
Radial con- The actuator squeezes .diamond-solid. Relatively easy
.diamond-solid. High force .diamond-solid. 1970 Zoltan USP
striction an ink reservoir, to fabricate single required
3,683,212
forcing ink from a nozzles from glass .diamond-solid.
Inefficient
constricted nozzle. tubing as .diamond-solid.
Difficult to
macroscopic integrate with
VLSI
structures processes
Coil/uncoil A coiled actuator .diamond-solid. Easy to fabricate
.diamond-solid. Difficult to .diamond-solid. IJ17, IJ21, IJ34,
uncoils or coils more as a planar VLSI fabricate for
non- IJ35
tightly. The motion of process planar
devices
the free end of the .diamond-solid. Small area
.diamond-solid. Poor out-of-plane
actuator ejects the ink. required, therefore
stiffness
low cost
Bow The actuator bows (or .diamond-solid. Can increase the
.diamond-solid. Maximum travel .diamond-solid. IJ16, IJ18, IJ27
buckles) in the middle speed of travel is
constrained
when energized. .diamond-solid. Mechanically
.diamond-solid. High force
rigid required
Push-Pull Two actuators control .diamond-solid. The structure is
.diamond-solid. Not readily .diamond-solid. IJ18
a shulter. One actuator pinned at both ends, suitable
for ink jets
pulls the shutter, and so has a high out-of- which
directly push
the other pushes it. plane rigidity the ink
Curl A set of actuators curl .diamond-solid. Good fluid flow
.diamond-solid. Design .diamond-solid. IJ20, IJ42
inwards inwards to reduce the to the region behind complexity
volume of ink that the actuator
they enclose. increases efficiency
Curl A set of actuators curl .diamond-solid. Relatively simple
.diamond-solid. Relatively large .diamond-solid. IJ43
outwards outwards, pressurizing construction chip area
ink in a chamber
surrounding the
actuators, and
expelling ink from a
nozzle in the chamber.
Iris Multiple vanes enclose .diamond-solid. High efficiency
.diamond-solid. High fabrication .diamond-solid.
IJ22
a volume of ink. These .diamond-solid. Small chip area
complexity
simultaneously rotate, .diamond-solid.
Not suitable for
reducing the volume pigmented inks
between the vanes.
Acoustic The actuator vibrates .diamond-solid. The actuator can
.diamond-solid. Large area .diamond-solid. 1993 Hadimioglu
vibration at a high frequency. be physically distant required
for et al, EUP 550,192
from the ink efficient
operation .diamond-solid. 1993 Elrod et al,
at useful
frequencies EUP 572,220
.diamond-solid.
Acoustic
coupling and
crosstalk
.diamond-solid.
Complex drive
circuitry
.diamond-solid. Poor
control of
drop volume and
position
None In various ink jet .diamond-solid. No moving parts
.diamond-solid. Various other .diamond-solid. Silverbrook, EP
designs the actuator tradeoffs are
0771 658 A2 and
does not move. required to
related patent
eliminate moving
applications
parts
.diamond-solid. Tone-jet
NOZZLE REFILL METHOD
Description Advantages Disadvantages
Examples
Surface This is the normal way .diamond-solid. Fabrication
.diamond-solid. Low speed .diamond-solid. Thermal ink jet
tension that ink jets are simplicity .diamond-solid.
Surface tension .diamond-solid. Piezoelectric ink
refilled. After the .diamond-solid. Operational force
relatively jet
actuator is energized, simplicity small compared to
.diamond-solid. IJ01-IJ07, IJ10-
it typically returns actuator force
IJ14, IJ16, IJ20,
rapidly to its normal .diamond-solid. Long
refill time IJ22-IJ45
position. This rapid usually dominates
return sucks in air the total repetition
through the nozzle rate
opening. The ink
surface tension at the
nozzle then exerts a
small force restoring
the meniscus to a
minimum area. This
force refills the nozzle.
Shuttered Ink to the nozzle .diamond-solid. High speed
.diamond-solid. Requires .diamond-solid. IJ08, IJ13, IJ15,
oscillating chamber is provided at .diamond-solid. Low actuator common ink
IJ17, IJ18, IJ19,
ink pressure a pressure that energy, as the pressure oscillator
IJ21
oscillates at twice the actuator need only .diamond-solid.
May not be
drop ejection open or close the suitable for
frequency. When a shutter, instead of pigmented inks
drop is to be ejected, ejecting the ink drop
the shutter is opened
for 3 half cycles: drop
ejection, actuator
return, and refill. The
shutter is then closed
to prevent the nozzle
chamber emptying
during the next
negative pressure
cycle.
Refill After the main .diamond-solid. High speed, as
.diamond-solid. Requires two .diamond-solid. IJ09
actuator actuator has ejected a the nozzle is independent
drop a second (refill) actively refilled actuators per
nozzle
actuator is energized.
The refill actuator
pushes ink into the
nozzle chamber. The
refill actuator returns
slowly, to prevent its
return from emptying
the chamber again.
Positive ink The ink is held a slight .diamond-solid. High refill rate,
.diamond-solid. Surface spill .diamond-solid. Silverbrook, EP
pressure positive pressure. therefore a high must be prevented
0771 658 A2 and
After the ink drop is drop repetition rate .diamond-solid.
Highly related patent
ejected, the nozzle is possible hydrophobic print
applications
chamber fills quickly head surfaces are
.diamond-solid. Alternative for:,
as surface tension and required
IJ01-IJ07, IJ10-IJ14,
ink pressure hoth
IJ16, IJ20, IJ22-IJ45
operate to refill the
nozzle.
METHOD OF RESTRICTING BACK-FLOW THROUGH INLET
Description Advantages Disadvantages
Examples
Long inlet The ink inlet channel .diamond-solid. Design simplicity
.diamond-solid. Restricts refill .diamond-solid. Thermal ink jet
channel to the nozzle chamber .diamond-solid. Operational rate
.diamond-solid. Piezoelectric ink
is made long and simplicity .diamond-solid. May
result in a jet
relatively narrow, .diamond-solid. Reduces relatively
large chip .diamond-solid. IJ42, IJ43
relying on viscous crosstalk area
drag to reduce inlet .diamond-solid. Only
partially
back-flow. effective
Positive ink The ink is under a .diamond-solid. Drop selection
.diamond-solid. Requires a .diamond-solid. Silverbrook, EP
pressure positive pressure, so and separation method (such as a
0771 658 A2 and
that in the quiescent forces can be nozzle rim or
related patent
state some of the ink reduced effective
applications
drop already protrudes .diamond-solid. Fast refill time
hydrophobizing, or .diamond-solid. Possible
from the nozzle. both) to prevent
operation of the
This reduces the flooding of the
following: IJ01-
pressure in the nozzle ejection surface of
IJ07, IJ09-IJ12,
chamber which is the print head.
IJ14, IJ16, IJ20,
required to eject a
IJ22, , IJ23-IJ34,
certain volume of ink.
IJ36-IJ41, IJ44
The reduction in
chamber pressure
results in a reduction
in ink pushed out
through the inlet.
Baffle One or more baffles .diamond-solid. The refill rate is
.diamond-solid. Design .diamond-solid. HP Thermal Ink
are placed in the inlet not as restricted as complexity
Jet
ink flow. When the the long inlet .diamond-solid. May
increase .diamond-solid. Tektronix
actuator is energized, method. fabrication
piezoelectric ink jet
the rapid ink .diamond-solid. Reduces complexity
(e.g.
movement creates crosstalk Tektronix hot melt
eddies which restrict Piezoelectric print
the flow through the heads).
inlet. The slower refill
process is unrestricted,
and does not result in
eddies.
Flexible flap In this method recently .diamond-solid. Significantly
.diamond-solid. Not applicable to .diamond-solid. Canon
restricts disclosed by Canon, reduces back-flow most ink jet
inlet the expanding actuator for edge-shooter configurations
(bubble) pushes on a thermal ink jet .diamond-solid.
Increased
flexible flap that devices fabrication
restricts the inlet. complexity
.diamond-solid.
Inelastic
deformation of
polymer flap results
in creep over
extended use
Inlet filter A filter is located .diamond-solid. Additional
.diamond-solid. Restricts refill .diamond-solid. IJ04, IJ12, IJ24,
between the ink inlet advantage of ink rate
IJ27, IJ29, IJ30
and the nozzle filtration .diamond-solid. May
result in
chamber. The filter .diamond-solid. Ink filter may be complex
has a multitude of fabricated with no construction
small holes or slots, additional process
restricting ink flow. steps
The filter also removes
particles which may
block the nozzle.
Small inlet The ink inlet channel .diamond-solid. Design simplicity
.diamond-solid. Restricts refill .diamond-solid. IJ02, IJ37, IJ44
compared to the nozzle chamber rate
to nozzle has a substantially .diamond-solid. May
result in a
smaller cross section relatively large
chip
than that of the nozzle, area
resulting in easier ink .diamond-solid.
Only partially
egress out of the nozzle effective
than out of the inlet.
Inlet shutter A secondary actuator .diamond-solid. Increases speed
.diamond-solid. Requires separate .diamond-solid. IJ09
controls the position of of the ink-jet print refill actuator
and
a shutter, closing off head operation drive circuit
the ink inlet when the
main actuator is
energized.
The inlet is The method avoids the .diamond-solid. Back-flow
.diamond-solid. Requires careful .diamond-solid. IJ01, IJ03, IJ05,
located problem of inlet back- problem is design to minimize
IJ06, IJ07, IJ10,
behind the flow by arranging the eliminated the negative
IJ11, IJ14, IJ16,
ink-pushing ink-pushing surface of pressure behind the
IJ22, IJ23, IJ25,
surface the actuator between paddle
IJ28, IJ31, IJ32,
the inlet and the
IJ33, IJ34, IJ35,
nozzle.
IJ36, IJ39, IJ40,
IJ41
Part of the The actuator and a .diamond-solid. Significant
.diamond-solid. Small increase in .diamond-solid. IJ07, IJ20, IJ26,
actuator wall of the ink reductions in back- fabrication
IJ38
moves to chamber are arranged flow can be complexity
shut off the so that the motion of achieved
inlet the actuator closes off .diamond-solid. Compact designs
the inlet. possible
Nozzle In some configurations .diamond-solid. Ink back-flow
.diamond-solid. None related to .diamond-solid. Silverbrook, EP
actuator of ink jet, there is no problem is ink back-flow on
0771 658 A2 and
does not expansion or eliminated actuation
related patent
result in ink movement of an
applications
back-flow actuator which may
.diamond-solid. Valve-jet
cause ink back-flow
.diamond-solid. Tone-jet
through the inlet.
NOZZLE CLEARING METHOD
Description Advantages Disadvantages
Examples
Normal All of the nozzles are .diamond-solid. No added
.diamond-solid. May not be .diamond-solid. Most ink jet
nozzle firing fired periodically, complexity on the sufficient to
systems
before the ink has a print head displace dried
ink .diamond-solid. IJ01, IJ02, IJ03,
chance to dry. When
IJ04, IJ05, IJ06,
not in use the nozzles
IJ07, IJ09, IJ10,
are sealed (capped)
IJ11, IJ12, IJ14,
against air.
IJ16, IJ20, IJ22,
The nozzle firing is
IJ23, IJ24, IJ25,
usually performed
IJ26, IJ27, IJ28,
during a special
IJ29, IJ30, IJ31,
clearing cycle, after
IJ32, IJ33, IJ34,
first moving the print
IJ36, IJ37, IJ38,
head to a cleaning
IJ39, IJ40;, IJ41,
station.
IJ42, IJ43, IJ44,
IJ45
Extra In systems which heat .diamond-solid. Can be highly
.diamond-solid. Requires higher .diamond-solid. Silverbrook, EP
power to the ink, but do not boil effective if the drive
voltage for 0771 658 A2 and
ink heater it under normal heater is adjacent to clearing
related patent
situations, nozzle the nozzle .diamond-solid. May
require applications
clearing can be larger drive
achieved by over- transistors
powering the heater
and boiling ink at the
nozzle.
Rapid The actuator is fired in .diamond-solid. Does not require
.diamond-solid. Effectiveness .diamond-solid. May be used
succession rapid succession. In extra drive circuits depends
with: IJ01, IJ02,
of actuator some configurations, on the print head substantially
upon IJ03, IJ04, IJ05,
purses this may cause heat .diamond-solid. Can be readily the
configuration of IJ06, IJ07, IJ09,
build-up at the nozzle controlled and the inkjet
nozzle IJ10, IJ11, IJ14,
which boils the ink, initiated by digital
IJ16, IJ20, IJ22,
clearing the nozzle. In logic
IJ23, IJ24, IJ25,
other situations, it may
IJ27, IJ28, IJ29,
cause sufficient
IJ30, IJ31, IJ32,
vibrations to dislodge
IJ33, IJ34, IJ36,
clogged nozzles.
IJ37, IJ38, IJ39,
IJ40, IJ41, IJ42,
IJ43, IJ44, IJ45
Extra Where an actuator is .diamond-solid. A simple
.diamond-solid. Not suitable .diamond-solid. May be used
power to not normally driven to solution where where there
is a with: IJ03, IJ09,
ink pushing the limit of its motion, applicable hard limit
to IJ16, IJ20, IJ23,
actuator nozzle clearing may be actuator
movement IJ24, IJ25, IJ27,
assisted by providing
IJ29, IJ30, IJ31,
an enhanced drive
IJ32, IJ39, IJ40,
signal to the actuator.
IJ41, IJ42, IJ43,
IJ44, IJ45
Acoustic An ultrasonic wave is .diamond-solid. A high nozzle
.diamond-solid. High .diamond-solid. IJ08, IJ13, IJ15,
resonance applied to the ink clearing capability implementation
cost IJ17, IJ18, IJ19,
chamber. This wave is can be achieved if system does
not IJ21
of an appropriate .diamond-solid. May be
already include an
amplitude and implemented at very acoustic
actuator
frequency to cause low cost in systems
sufficient force at the which already
nozzle to clear include acoustic
blockages. This is actuators
easiest to achieve if
the ultrasonic wave is
at a resonant
frequency of the ink
cavity.
Nozzle A microfabricated .diamond-solid. Can clear
.diamond-solid. Accurate .diamond-solid. Silverbrook, EP
clearing plate is pushed against severely clogged mechanical
0771 658 A2 and
plate the nozzles. The plate nozzles alignment is
related patent
has a post for every required
applications
nozzle. A post moves .diamond-solid.
Moving parts are
through each nozzle, required
displacing dried ink. .diamond-solid.
There is risk of
damage to the
nozzles
.diamond-solid.
Accurate
fabrication is
required
Ink The pressure of the ink .diamond-solid. May be effective
.diamond-solid. Requires .diamond-solid. May be used
pressure is temporarily where other .diamond-solid.
pressure pump or with all IJ series
pulse increased so that ink methods cannot be other
pressure ink jets
streams from all of the used actuator
nozzles. This may be .diamond-solid.
Expensive
used in conjunction .diamond-solid.
Wasteful of ink
with actuator
energizing.
Print head A flexible `blade` is .diamond-solid. Effective for
.diamond-solid. Difficult to use if .diamond-solid. Many ink jet
wiper wiped across the print planar print head print head
surface is systems
head surface. The surfaces non-planar or
very
blade is usually .diamond-solid. Low cost
fragile
fabricated from a .diamond-solid.
Requires
flexible polymer, e.g. mechanical
parts
rubber or synthetic .diamond-solid. Blade
can wear
elastomer. out in high
volume
print systems
Separate A separate heater is .diamond-solid. Can be effective
.diamond-solid. Fabrication .diamond-solid. Can be used with
ink boiling provided at the nozzle where other nozzle complexity
many IJ series ink
beater although the normal clearing methods
jets
drop e-ection cannot be used
mechanism does not .diamond-solid. Can be
require it. The heaters implemented at no
do not require additional cost in
individual drive some ink jet
circuits, as many configurations
nozzles can be cleared
simultaneously, and no
imaging is required.
NOZZLE PLATE CONSTRUCTION
Description Advantages Disadvantages
Examples
Electro- A nozzle plate is .diamond-solid. Fabrication
.diamond-solid. High .diamond-solid. Hewlett Packard
formed separately fabricated simplicity temperatures
and Thermal Ink jet
nickel from electroformed pressures are
nickel, and bonded to required to
bond
the print head chip. nozzle plate
.diamond-solid.
Minimum
thickness
constraints
.diamond-solid.
Differential
thermal expansion
Laser Individual nozzle .diamond-solid. No masks
.diamond-solid. Each hole must .diamond-solid. Canon Bubblejet
ablated or holes are ablated by an required be
individually .diamond-solid. 1988 Sercel et
drilled intense UV laser in a .diamond-solid. Can be quite fast
formed al., SPIE, Vol. 998
polymer nozzle plate, which is .diamond-solid. Some control
.diamond-solid. Special Excimer Beam
typically a polymer over nozzle profile equipment
required Applications, pp.
such as polyimide or is possible .diamond-solid. Slow
where there 76-83
polysulphone .diamond-solid. Equipment are
many thousands .diamond-solid. 1993 Watanabe
required is relatively of nozzles
per print et al., U.S. Pat. No.
low cost head
5,208,604
.diamond-solid. May
produce thin
burrs at exit
holes
Silicon A separate nozzle .diamond-solid. High accuracy is
.diamond-solid. Two part .diamond-solid. K. Bean, IEEE
micro- plate is attainable construction
Transactions on
machined micromachined from .diamond-solid. High
cost Electron Devices,
single crystal silicon, .diamond-solid.
Requires Vol. ED-25, No. 10,
and bonded to the precision
alignment 1978, pp 1185-1195
print head wafer. .diamond-solid.
Nozzles may be .diamond-solid. Xerox 1990
clogged by
adhesive Hawkins et al., U.S. Pat. No.
4,899,181
GIass Fine glass capillaries .diamond-solid. No expensive
.diamond-solid. Very small .diamond-solid. 1970 Zoltan U.S. Pat. No.
capillaries are drawn from glass equipment required nozzle sizes
are 3,683,212
tubing. This method .diamond-solid. Simple to make
difficult to form
has been used for single nozzles .diamond-solid. Not
suited for
making individual mass production
nozzles, but is difficult
to use for bulk
manufacturing of print
heads with thousands
of nozzles.
Monolithic, The nozzle plate is .diamond-solid. High accuracy
.diamond-solid. Requires .diamond-solid. Silverbrook, EP
surface deposited as a layer (<1 .mu.m) sacrificial layer
0771 658 A2 and
micro- using standard VLSI .diamond-solid. Monolithic under
the nozzle related patent
machined deposition techniques. .diamond-solid. Low cost
plate to form the applications
using VLSI Nozzles are etched in .diamond-solid. Existing
nozzle chamber .diamond-solid. IJ01, IJ02, IJ04,
Iitho- the nozzle plate using processes can be .diamond-solid.
Surface may be IJ11, IJ12, IJ17,
graphic VLSI lithography and used fragile to the
touch IJ18, IJ20, IJ22,
processes etching.
IJ24, IJ27, IJ28,
IJ29, IJ30, IJ31,
IJ32, IJ33, IJ34,
IJ36, IJ37, IJ38,
IJ39, IJ40, IJ41,
IJ42, IJ43, IJ44
Monolithic, The nozzle plate is a .diamond-solid. High accuracy
.diamond-solid. Requires long .diamond-solid. IJ03, IJ05, IJ06,
etched buried etch stop in the (<1 .mu.m) etch times
IJ07, IJ08, IJ09,
through wafer. Nozzle .diamond-solid. Monolithic
.diamond-solid. Requires a IJ10, IJ13, IJ14,
substrate chambers are etched in .diamond-solid. Low cost
support wafer IJ15, IJ16, IJ19,
the front of the wafer, .diamond-solid. No differential
IJ21, IJ23, IJ25,
and the wafer is expansion
IJ26
thinned from the back
side. Nozzles are then
etched in the etch stop
layer.
No nozzle Various methods have .diamond-solid. No nozzles to
.diamond-solid. Difficult to .diamond-solid. Ricoh 1995
plate been tried to eliminate become clogged control drop
Sekiya et al U.S. Pat. No.
the nozzles entirely, to position
accurately 5,412,413
prevent nozzle .diamond-solid.
Crosstalk .diamond-solid. 1993 Hadimioglu
clogging. These problems
et al EUP 550,192
include thermal bubble
.diamond-solid. 1993 Elrod et al
mechanisms and
EUP 572,220
acoustic lens
mechanisms
Trough Each drop ejector has .diamond-solid. Reduced
.diamond-solid. Drop firing .diamond-solid. IJ35
a trough through manufacturing direction is
sensitive
which a paddle moves. complexity to wicking.
There is no nozzle .diamond-solid. Monolithic
plate.
Nozzle slit The elimination of .diamond-solid. No nozzles to
.diamond-solid. Difficult to .diamond-solid. 1989 Saito et al
instead of nozzle holes and become clogged control drop
U.S. Pat. No. 4,799,668
individual replacement by a slit position
accurately
nozzles encompassing many .diamond-solid.
Crosstalk
actuator positions problems
reduces nozzle
clogging, but increases
crosstalk due to ink
surface waves
DROP EJECTION DIRECTION
Description Advantages Disadvantages
Examples
Edge Ink flow is along the .diamond-solid. Simple
.diamond-solid. Nozzles limited .diamond-solid. Canon Bubble
(`edge surface of the chip, construction to edge
1979 Endo et al GB
shooter`) and ink drops are .diamond-solid. No silicon
.diamond-solid. High resolution patent 2,007,162
ejected from the chip etching required is difficult
.diamond-solid. Xerox heater-in-
edge. .diamond-solid. Good heat
.diamond-solid. Fast color pit 1990 Hawkins et
sinking via substrate printing
requires al U.S. Pat. No. 4,899,181
.diamond-solid. Mechanically one
print head per .diamond-solid. Tone-jet
strong color
.diamond-solid. Ease of chip
handing
Surface Ink flow is along the .diamond-solid. No bulk silicon
.diamond-solid. Maximum ink .diamond-solid. Hewlett-Packard
(`roof surface of the chip, etching required flow is severely
TIJ 1982 Vaught et
shooter`) and ink drops are .diamond-solid. Silicon can make
restricted al U.S. Pat. No. 4,490,728
ejected from the chip an effective heat
.diamond-solid. IJ02, IJ11, IJ12,
surface, normal to the sink
IJ20, IJ22
plane of the chip. .diamond-solid. Mechanical
strength
Through Ink flow is through the .diamond-solid. High ink flow
.diamond-solid. Requires bulk .diamond-solid. Silverbrook, EP
chip, chip, and ink drops are .diamond-solid. Suitable for
silicon etching 0771 658 A2 and
forward ejected from the front pagewidth print
related patent
(`up surface of the chip. heads
applications
shooter`) .diamond-solid. High nozzle
.diamond-solid. IJ04, IJ17, IJ18,
packing density
IJ24, IJ27-IJ45
therefore low
manufacturing cost
Through Ink flow is through the .diamond-solid. High ink flow
.diamond-solid. Requires wafer .diamond-solid. IJ01, IJ03, IJ05,
chip, chip, and ink drops are .diamond-solid. Suitable for
thinning IJ06, IJ07, IJ08,
reverse ejected from the rear pagewidth print .diamond-solid.
Requires special IJ09, IJ10, IJ13,
(`down surface of the chip. heads handling during
IJ14, IJ15, IJ16,
shooter`) .diamond-solid. High nozzle
manufacture IJ19, IJ21, IJ23,
packing density
IJ25, IJ26
therefore low
manufacturing cost
Through Ink flow is through the .diamond-solid. Suitable for
.diamond-solid. Pagewidth print .diamond-solid. Epson Stylus
actuator actuator, which is not piezoelectric print heads
require Tektronix hot
fabricated as part of heads several
thousand melt piezoelectric
the same substrate as connections to
drive ink jets
the drive transistors. circuits
.diamond-solid. Cannot
be
manufactured in
standard CMOS
fabs
.diamond-solid.
Complex
assembly required
INK TYPE
Description Advantages Disadvantages
Examples
Aqueous, Water based ink which .diamond-solid. Environmentally
.diamond-solid. Slow drying .diamond-solid. Most existing ink
dye typically contains: friendly .diamond-solid.
Corrosive jets
water, dye, surfactant, .diamond-solid. No odor
.diamond-solid. Bleeds on paper .diamond-solid. All IJ series ink
humectant, and .diamond-solid. May
jets
biocide. strikethrough
.diamond-solid. Silverbrook, EP
Modern ink dyes have .diamond-solid.
Cockles paper 0771 658 A2 and
high water-fastness,
related patent
light fastness
applications
Aqueous, Water based ink which .diamond-solid. Environmentally
.diamond-solid. Slow drying .diamond-solid. IJ02, IJ04, IJ21,
pigment typically contains: friendly .diamond-solid.
Corrosive IJ26, IJ27, IJ30
water, pigment, .diamond-solid. No odor
.diamond-solid. Pigment may .diamond-solid. Silverbrook, EP
surfactant, humectant, .diamond-solid. Reduced bleed
clog nozzles 0771 658 A2 and
and biocide. .diamond-solid. Reduced wicking
.diamond-solid. Pigment may related patent
Pigments have an .diamond-solid. Reduced clog
actuator applications
advantage in reduced strikethrough mechanisms
.diamond-solid. Piezoelectric ink-
bleed, wicking and .diamond-solid.
Cockles paper jets
strikethrough.
.diamond-solid. Thermal ink jets
(with significant
restrictions)
Methyl MEK is a highly .diamond-solid. Very fast drying
.diamond-solid. Odorous .diamond-solid. All IJ series ink
Ethyl volatile solvent used .diamond-solid. Prints on various
.diamond-solid. Hammable jets
Ketone for industrial printing substrates such as
(MEK) on difficult surfaces metals and plastics
such as aluminum
cans.
Alcohol Alcohol based inks .diamond-solid. Fast drying
.diamond-solid. Slight odor .diamond-solid. All IJ series ink
(ethanol, 2- can be used where the .diamond-solid. Operates at sub-
.diamond-solid. Hammable jets
butanol, printer must operate at freezing
and others) temperatures below temperatures
the freezing point of .diamond-solid. Reduced paper
water. An example of cockle
this is in-camera .diamond-solid. Low cost
consumer
photographic printing.
Phase The ink is solid at .diamond-solid. No drying time-
.diamond-solid. High viscosity .diamond-solid. Tektronix hot
change room temperature, and ink instantly freezes
.diamond-solid. Printed ink melt piezoelectric
(hot melt) is melted in the print on the print medium typically
has a ink jets
head before jetting. .diamond-solid. Almost any print
`waxy` feel .diamond-solid. 1989 Nowak
Hot melt inks are medium can be used .diamond-solid.
Printed pages U.S. Pat. No. 4,820,346
usually wax based, .diamond-solid. No paper cockle may
`block` .diamond-solid. All IJ series ink
with a melting point occurs .diamond-solid. Ink
temperature jets
around 80.degree. C. After .diamond-solid. No wicking
may be above the
jetting the ink freezes occurs curie point
of
almost instantly upon .diamond-solid. No bleed occurs
permanent magnets
contacting the print .diamond-solid. No strikethrough
.diamond-solid. Ink heaters
medium or a transfer occurs consume power
roller. .diamond-solid. Long
warm-up
time
Oil Oil based inks are .diamond-solid. High solubility
.diamond-solid. High viscosity: .diamond-solid. All IJ series ink
extensiveiy used in medium for some this is a
significant jets
offset printing. They dyes limitation for
use in
have advantages in .diamond-solid. Does not cockle ink
jets, which
improved paper usually require a
characteristics on .diamond-solid. Does not wick low
viscosity. Some
paper (especially no through paper short chain and
wicking or cockle). multi-branched
oils
Oil soluble dies and have a
sufficiently
pigments are required. low
viscosity.
.diamond-solid. Slow
drying
Micro- A microemulsion is a .diamond-solid. Stops ink bleed
.diamond-solid. Viscosity higher .diamond-solid. All IJ series ink
emulsion stable, self forming .diamond-solid. High dye than
water jets
emulsion of oil, water, solubiiity .diamond-solid.
Cost is slightly
and surfactant. The .diamond-solid. Water, oil, and
higher than water
characteristic drop size amphiphilic soluble based
ink
is less than 100 nm, dies can be used .diamond-solid. High
surfactant
and is determined by .diamond-solid. Can stabilize
concentration
the preferred curvature pigment required
(around
of the surfactant. suspensions 5%)
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