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United States Patent |
6,190,793
|
Barton
,   et al.
|
February 20, 2001
|
Electrochemical fuel cell stack with an improved compression assembly
Abstract
An electrochemical fuel cell stack with an improved compression assembly
comprises a tension member which is electrically non-conductive and
preferably non-metallic. The tension member can be made from a composite
material which has similar expansion and contraction properties as the
stack materials, thereby reducing undesirable fluctuations in the
compressive force applied to the stack. An improved apparatus for securing
the improved tension member to the rest of the compression assembly is
also provided. Preferred embodiments of an improved compression assembly
employ a collet and wedges to grip the tension member and compress a
resilient member which imparts a tensile force to the tension member and a
compressive force to the fuel cell assemblies. In other embodiments, an
improved compression assembly employs a unitary resilient member and
fastener in combination with a tension member. The improved apparatus is
easier to assemble in high speed manufacturing processes because the
compression assembly can be assembled or installed using the same
machinery which is used to compress the stack in one fixturing because the
compression assembly is assembled by being stacked in essentially the same
direction as the other fuel cell components. An improved method of
assembling a compression assembly for an electrochemical fuel cell stack
is also provided.
Inventors:
|
Barton; Russell H. (New Westminster, CA);
Ronne; Joel A. (Vancouver, CA);
Voss; Henry H. (West Vancouver, CA)
|
Assignee:
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Ballard Power Systems Inc. (Burnaby, CA)
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Appl. No.:
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116178 |
Filed:
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July 15, 1998 |
Current U.S. Class: |
429/34; 429/37 |
Intern'l Class: |
H01M 008/04 |
Field of Search: |
429/34,37,25,159,183
29/623.1
|
References Cited
U.S. Patent Documents
4973531 | Nov., 1990 | Zaima | 429/37.
|
5409787 | Apr., 1995 | Blayner | 429/66.
|
5484666 | Jan., 1996 | Gibb | 429/34.
|
5686200 | Nov., 1997 | Barton et al. | 429/37.
|
5789091 | Aug., 1998 | Wozniczka et al. | 429/12.
|
Foreign Patent Documents |
0329161 | Aug., 1989 | EP.
| |
Other References
Hideo, et al., JP 63-043270, "Fuel Cell Stack Clamping Device," Publication
Date: Feb. 24, 1988 (Abstract Only).
|
Primary Examiner: Chaney; Carol
Assistant Examiner: Ruthkosky; Mark
Attorney, Agent or Firm: McAndrews, Held & Malloy, Ltd.
Parent Case Text
CROSS-REFERENCE TO RELATED APPLICATION
This application relates to and claims priority benefits from U.S.
Provisional Patent Application Ser. No. 60/052,713 filed Jul. 16, 1997,
which is incorporated by reference herein in its entirety.
Claims
What is claimed is:
1. An electrochemical fuel cell stack comprising:
a first end plater;
a second end plater;
a fuel cell assembly interposed between said first and second end plates;
and
a compression assembly associated with said first and second end plates,
said compression assembly comprising:
a resilient member which urges said first end plate towards said second end
plate;
an elongate tension member, with a longitudinal axis, extending between
said first end plate and said second end plate; and
a restraining member which is engaged with said tension member in the
direction of said longitudinal axis of said tension member, wherein said
restraining member cooperates with said tension member to transmit a
tension load to said tension member from said fuel cell stack, wherein
said restraining member is unitary with said resilient member, and wherein
said restraining member comprises a spring arm extending from and unitary
with said resilient member which is deflectable to engage said tension
member.
2. The electrochemical fuel cell stack of claim 1, wherein said restraining
member comprises a pair of spring arms which extend towards each other,
and said first and second spring arms are engaged with said tension member
by inserting said tension member therebetween.
3. The electrochemical fuel cell stack of claim 2 wherein tension member
has a textured surface for improving gripping between contact surfaces of
said spring arms and said tension member.
4. An electrochemical fuel cell stack comprising:
a first end plate;
a second end plate;
a fuel cell assembly interposed between said first and second end plates;
and
a compression assembly associated with said first and second end plates,
said compression assembly comprising:
a resilient member which urges said first end plate towards said second end
plate;
an elongate tension member, with a longitudinal axis, extending between
said first end plate and said second end plate; and
a restraining member which is engaged with said tension member in the
direction of said longitudinal axis of said tension member, wherein said
restraining member cooperates with said tension member to transmit a
tension load to said tension member from said fuel cell stack and wherein
said restraining member comprises a collet through which said tension
member is inserted and a wedge inserted between said tension member and
said collet, said wedge cooperating with said collet to grip said tension
member.
5. The electrochemical fuel cell stack of claim 4 wherein a surface of said
wedge is textured for improving said grip between said tension member and
said wedge.
6. The electrochemical fuel cell stack of claim 5 wherein said textured
surface comprises lateral ridges or teeth.
7. The electrochemical fuel cell stack of claim 4 wherein a surface of said
tension member, which contacts said wedge, is textured for improving said
grip between said tension member and said wedge.
8. The electrochemical fuel cell stack of claim 4 wherein opposing surfaces
of said wedge and said tension member each have lateral ridges or teeth
which cooperate with each other for improved gripping.
9. The electrochemical fuel cell stack of claim 8 wherein said lateral
ridges or teeth interlock and operate as a ratchet.
10. The electrochemical fuel cell stack of claim 3 wherein said resilient
member is a spring plate or a leaf spring.
11. The electrochemical fuel cell stack of claim 3 wherein said resilient
member is a resilient elastomer.
12. The electrochemical fuel cell stack of claim 3 wherein said tension
member is electrically non-conductive.
13. The electrochemical fuel cell stack of claim 6 wherein said tension
member is nonmetallic.
14. The electrochemical fuel cell stack of claim 13 wherein said tension
member is made from a composite material.
15. The electrochemical fuel cell stack of claim 14 wherein said composite
material is pultruded fiberglass.
16. The electrochemical fuel cell stack of claim 14 wherein said composite
material is laminated.
17. The electrochemical fuel cell stack of claim 12 wherein said tension
member comprises an electrically conductive core and an electrically
insulating outer layer.
18. The electrochemical fuel cell stack of claim 17 wherein said
electrically insulating layer is a coating which is bonded to said core.
19. The electrochemical fuel cell stack of claim 17 wherein said
electrically conductive core is a metal bar or rod.
20. A method of assembling a compression assembly for an electrochemical
fuel cell stack comprising at least one fuel cell assembly interposed
between a first end plate and a second end plate, said method comprising
the steps of:
(a) extending a longitudinal axis of a tension member through a first end
plate and a second end plate of said fuel cell stack;
(b) applying a compressive force to said fuel cell stack in a direction
parallel to said longitudinal axis, wherein said compressive force engages
a restraining member with said tension member, and compresses a resilient
member until it is in equilibrium with said compressive force; and
(c) placing a resilient member over an end of said tension member, such
that a through opening in said resilient member receives said end of said
tension member, and
the step of engaging said restraining member comprises employing said
compressive force to insert at least one wedge into a gap between said
tension member and said resilient member.
21. The method of claim 20 wherein said resilient member is a spring plate.
22. The method of claim 21 wherein said spring plate is a plurality of
spring plates.
23. The method of claim 20 wherein said wedge has a flange which limits
movement of said resilient member along the surface of said wedge.
24. The method of claim 20 wherein said resilient member is a disc spring.
25. The method of claim 20 further comprising the step of applying an
adhesive between said wedge and said tension member.
26. The method of claim 20 further comprising a second compression assembly
which is assembled according to said steps in claim 20 wherein said two
compression assemblies are each associated with an opposite end of said
tension member.
27. A method of assembling a compression assembly for an electrochemical
fuel cell stack comprising at least one fuel cell assembly interposed
between a first end plate and a second end plate, said method comprising
the steps of:
(a) extending a longitudinal axis of a tension member through a first end
plate and a second end plate of said fuel cell stack;
(b) applying a compressive force to said fuel cell stack in a direction
parallel to said longitudinal axis, wherein said compressive force engages
a restraining member with said tension member, and compresses a resilient
member until it is in equilibrium with said compressive force; and
(c) placing a resilient member over an end of said tension member, such
that a through opening in said resilient member receives said end of said
tension member;
(d) placing a collet over an end of said tension member and extending said
tension member through said collet; and
the step of engaging said restraining member comprises employing said
compressive force to insert at least one wedge into a gap between said
tension member and said collet until said resilient member is compressed
and in equilibrium with said compressive force.
28. The method of claim 27 wherein said resilient member is a spring plate.
29. The method of claim 28 wherein said spring plate is a plurality of
spring plates.
30. The method of claim 27 wherein said resilient member is a disc spring.
31. The method of claim 27 wherein said wedge has a textured surface for
gripping said tension member.
32. The method of claim 27 further comprising a second compression assembly
which is assembled according to said steps in claim 26 wherein said two
compression assemblies are each associated with an opposite end of said
tension member.
33. A method of assembling a compression assembly for an electrochemical
fuel cell stack comprising at least one fuel cell assembly interposed
between a first end plate and a second end plate, said method comprising
the steps of:
(a) extending a longitudinal axis of a tension member through a first end
plate and a second end plate of said fuel cell stack;
(b) applying a compressive force to said fuel cell stack in a direction
parallel to said longitudinal axis, wherein said compressive force engages
a restraining member with said tension member, and compresses a resilient
member until it is in equilibrium with said compressive force; and
the step of engaging said restraining member comprises inserting an end of
said tension member through an opening in said resilient member and
engaging said tension member through an opening in said resilient member
and engaging said tension member with said resilient member by deflecting
spring arms which are unitary with said resilient member.
34. The method of claim 33 wherein said resilient member is a spring plate.
35. The method of claim 33 further comprising a second compression assembly
which is assembled according to the same steps as the compression assembly
of claim 44 wherein said two compression assemblies are each associated
with an opposite end of said tension member.
Description
TECHNICAL FIELD
The present invention relates to electrochemical fuel cells. In particular,
the invention provides a fuel cell stack with an improved compression
assembly for facilitating high speed manufacturability.
BACKGROUND
Electrochemical fuel cells convert reactants, namely fuel and oxidant fluid
streams, to generate electric power and reaction products. Solid polymer
electrochemical fuel cells generally employ a membrane electrode assembly
("MEA") consisting of a solid polymer electrolyte or ion exchange membrane
disposed between two electrode layers comprising porous, electrically
conductive sheet material. An electrocatalyst is disposed at each
membrane/electrode layer interface to induce the desired electrochemical
reaction. The location of the electrocatalyst generally defines the
electrochemically active area of the MEA.
In typical fuel cells, the MEA is disposed between two electrically
conductive separator plates or fluid flow field plates. Fluid flow field
plates have at least one flow passage formed therein to direct the fuel
and oxidant fluid streams to the respective electrode layers, namely the
anode on the fuel side and the cathode on the oxidant side. In a single
cell arrangement, fluid flow field plates are provided on each of the
anode and cathode sides. The plates act as current collectors and provide
support for the electrodes.
Two or more fuel cells can be connected together, generally in series, but
sometimes in parallel, to increase the overall power output of the
assembly. In series arrangements, one side of a given plate serves as an
anode plate for one cell and the other side of the plate can serve as the
cathode plate for the adjacent cell. Such a series connected multiple fuel
cell arrangement is referred to as a fuel cell stack.
The stack typically includes inlet ports and manifolds for directing the
fuel and the oxidant to the anode and cathode flow field passages
respectively. The stack often also includes an inlet port and manifold for
directing a coolant fluid to interior passages within the stack to absorb
heat generated by the exothermic reaction in the fuel cells. The stack
also generally includes exhaust manifolds and outlet ports for expelling
the unreacted fuel and oxidant gases, as well as an exhaust manifold and
outlet port for the coolant exhaust stream exiting the stack.
The fuel fluid stream typically comprises hydrogen. For example, the fuel
fluid stream may be substantially pure hydrogen or a gas comprising
gaseous hydrogen such as a reformate stream. Alternatively, a liquid fuel
stream such as aqueous methanol may be used. The oxidant fluid stream
which is supplied to the cathode typically comprises oxygen, such as, for
example, air or another dilute oxygen stream.
It is desirable to seal reactant fluid stream passages in fuel cell stack
to prevent leaks or inter-mixing of the fuel and oxidant fluid streams.
Fuel cell stacks typically employ fluid tight resilient seals, such as
elastomeric gaskets between the separator plates and membranes. Such seals
typically circumscribe the manifolds and the electrochemically active
area. Sealing is effected by applying a compressive force to the resilient
gasket seals.
Fuel cell stacks are compressed to enhance sealing and electrical contact
between the surfaces of the separator plates and the MEAs, and sealing
between adjacent fuel cell stack components. In conventional fuel cell
stacks, the fuel cell stacks are typically compressed and maintained in
their assembled state between a pair of end plates by one or more metal
tie rods or tension members. The tie rods typically extend through holes
formed in the stack end plates, and have associated nuts or other
fastening means to secure them in the stack assembly. The tie rods may be
external, that is, not extending through the fuel cell plates and MEAs,
however, external tie rods can add significantly to the stack weight and
volume. It is generally preferable to use one or more internal tie rods
which extend between the stack end plates through openings in the fuel
cell plates and MEAs as described in U.S. Pat. No. 5,484,666. Typically
resilient members are utilized to cooperate with the tie rods and end
plates to urge the two end plates towards each other to compress the fuel
cell stack.
The resilient members accommodate changes in stack length caused by, for
example, thermal or pressure induced expansion and contraction, and/or
deformation. That is, the resilient member expands to maintain a
compressive load on the fuel cell assemblies if the thickness of the fuel
cell assemblies shrinks. The resilient member may also compress to
accommodate increases in the thickness of the fuel cell assemblies.
Preferably, the resilient member is selected to provide a substantially
uniform compressive force to the fuel cell assemblies, within an
anticipated expansion and contraction limits for an operating fuel cell.
The resilient member may comprise mechanical springs, or a hydraulic or
pneumatic piston, or spring plates, or pressure pads, or other resilient
compressive devices or mechanisms. For example, one or more spring plates
may be layered in the stack. The resilient member cooperates with the
tension member to urge the end plates toward each other, thereby applying
a compressive load to the fuel cell assemblies and a tensile load to the
tension member.
Conventional tension members typically have a mechanism for receiving a
tensile load which is transferred to the tension member from the
compression assembly. For example, the mechanism may be a protrusion or
flange which typically bears against the resilient member or end plate to
essentially prevent the end plates from moving apart. Conventionally, the
ends of the tension member are threaded to receive a nut or other fastener
which provides a bearing surface for receiving a tensile load. An
advantage of a threaded connection is that the nut may be tightened to
precisely adjust the tensile load applied to the tension member. However,
there are several disadvantages of threaded connections, including the
susceptibility of threaded ends to damage, the time required for assembly,
and the production costs for high speed manufacturing processes. Threaded
ends may be damaged, for example, by mishandling or by being stripped by
the nuts during assembly (e.g. from misalignment or over-tightening).
During assembly, to prevent the nuts from being over-tightened it may be
necessary to monitor or limit the torque applied to the nuts.
A particular disadvantage with metallic tension members, and especially
internal tension members, is that they need to be electrically insulated
from the fuel cells in the stack to prevent the tension members from
causing a short circuit. Metallic tension members are typically used with
an electrically insulating sleeve. In addition to such sleeves being an
additional component, a problem with sleeves is that repeated temperature
cycles, the humid environment within the fuel cell assemblies, or other
characteristics of the operating environment within the fuel cell stack
may cause a sleeve to develop cracks or holes.
Still another disadvantage of metallic tension members is that they are
also a potential source of metal ion contamination which can adversely
affect the membrane electrolyte and/or electrocatalyst in the MEAs. For
example, contamination may cause the electrocatalyst to become poisoned.
Corrective action for electrocatalyst poisoning typically requires the
fuel cell to be shut down. For electrocatalyst which is severely poisoned,
it may be necessary to dismantle the fuel cell stack and replace the MEAs
and the components which caused the contamination. Furthermore, metal ion
contamination may be particularly extensive if the source of the
contamination is internal tension members which extend through the
interior of the fuel cell stack. Such tension members typically extend
through the reactant fluid manifolds. Thus metal ions originating from a
faulty metallic tension members can be transported to all of the interior
fluid passages which are fluidly connected to the reactant manifold,
including fluid passages leading to the electrocatalyst layer.
Accordingly, there is a need for an improved compression assembly which
mitigates some or all of the aforementioned disadvantages which are
associated with conventional compression assemblies which employ
electrically conductive metallic tension members.
SUMMARY OF THE INVENTION
An electrochemical fuel cell stack with an improved compression assembly
for high speed manufacturing processes is provided, wherein the fuel cell
stack comprises:
a first end plate;
a second end plate;
at least one fuel cell assembly interposed between the first and second end
plates; and
a compression assembly associated with the first and second end plates, the
compression assembly comprising:
a resilient member which urges the first end plate towards the second end
plate;
an elongate tension member with a longitudinal axis extending between the
first end plate and the second end plate; and
a restraining member which is linearly engaged with the tension member in
the direction of the longitudinal axis of the tension member,
wherein the restraining member cooperates with the tension member to
transmit a tension load to the tension member from the fuel cell stack.
The resilient member preferably comprises a spring plate or leaf spring, or
a plurality of leaf springs layered on top of each other. Alternatively,
the resilient member may comprise another type of resilient member, known
to those skilled in the art, such as a disc spring, a coil spring, or a
resilient elastomer.
In a preferred embodiment the restraining member is unitary with the
resilient member. The unitary restraining member is preferably a spring
arm which extends from an opening in the resilient member which receives
the tension member. The spring arm is deflected by the tension member when
the tension member is inserted through the opening in the resilient
member. The spring arm is disposed to an undeflected position; thus the
deflected spring arm exerts a force onto the tension member which grips
the tension member, thereby engaging the restraining member with the
tension member.
Preferably the spring arm is a pair of spring arms which extend towards
each other from opposite sides of the opening in the resilient member.
Both first and second spring arms extend into the opening in the resilient
member. The tension member is engaged between the first and second spring
arms by inserting the tension member through the opening in the resilient
member. To improve the grip of the restraining member on the tension
member, the tension member may be provided with a textured surface.
In another preferred embodiment, the restraining member comprises a collet
through which the tension member is inserted and a wedge which is inserted
between the tension member and the collet. The wedge cooperates with the
collet to grip the tension member. To improve the grip between the wedge
and the tension member, the surfaces of the wedge and/or the surfaces of
the tension member may be textured. The textured surface may comprise
lateral ridges or teeth. The lateral ridges or teeth may be shaped to
cooperate with each other for improved gripping. In one embodiment, the
teeth may be angled to engage operate as a ratchet.
In preferred embodiments, the resilient member is located immediately
between one of the first and second end plates and a restraining member.
The spring can thus expand or contract in response to corresponding
contraction or expansion of the fuel cell components. In other
embodiments, the order in which the resilient member(s), end plates, and
restraining member(s) are stacked may be changed. For example, the
resilient member may be located between the end plates with the
restraining member next to one of the end plates. However, a disadvantage
of this embodiment is that the restraining member can not be made unitary
with the resilient member and an additional plate may be required next to
the resilient member to evenly distribute the compressive forces over the
cross-sectional area of the stack. Alternatively, other fuel cell
components may be interposed between the resilient member and the end
plate or the restraining member. For example, a compression plate could be
employed instead of a collet between the restraining member and the
resilient member.
In particular preferred embodiments the tension member is electrically
non-conductive. In some fuel cell stacks the tension members extend
through openings in the fuel assemblies. An advantage of electrically
non-conductive tension members is that an insulating sleeve is not
required to electrically insulate it from the fuel cell assemblies.
The tension member is also preferably non-metallic. An advantage of a
non-metallic tension member is that it is not a source of metal ions which
may contaminate the fuel cell assemblies. The tension member may be made
from a composite material, such as, for example, one which comprises a
bonding agent and a plurality of reinforcing fibers. The fibers may be
randomly arranged, but preferably the fibers are oriented to improve the
tensile strength of the tension member. In one embodiment the composite
material has a laminated structure. An example of a preferred material is
pultruded fiberglass. Other electrically non-conductive fibers may be
used, such as sapphire fibers or Kevlar.TM. fibers. Electrically
conductive fibers such as carbon fibers may be used in a non-conductive
matrix such as epoxy to produce an electrically non-conductive composite.
Alternatively, the tension member may comprise an electrically conductive
core and an electrically insulating integral outer layer. For example, an
electrically insulating coating may be bonded to the core. The coating is
preferably impermeable to reactant and cooling fluids and compatible with
the environment within the fuel cell stack. Coatings with such properties
may be used to isolate metal cores to reduce the risk of metal ion
contamination.
Also provided is an embodiment of an improved compression assembly for an
electrochemical fuel cell stack comprising a resilient member which urges
the first end plate towards the second end plate, a substantially
electrically non-conductive tension member extending between the first end
plate and the second end plate, and a restraining member which cooperates
with the tension member to transmit a tension load to the tension member
from the resilient member. In preferred embodiments, the tension member is
non-metallic. The tension member may be a composite material such as
pultruded fiberglass. Fiberglass and like composite materials also have
advantageous structural characteristics. For example, pultruded fiberglass
is a high strength lightweight material which is stable under tension
loading. Accordingly, the weight of a fuel cell stack can be reduced by
substituting fiberglass tension members for conventional metal ones.
Fiberglass is also a material which is compatible and stable in a wet,
acidic environment, such as the operating environment within a solid
polymer fuel cell. Furthermore, because fiberglass is a composite
material, component materials can be selected which have thermal expansion
properties similar to the properties of the fuel cell stack. Accordingly,
it is possible to make a compression assembly which will apply a
consistent compressive force to a fuel cell stack without being influenced
by changes in the temperature within the fuel cell stack.
A method is provided for assembling a compression assembly for an
electrochemical fuel cell stack comprising at least one fuel cell
assembly. This method employs wedges and comprises the steps of:
(a) extending a longitudinal axis of a tension member through a first end
plate and a second end plate of the fuel cell stack;
(b) placing a resilient member over an end of the tension member, such that
a through opening in the resilient member receives the end of the tension
member;
(c) applying an external compressive force to the fuel cell stack in a
direction parallel to the longitudinal axis; and
(d) employing the external compressive force to insert at least one wedge
into a gap between the tension member and the resilient member until the
resilient member is compressed and in equilibrium with the compressive
force.
After the external compressive force is removed, the resilient member
provides a force to hold the fuel cell assemblies in compression for
compressing fluid seals and pressing the stack components together for
improved electrical and thermal conductivity.
To limit movement of the resilient member along the contact surface of the
wedge, the wedge may employ a flange which has a depth greater than the
largest gap distance between the tension member and the resilient member.
Another preferred method is provided for assembling a compression assembly
for an electrochemical fuel cell stack comprising at least one fuel cell
assembly. This method employs collets and wedges and comprises the
following steps of:
(a) extending a longitudinal axis of a tension member through an opening in
a first end plate and an opening in a second end plate of the fuel cell
stack;
(b) placing a resilient member over an end of the tension member, such that
a through opening in the resilient member receives the end of the tension
member;
(c) placing a collet over an end of the tension member and extending the
tension member through the collet;
(d) applying a compressive force to the fuel cell stack in a direction
parallel to the longitudinal axis; and
(e) employing the compressive force to insert at least one wedge into a gap
between the tension member and the collet until the resilient member is
compressed and in equilibrium with the compressive force.
The wedge preferably has a textured surface for gripping the tension
member. According to this method, the wedge is inserted between the collet
and the tension member instead of between the spring plate and tension
member. Preferably the resilient member provides an opening which is sized
to receive the collet. The collet provides a through opening which is
large enough to accommodate the tension member and the narrow end of the
wedge. The resilient member does serve as part of the restraining member.
Accordingly, in one embodiment, the resilient member may be located apart
from the collet (e.g. within the fuel cell stack). In this embodiment, the
collet may bear against one of the end plates with the wedge inserted into
the gap between the collet and the tension member.
Another embodiment of the method of assembling a compression assembly for
an electrochemical fuel cell stack comprising at least one fuel cell
assembly comprises a unitary resilient member and restraining member. This
method comprises the following steps:
(a) extending a longitudinal axis of a tension member through a first end
plate and a second end plate of the fuel cell stack;
(b) inserting an end of the tension member through an opening in the
resilient member and engaging the tension member with the resilient member
by deflecting spring arms which are unitary with the resilient member; and
(c) applying a compressive force to the fuel cell stack in a direction
parallel to the longitudinal axis, wherein the compressive force
compresses the resilient member until it is in equilibrium with the
compressive force.
In all of the described methods, the resilient member is preferably a
spring plate or a plurality of stacked spring plates. However, the
resilient member may also another type of resilient member, such as a disc
spring or a plurality of disc springs.
Any of the above described methods may further comprise employing a second
compression assembly wherein both first and second compression assemblies
are assembled according to the same steps. Each one of the first and
second compression assemblies is associated with an opposite end of the
elongate tension member. Similarly, a plurality of tension members may be
simultaneously engaged with respective compression assemblies. The
preferred number of tension members and compression assemblies is
dependent upon the size of the fuel cell stack.
To further improve the grip between the restraining member and the tension
member in any of the above embodiments of the improved compression
assembly, an adhesive may be applied to surfaces of one or both of the
restraining member and the tension member.
In all of the embodiments of the method, the restraining member is
installed employing a compressive force in the same direction in which a
compressive force is used to compress the fuel stack during the assembly
process. That is, the disclosed restraining members are positioned and
linearly engaged with the tension member in response to an applied linear
force. The linear force is applied in a direction parallel to the
longitudinal axis of the tension member. For example, for an embodiment
comprising a resilient member with an integral restraining member
comprising a pair of opposing spring arms, the resilient member is
positioned on the tension member by a linear compressive force, and the
integral restraining member is linearly engaged with the tension member by
the deflection of spring arms. The spring arms are deflected in response
to the linear insertion of the tension member between the opposing the
spring arms which is caused by the linear compressive force. Similarly,
for an embodiment of the restraining member which comprises wedges, the
restraining member is linearly engaged in response to a linear compressive
force which inserts the wedges into a gap between the tension member and
another component such as a collet or the face of a resilient member. The
linear force which inserts the wedges into the gap causes the wedges grip
the tension member, thereby linearly engaging the restraining member with
the tension member. The clamping forces applied by the restraining member
to the tension member prevent the restraining member from releasing its
grip on the tension member after the external compressive force is
removed. That is, after the external compressive force is removed, the
restraining member maintains a fixed position relative to the tension
member. Thus the restraining member transmits loads between the fuel cell
stack and the tension member, keeping the resilient member in compression
and the tension member in tension.
Linear engagement of the restraining member is an advantage over known
restraining members and methods of installing them. For example, tie rods
and nuts require separate steps and machinery to apply a linear force to
compress the fuel cell stack, and a rotational force to tighten the nuts
to the desired torque.
BRIEF DESCRIPTION OF THE DRAWINGS
The advantages, nature and additional features of the invention will become
more apparent from the following description, together with the
accompanying drawings of embodiments of the invention, in which:
FIG. 1 is a partially exploded perspective view of an electrochemical solid
polymer fuel cell stack with a compression assembly comprising a tension
member and a spring plate acting as a unitary resilient restraining member
and spring arms;
FIG. 2 is partially exploded perspective view of an end plate, tension
member, and a compression assembly comprising a collet and wedges;
FIGS. 3A-3F are partial section views of six embodiments of a compression
assembly;
FIGS. 4A-4D depict four embodiments of tension members and associated
wedges;
and
FIGS. 5A-5B schematically illustrate the sequential steps which comprise
two embodiments of the method of the invention.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
FIG. 1 illustrates a solid polymer electrochemical fuel cell stack 10,
including a pair of end plate assemblies 20 and 30, and a plurality of
stacked fuel cell assemblies 50, each comprising an MEA 100, and a pair of
flow field plates 200. An elongate tension member 60 extends between and
through end plate assemblies 20 and 30 to retain and secure stack 10 in
its assembled state. Tension member 60 is preferably rigid and
electrically non-conductive. Spring plate 70 with integral spring arms 80
grip each end of tension member 60 to apply a compressive force to fuel
cell assemblies 50 of stack 10 and act as restraining members.
Fluid reactant streams are supplied to and exhausted from internal
manifolds and passages in stack 10 via inlet and outlet ports 40 in end
plate assemblies 20 and 30. Aligned openings 105 and 205 in MEAs 100 and
flow field plates 200, respectively, form reactant manifolds extending
through stack 10.
In the illustrated embodiment, perimeter seal 110 is provided around the
outer edge of MEA 100. Manifold seals 120 circumscribe manifold openings
105. When stack 10 is secured in its assembled, compressed state, seals
110 and 120 cooperate with the adjacent pair of plates 200 to fluidly
isolate fuel and oxidant reactant streams in internal reactant manifolds
and passages, thereby isolating one reactant stream from the other and
preventing the reactant streams from leaking from stack 10.
As illustrated in FIG. 1, each MEA 100 is positioned between the active
surfaces of two flow field plates 200. Each flow field plate 200 has flow
field channels 210 on the active surface thereof (which contacts the MEA)
for distributing fuel or oxidant fluid streams to the active area of the
MEA 100. In the embodiment illustrated in FIG. 1, flow field channels 210
are fluidly connected to manifold openings 205 in plate 200 via
supply/exhaust channels 220 (partially shown) located on the non-active
surface of flow field plate 200 and ports 230 extending through plate 200.
In the illustrated embodiment, flow field plates 200 have a plurality of
open-faced parallel channels 250 formed in the non-active surface thereof.
Channels 250 on adjacent pairs of plates 200 cooperate to form passages
extending through stack 10, through which a coolant stream, such as air,
may be directed.
In preferred embodiments, tension member 60 is made from a rigid
non-metallic (preferably non-electrically conductive) material. Tension
member 60 must be strong along its longitudinal axis but it need not be as
strong in the lateral direction since tension member 60 is protected from
lateral forces by being located internally inside fuel cell stack 10.
Pultruded fiberglass is an example of a suitable material for tension
member 60. In FIG. 1, tension member 60 has a generally rectangular cross
section with rounded corners. Tension member 60 can be fabricated with any
cross-sectional shape. A rectangular shape, however, provides a wide flat
surface for contacting clamping mechanism 80 which is part of spring plate
70.
In the embodiment depicted in FIG. 1, spring plate 70 is a bowed metal
plate. Integral spring arms 80 comprise metal tabs or flaps flanking a
central opening hole in spring plate 70. The tabs are angled away from the
crest of bowed spring plate 70. In the preferred embodiment, for one
tension member 60, two spring plates 70 with integral spring arms 80 are
preferably used, one on each end of tension member 60 to exert a uniform
compressive force on assembled fuel cell stack 10. Spring plate 70 is
adapted to fit over tension member 60. Clamping mechanism 80 allows spring
plate 70 to easily slide down tension member 60 in one direction, while
resisting movement in the other direction. This type of integral spring
plate 70 and clamping mechanism 80 facilitates assembly of fuel cell stack
10. An external compressive force is applied to fuel cell stack 10 through
spring plate 70. During assembly an external compressive force is applied
to push spring plate 70 down tension member 60 until a predetermined
compressive force is applied to fuel cell assemblies 50 of stack 10. The
external compressive force is released and spring plate 70 maintains a
compressive loading on fuel cell stack 10. Integral spring arms 80 prevent
the compressive force from being released by holding spring plate 70 in
position.
FIG. 2 shows an end plate 300 of a fuel cell stack (not shown) which
employs two compression assemblies 310, 320. The preferred number and
configuration of the compression assemblies depends upon the size and
shape of the stack components. Compression assembly 310 is shown in an
assembled state and compression assembly 320 is shown in exploded view.
With reference to compression assembly 320, tension member 330 protrudes
through an opening in end plate 300 and extends through a series of spring
plates or leaf springs 340 and collet 350. In the illustrated embodiment,
the compression assemblies 310 and 320 each employ three spring plates 340
as a resilient member. Tension member 330 is shown as a flat bar with a
generally rectangular cross-section with beveled corners. Spring plates
340 provide a resilient compressive force to the fuel cell stack by
cooperating with rigid tension member 330 and the restraining member which
compress spring plates 340 against end plate 300.
As shown in FIG. 2, wedges 360 have substantially flat contact surfaces
which cooperate with opposing flat surfaces of tension member 330. The
illustrated wedges 360 employ ridges or teeth 370 to improve the grip on
tension member 330. The outward facing surface of wedges 360 are conical
and convex to cooperate with the conical and concave shape of the opening
in collet 350 which receives wedges 360. The shape of the contact surfaces
of wedges 360 may be different depending upon the shape of the cooperating
surfaces of tension member 330 and the shape of the opening in collet 350.
For example, if tension member 330 is a cylindrical bar, wedges 360 may
have contact surfaces which are concave to cooperate with the cylindrical
shape of tension member 330.
The thin edge of wedge 360 is the leading edge 380 which is pushed into the
gap between tension member 330 and collet 350. The thick ends of wedges
360 are the ends which are visible in the assembled compression assembly
310.
In the preferred embodiment, the receiving surface of the collet opening is
tapered to the same angle as wedges 360 to increase the contact area
between wedges 360 and tension member 330 and collet 350. In the preferred
embodiment, collet 350 and wedges 360 are shaped and sized so that tension
member 330 is tightly gripped between wedges 360 when wedges 360 protrude
slightly from the face of collet 350.
FIG. 3A is a partial section view of a fuel cell stack illustrating a
preferred embodiment of a compression assembly (similar to the compression
assembly of FIG. 2). FIG. 3a shows an end plate 400a, with an end of a
tension member 405a extending therethrough with wedges 410 gripping
tension member 405a. Collet 420 is seated in an opening in spring plate
415a. The opening in collet 420 is larger than the thickness of tension
member 405a so that a gap is provided for receiving wedges 410. The
interior surface of collet 420 are preferably angled in relation to the
opposing surfaces of tension member 405a to provide a larger contact
surface between wedge 410 and collet 420.
FIG. 3B illustrates an alternative embodiment which does not employ a
collet.
Tension member 405b is gripped between wedges 430. Wedges 430 engage
tension member 405b and spring plates 415b directly. Wedges 410 may have
unitary flanges 425 for providing an enlarged contact surface with spring
plates 415b. Flanges 425 may also ensure that wedges 430 are not pushed
entirely through the opening in spring plate 415b. Edges 432 of the spring
plate opening may optionally be folded down at an angle which cooperates
with the angled surface of wedge.
FIG. 3C depicts an embodiment of a compression assembly which employs only
one wedge 435. Spring plate 415c has an opening for receiving tension
member 405c and wedge 435. Spring plate 415c has folded edges 440 facing
the contacting surface of tension member 405c. Folded edges 440 provide a
larger surface for engaging tension member 405c and wedge 435.
FIG. 3D shows an embodiment of a compression assembly which uses disc
springs 445 instead of spring plates. Disc springs 445 are compressed
between collet 450 and end plate 400d. Wedges 455 are pushed into contact
with tension member 405d and collet 450 to grip tension member 455 and to
prevent collet 450 from sliding off the end of tension member 405d. In
alternative embodiments of this arrangement, coil springs or a resilient
elastomer could be substituted for disc springs 445.
FIG. 3E shows another preferred embodiment of a compression assembly
(similar to that shown in FIG. 1). Spring plate 415e has unitary spring
arms 470 which are disposed toward an undeflected position. When spring
arms 470 are deflected as they are in FIG. 3E, they apply a clamping force
to grip tension member 405e.
FIG. 3F illustrates how a single spring arm 475 may be used to grip tension
member 405f. Edge 480 of spring plate 415f is optionally bent to provide a
larger surface for bearing against tension member 405f. Tension member
405f is pressed into contact with edge 480 by deflected spring arm 475.
FIG. 4A is a side view of the end of a laminated tension member 500 and two
wedges 505. Laminated tension member 500 has opposing flat surfaces for
contacting the adjacent substantially flat surfaces of wedges 505. In the
embodiment illustrated by FIG. 4A, wedges 505 have teeth 510 on the
contact surfaces which grip tension member 500.
FIG. 4B is a side view of a tension member 515 which has ridges 520 which
protrude from the flat surface of tension member 515. Ridges 520 are
angled to receive interlocking ridges 525 on wedges 530. The ridges are
angled to operate in a ratcheting fashion which facilitates installation
of wedges 530, while resisting the removal of same.
FIG. 4C is a side view of tension member 535 similar to tension member 515,
except that instead of protruding ridges 520, tension member 535 employs
grooves or recesses which cooperate with the angled ridges 540 of wedges
545.
FIG. 4D is a perspective view of the end of a cylindrical tension member
550 with two wedges 555. Wedges 555 have a concave surfaces which
cooperate with the cylindrical exterior surface of tension member 550 to
grip tension member 550 therebetween.
With reference to FIGS. 5A and 5B, embodiments of the method are
illustrated by diagrams which depict sequential steps for two methods of
assembling a fuel cell stack using an improved compression assembly as
disclosed by the present invention. In particular, FIGS. 5A and 5B
illustrate method comprising the steps of:
(a) extending a longitudinal axis of a tension member through a first end
plate and a second end plate of the fuel cell stack; and
(b) applying a compressive force to the fuel cell stack in a direction
parallel to the longitudinal axis, wherein the compressive force linearly
engages a restraining member with the tension member, and compresses a
resilient member until it is in equilibrium with the compressive force.
In FIG. 5A, diagram I depicts a fuel cell stack 560 comprising fuel cell
assemblies interposed between end plates 565. At this stage, fuel cell
stack 560 has not been compressed, but internal tension member 570 has
been inserted through an opening which extends through the interior of
fuel cell stack 560 and end plates 565 . The opposite ends of tension
member 570 protrude from end plates 565. Diagram II depicts spring plates
575 positioned next to each end plate with an external compression device
580 bearing against spring plates 575. Diagram III depicts fuel cell stack
560 after being compressed by a linear compressive force applied in the
direction of the longitudinal axis of tension member 570 (as indicated by
the arrows). The magnitude of compression illustrated by Diagram III is
exaggerated for illustrative purposes. Diagram III shows how spring plates
575 have been deflected and spring arms 585 have engaged tension member
570. Diagram IV depicts the removal of external compression device 580.
Spring arms 585 are unitary with spring plate 575. The linear compressive
force linearly engages spring arms 585 which are deflected in response to
the insertion of tension member 570 between spring arms 585, which is
caused by the linear compressive force.
With reference now to FIG. 5B, diagram I depicts a fuel cell stack 600
comprising fuel cell assemblies interposed between end plates 605. At this
stage fuel cell stack 600 is not compressed, but internal tension member
610 has been inserted through an opening which extends through the
interior of fuel cell stack 600 and end plates 605. The opposite ends of
tension member 610 protrude from end plates 605. Diagram II depicts spring
plates 615 positioned next to each end plate. In diagram III collets 620
have been inserted into openings provided in spring plates 615. Flanges on
collets 620 are seated against spring plates 615. An opening in collet 620
is aligned with tension member 610. In the step illustrated by diagram IV,
an external compressive device 625 pushes against the compression assembly
in the longitudinal direction of the tension member (as indicated by
arrows in Diagram IV). External compressive device 625 compresses fuel
cell stack 600, causing tension member 610 to protrude through collets
620. With reference to diagram V, once fuel cell stack 600 is compressed,
member 630 of external compression device 625 continues to apply a linear
compressive force in the longitudinal direction of the tension member to
insert wedges 635 into respective gaps between collet 620 and tension
member 610. Wedges 635 are inserted until they fill the available gaps
such that linear forces cause the wedge surfaces in contact with tension
member 610 to grip onto tension member 610, thereby linearly engaging the
compression assembly with tension member 610. Once the compression
assembly is positioned so that the external compressive force and
resilient member 615 are in equilibrium, external compression device 625
can be removed. Diagram V depicts fuel cell stack 600 after being
compressed with only the thick ends of wedges 635 protruding from collet
620. Diagram V also shows how spring plates 615 have been deflected. The
steps depicted by diagrams IV and V have been separated for illustrative
purposes. Alternatively, external compression device 625 could designed to
combine these steps such that the application of one external compressive
force compresses stack 600 and resilient member 615 while also positioning
and engaging wedges 635.
As will be apparent to those skilled in the art in the light of the
foregoing disclosure, many alterations and modifications are possible in
the practice of this invention without departing from the spirit or scope
thereof Accordingly, the scope of the invention is to be construed in
accordance with the substance defined by the following claims.
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