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United States Patent |
5,139,585
|
Watanabe
,   et al.
|
August 18, 1992
|
Structural member made of titanium alloy having embedded beta phase of
different densities and hard metals
Abstract
A structural member made of titanium or titanium alloy has a metal
structure at its surface layer portion formed of a plurality of kinds of
.beta.-phases of different characteristics which are present in
combination.
Inventors:
|
Watanabe; Naoya (Saitama, JP);
Hohda; Tatsuya (Saitama, JP);
Tokune; Toshio (Saitama, JP);
Wajima; Yoshihiko (Saitama, JP)
|
Assignee:
|
Honda Giken Kogyo Kabushiki Kaisha (Tokyo, JP)
|
Appl. No.:
|
563660 |
Filed:
|
August 7, 1990 |
Foreign Application Priority Data
| Aug 07, 1989[JP] | 1-204287 |
| Aug 11, 1989[JP] | 1-209454 |
Current U.S. Class: |
148/421; 75/10.26; 148/512; 148/902; 420/417 |
Intern'l Class: |
C22C 014/00 |
Field of Search: |
420/417
148/902,2,421
75/10.26
204/192.16
|
References Cited
U.S. Patent Documents
4157923 | Jun., 1979 | Yen et al. | 148/4.
|
4279667 | Jul., 1981 | Anthony et al. | 148/903.
|
4639281 | Jan., 1987 | Sastry et al. | 420/417.
|
4825035 | Apr., 1989 | Moriyasu et al. | 148/903.
|
4902359 | Feb., 1990 | Takeuchi et al. | 149/903.
|
4905538 | Mar., 1990 | Watanabe et al. | 148/903.
|
Other References
Vigier et al in Titanium & Titanium Alloys vol. 3, eds. Williams et al,
Plenum, 1982, p. 1691.
|
Primary Examiner: Roy; Upendra
Attorney, Agent or Firm: Lyon & Lyon
Claims
What is claimed is:
1. A structural member made of titanium or titanium alloy comprising a
surface layer portion having a metal structure formed of a plurality of
kinds of .beta.-phases of different characteristics present in
combination.
2. A structural member made of titanium or titanium alloy according to
claim 1, wherein said metal structure is formed of a first .beta.-phase
distributed into scattered spots and a second .beta.-phase developed in a
mesh-like pattern so as to surround the first .beta.-phase.
3. A structural member made of titanium or titanium alloy according to
claim 2, wherein the diameter of a mesh of said second .beta.-phase is of
not more than 10 .mu.m.
4. A structural member made of titanium or titanium alloy according to
claim 2, wherein said first and second .beta.-phases are obtained through
a resolidifying process, respectively, said first .beta.-phase having been
solidified at a temperature higher than said second .beta.-phase.
5. A structural member made of titanium or titanium alloy according to
claim 3, wherein said first .beta.-phase contains not less than 10% by
weight of Mo, and said second .beta.-phase contains not less than 3.5% but
not more than 40% by weight of Fe.
6. A structural member made of titanium or titanium alloy according to
claim 5, wherein said surface layer portion contains hard particles
uniformly dispersed therein, a volume fraction of said hard particles
being of not less than 10% but not more than 30%.
7. A structural member made of titanium or titanium alloy according to
claim 6, wherein said structural member is a rocker arm for an internal
combustion engine, and said surface layer portion forms a slipper surface.
8. A structural member made of titanium or titanium alloy according to
claim 6, wherein said Mo is added in the form of a carbide and said hard
particles are TiC particles which have been obtained by a reaction between
said carbide and titanium or titanium alloy as a matrix material of the
structural member.
9. A structural member made of titanium or titanium alloy comprising a
surface layer portion modified by a locally melting alloying process using
a high-density energy source, said surface layer portion having a metal
structure formed of two phases present in combination: a first
.beta.-phase containing a homogeneous solid solution type .beta.
stabilizing element and a second .beta.-phase containing an eutectoid type
.beta. stabilizing element.
10. A structural member made of titanium or titanium alloy according to
claim 9, wherein the content of said homogeneous solid solution type
.beta. stabilizing element is of not less than 10% by weight and the
content of said eutectoid type .beta. stabilizing element is of not less
than 3.5% but not more than 40% by weight.
11. A structural member made of titanium or titanium alloy according to
claim 10, wherein said homogeneous solid solution type .beta. stabilizing
element is at least one of Mo and V, and said eutectoid type .beta.
stabilizing element is at least one selected from the group consisting of
Fe, Cr, Mn, Co and Ni.
12. A structural member made of titanium or titanium alloy according to
claim 11, wherein said surface layer portion contains hard particles
uniformly dispersed therein, said hard particles having a volume fraction
of not less than 10% but not more than 30% by weight.
13. A structural member made of titanium or titanium alloy according to
claim 12, wherein said structural member is a rocker arm for an internal
combustion engine, and said surface layer portion forms a slipper surface.
14. A structural member made of titanium or titanium alloy according to
claim 12, wherein said Mo is added in the form of a carbide and said hard
particles are TiC particles which have been obtained by a reaction between
said carbide and titanium or titanium alloy as a matrix material of the
structural member.
Description
BACKGROUND OF THE INVENTION
1. Field of the Invention
The field of the present invention is structural members made of titanium
or titanium alloy.
2. Description of the Prior Art
There are conventionally known structural members of this type in which a
portion thereof requiring slide characteristic is formed of a .beta.-type
titanium alloy having a single .beta.-phase metal structure (see Japanese
Patent Application Laid-open No. 247806/86).
However, although the above .beta.-type titanium alloy has a slightly
improved slide characteristic as compared with an .alpha.-type and an
.alpha.+.beta.-type titanium alloy, it cannot meet the slide
characteristic required by a structural member which is used at a high
speed and a high surface pressure.
SUMMARY OF THE INVENTION
It is an object of the present invention to provide a structural member
made of titanium or titanium alloy of the type described above, which
includes a surface layer portion having a combined-type metal structure
and excellent in slide characteristic and strength.
To achieve the above object, according to the present invention, there is
provided a structural member made of titanium or titanium alloy with a
surface layer portion thereof being formed to have a metal structure
constructed such that a plurality of kinds of .beta.-phases of different
characteristics are present in combination therein.
When a plurality of kinds of .beta.-phases of different characteristics are
present in the surface layer portion as described above, the slide
characteristic of the surface layer portion can substantially be improved
as compared with a surface layer portion having a single .beta.-phase. The
surface layer portion thus constructed shows an excellent durability even
at a high speed operation and a high surface pressure, and has a
substantially improved strength.
According to the present invention, there is also provided a structural
member made of titanium or titanium alloy comprising a surface layer
portion which is modified by a locally melting alloying process using a
high-density energy source, the surface layer portion having a metal
structure formed of two phases present in combination: a first
.beta.-phase containing homogeneous solid solution type .beta. stabilizing
element and a second .beta.-phase containing an eutectoid type .beta.
stabilizing element.
If the locally melting alloying process is applied as described above, a
rapidly solidifying effect can be obtained by self-cooling after melting
and hence, the metal structure of the surface layer portion is made fine
and homogeneous. The surface layer portion is formed of two kinds of
.beta.-phases present in combination and hence, has a substantially
improved slide characteristic. This ensures that the surface layer portion
shows an excellent durability even at a high speed and a high surface
pressure and also has a high strength.
The surface layer portion formed by the locally melting alloying process
has a strong adhesion to titanium or a titanium alloy as a matrix material
and cannot be peeled off when sliding at a high speed and a high surface
pressure.
The above and other objects, features and advantages of the invention will
become apparent from a reading of the following description of the
preferred embodiment, taken in conjunction with the accompanying drawings.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a front view of a rocker arm with an essential portion being
broken away;
FIG. 2 is a schematic representation of a metal structure of a surface
layer portion;
FIG. 3 is a graph illustrating Vickers hardness of the surface layer
portion and others;
FIG. 4 is a graph illustrating a relationship between the Fe content and
averaged Vickers hardness of the surface layer portion;
FIG. 5 is a graph illustrating a relationship between the volume fraction
and Vickers hardness of hard particles in the surface layer portion;
FIG. 6 is a view explaining a modifying process;
FIG. 7A and 7B are microphotographs each showing a metal structure of the
surface layer portion;
FIG. 8 is a graph illustrating a relationship between the depth and Vickers
hardness of the surface layer portion; and
FIG. 9 is a graph illustrating the limiting baking load of the surface
layer portion.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
FIG. 1 illustrates a rocker arm 1 as a structural member made of titanium
alloy. The rocker arm 1 is used in a valve operating mechanism for an
internal combustion engine and is provided at one end thereof with a
slipper surface 2 which is in slide contact with a cam.
In producing the rocker arm 1, an .alpha.+.beta.-type titanium alloy blank
having a composition of Ti-6Al-4V is used and a surface layer portion 3
constituting the slipper surface 2 is formed by subjecting the blank to a
modifying treatment.
A metal structure of the surface layer portion 3 is formed of a plurality
of, e.g., two (in the present embodiment) kinds of .beta.-phases of
different characteristics present in combination.
As apparent from a schematic representation of the metal structure shown in
FIG. 2, a first .beta.-phase b.sub.1 is distributed into scattered spots,
and a second .beta.-phase b.sub.2 is developed in a mesh-like fashion so
as to surround the first .beta.-phase b.sub.1. The surface layer portion 3
contains hard particles p uniformly dispersed therein.
In the modifying treatment, a locally melting alloying treatment under a
high density energy beam is conducted using a carbide powder of a
homogeneous solid solution type .beta. stabilizing element and a powder of
an eutectoid .beta. stabilizing element and therefore, the first
.beta.-phase b.sub.1 contains a high density of the homogeneous solid
solution type .beta. stabilizing element and the second .beta.-phase
b.sub.2 contains a high density of the eutectoid .beta. stabilizing
element.
The homogeneous solid solution type .beta. stabilizing element may be at
least one of Mo and V. The eutectoid .beta. stabilizing element may be at
least one selected from the group consisting of Fe, Cr, Mn, Co and Ni.
The homogeneous solid solution type .beta. stabilizing element forms a
homogeneous solid solution structure in combination with the
.alpha.+.beta.-type titanium alloy which is a matrix material. Inclusion
of 10% or more by weight of this element ensures that the first
.beta.-phase b.sub.1 can be brought into room temperature. This element
has effects of improving the slide characteristic and heat resistance of
the first .beta.-phase b.sub.1.
The specified contents of Mo and V to provide these effects are of 10% or
more by weight for Mo and 14.9% by weight for V.
However, if the homogeneous solid solution type .beta. stabilizing element
is added alone, the first .beta.-phase b.sub.1 is low in hardness, only
providing an insufficient wear resistance.
Inclusion of 3.5% or more by weight of the eutectoid type .beta.
stabilizing element ensures stabilization of the second .beta.-phase
b.sub.2 and permits precipitation hardening effects to be produced to
improve the hardness of the second .beta.-phase b.sub.2.
The specified contents of Fe, Cr, Mn, Co and Ni to provide these effects
are 3.5% or more by weight for Fe; 6.3% or more by weight for Cr; 6.4% or
more by weight for Mn; 7% or more by weight for Co; and 9% or more by
weight for Ni.
However, if the content of the eutectoid type .beta. stabilizing element
exceeds 40% by weight, a segregation or the like may be produced due to a
low solid solution property of this element, and thus a stable second
.beta.-phase b.sub.2 cannot be obtained. Therefore, the upper limit of the
content of this element is set at 40% by weight.
If only the eutectoid type .beta. stabilizing element is added without
addition of the homogeneous solid solution type .beta. stabilizing
element, an intermetallic compound is formed owing to the above-described
precipitation hardening effects, so that the resulting second .beta.-phase
b.sub.2 tends to be embrittled. This problem can, however, be overcome by
using the homogeneous solid solution type .beta. stabilizing element in
combination with the eutectoid type .beta. stabilizing element.
Specified examples using Mo as the homogeneous solid solution type .beta.
stabilizing element and Fe as the eutectoid type .beta. stabilizing
element will be described below.
FIG. 3 is a graph illustrating a comparison in hardness among a matrix
(Ti-6Al-4V), a comparative example of surface layer portion comprising the
matrix and 26% by weight of Mo contained therein and a surface layer
portion according to the present invention comprising the matrix and 26%
by weight of Mo and 8% by weight of Fe contained therein.
It can be seen from FIG. 3 that the comparative example of surface layer
portion containing only Mo is relatively small in degree of increase in
hardness as compared with that of the matrix alone, but if Fe is also
contained, the hardness can be substantially increased.
Table 1 shows an average composition (estimated), an average hardness and a
feed ratio of an Mo.sub.2 C powder to an Fe powder in each of the surface
layer portions, and FIG. 4 is a graph based on Table 1.
TABLE 1
______________________________________
Surface
Chemical Composition
layer (% by weight) Feed ratio
Av. har.
No. Mo Fe Al V Ti Mo.sub.2 C/Fe
(Hv)
______________________________________
I 37.7 -- 4.1 3.2 Ba. 100/0 400
II 34.8 2.9 4.1 3.2 Ba. 95/5 587.7
III 32.1 5.6 4.1 3.2 Ba. 90/10 707.8
IV 27.1 10.6 4.1 3.2 Ba. 80/20 721.6
V 22.6 15.1 4.1 3.2 Ba. 70/30 686.2
VI 18.5 19.2 4.1 3.2 Ba. 60/40 719.5
VII 14.7 23.0 4.1 3.2 Ba. 50/50 714.6
______________________________________
Av. har. = Average hardness
Ba. = Balance
It can be seen from Table 1 and FIG. 4 that the Fe content should be of
3.5% or more by weight and preferably of 5% or more by weight.
It is desirable that the diameter of a mesh 4 in the second .beta.-phase
b.sub.2 is as fine as 10 .mu.m or less from the viewpoint of improvements
in slide characteristic and strength.
The hard particles p are carbide particles, i.e., TiC particles
precipitated through the modifying treatment by reactions: Mo.sub.2
C.fwdarw.2Mo+C and Ti+C.fwdarw.TiC, and the volume fraction (Vf) of the
hard particles p is set in a range of from 10% to 30%. The inclusion of
the hard particles p insures the hardness of the surface layer portion 3
to provide an improved wear resistance. Thus, the surface layer portion 3
comprising the first and second .beta.-phases b.sub.1 and b.sub.2 and the
hard particles p exhibits a wear resistance equal to or more than that of
a conventional iron-based sintered slide member under a sliding condition
at a high speed and a high surface pressure.
Because the hard particles p are produced by a precipitation phenomenon,
they are fine particles having a particle size of 1 to 5 .mu.m and having
a good dispersability and a rounded shape and therefore, have an advantage
that their attacking characteristic such as, for example, of increasing
the amount of mating slide member worn is low.
In general, in dispersing the hard particles, a pulverized powder is
necessarily used in order to provide a particle size of the
above-described range, but the pulverized powder has a high attacking
characteristic to the mating slide member because of an angular shape
thereof and exhibiting an abrasive effect. In addition, in order to
achieve a very fine particle size within the abovedescribed range, a
precision classification must be conducted, bringing about a considerable
increase in cost.
If the volume fraction of the hard particles p is less than 10%, the
above-described effects are not obtained. On the other hand, any volume
fraction exceeding 30% will lead to an increased attacking characteristic
to the mating slide member and to embrittlement of the surface layer
portion 3. Further, the hard particles p will be liable to be fallen off
the portion 3.
FIG. 5 illustrates a relationship between the volume fraction (Vf) and
Vickers hardness (maximum hardness) of the hard particles p in the surface
layer portion 3.
In this case, an .alpha.+.beta.-type titanium alloy similar to that
described above was used as a matrix, and the amount of Mo.sub.2 C powder
added was varied to adjust the amount of TiC particles precipitated.
It can be seen from FIG. 5 that the hardness of the surface layer portion 3
is increased as the volume fraction of the hard particles p is increased.
The modifying treatment for the rocker arm 1 will be described below.
FIG. 6 illustrates a modifying process (a locally melting alloying process)
which comprises moving a rocker arm blank 1.sub.0 made of the matrix
material (Ti-6Al-4V) in a direction indicated by an arrow, and irradiating
a carbon dioxide gas laser from an oscillator 5 to a portion 2.sub.0 of
the blank 1.sub.0 corresponding to the slipper surface while at the same
time supplying a helium gas which serves as a shielding gas from a gas
supply nozzle 6 and supplying powders of Mo.sub.2 C and Fe from a powder
supply nozzle 7.
Modifying conditions are as follows:
Moving rate or speed (treating rate) of the rocker arm blank 1.sub.0 300
mm/min.;
The carbon dioxide gas laser: an output power of 5 kW, a spot diameter of 2
mm, an amplitude of 5 mm, and a power density of 5 to 6.times.10.sup.4
W/cm.sup.2 ;
The powder of Mo.sub.2 C: a diameter of 10 to 44 .mu.m; a supply amount of
15.7 g/min.; and the powder of Fe: a purity of 99% or more, a particle
size of 200 mesh or less, and a supply amount of 4.6 g/min.
The formation of the surface layer portion 3 is effected via the following
first to fourth steps:
A first step: the matrix and the powders of Mo.sub.2 C and Fe are molten in
a temperature range of 3,200.degree. C. or more. In this case, the
reaction of Mo.sub.2 C.fwdarw.2Mo+C takes place.
A second step: the reaction of Ti+C.fwdarw.TiC takes place in a temperature
range of 3,200.degree. C. or less to precipitate TiC particles as hard
particles.
A third step: a first .beta.-phase b.sub.1 having a high density of Mo
starts to be crystallized in a temperature range of about 2,000.degree. C.
A fourth step: a second .beta.-phase b.sub.2 having a high density of Fe
starts to be crystallized in a temperature range of about 1,400.degree. C.
FIGS. 7A and 7B are microphotographs each showing a metal structure of the
surface layer portion 3 formed by the above-described modifying treatment,
taken by an X-ray microanalyzer (EPMA).
FIG. 7A shows a distribution of Mo, wherein white portions are Mo, and it
is seen that the first .beta.-phase b.sub.1 having a high density of Mo is
distributed into scattered spots.
FIG. 7B shows a distribution of Fe, wherein white portions are Fe, and it
is seen that the second .beta.-phase b.sub.2 having a high density of Fe
is developed in a mesh-like fashion so as to surround the black first
.beta.-phase b.sub.1 having a high density of Mo.
The mesh-like structure formed by the first .beta.-phase b.sub.1 and the
second .beta.-phase b.sub.2 is produced due to a difference in solidifying
point between the phases b.sub.1 and b.sub.2 at a resolidifying stage, and
is formed as a result of the first .beta.-phase b.sub.1 of a higher
solidifying point having first been crystallized and the second
.beta.-phase b.sub.2 having then been formed so as to fill gaps defined by
the crystallized first .beta.-phase b.sub.1.
In the locally melting alloying treatment using a high density energy beam
such as a carbon dioxide gas laser, a rapid solidifying effect is provided
by self-cooling after melting and hence, the mesh-like structure is made
very fine and homogeneous, thereby providing a stable slide characteristic
and strength. In addition, the adhesion of the surface layer portion 3 to
the matrix is strong.
The reason why the carbide such as Mo.sub.2 C is used for the purpose of
addition of Mo is that a lower melting point effect of the carbide is
aimed at, as will be described hereinafter, in addition to providing
precipitation of the TiC particles which are hard particles.
More specifically, a metal Mo is a material having a high melting point of
2,610.degree. C. and if the metal Mo is used as it is, it is difficult to
be alloyed with Ti in a titanium alloy having a melting point of
1,668.degree. C. However, if Mo is used in the form of a carbide, the
melting point thereof is reduced to about 2,400.degree. C., resulting in a
reduced difference in melting point from Ti, which facilitates their
alloying.
The carbide powder also has a high heat absorptivity (light absorptivity),
as compared with the metal Mo and hence, is convenient even for energy
efficiency.
The average composition of the surface layer portion 3 provided by the
above-described modifying treatment was Ti-26Mo-11.8Fe-4.1 Al-3.2V; and
the average particle size of TiC particles therein was of 2.4 .mu.m, and
the volume fraction was of 18.75%.
In this case, the content of Mo in the first .beta.-phase b.sub.1 is of
40.5% by weight and the content of Fe therein is of 5.7% by weight and
hence, the density of Mo in the first .beta.-phase b.sub.1 is higher. On
the other hand, the content of Fe in the second .beta.-phase b.sub.2 is of
22.4% by weight and the content of Mo therein is of 10.0% by weight and
hence, the density of Fe is higher in the second .beta.-phase b.sub.2.
FIG. 8 illustrates a relationship between the depth and hardness of the
surface layer portion 3. In this Figure, S1 indicates a position of the
slipper surface before the modifying treatment, and S2 indicates a
position of the slipper surface after the modifying treatment. As
apparent, its thickness is slightly increased through the modifying
treatment.
It can be seen from FIG. 8 that the hardness (Hv) of the slipper surface 2
shows a value as high as about 750 as a result of the modifying treatment.
FIG. 9 illustrates results of a slide test for various chip materials
constituting conventional surface layer portion and the slipper surface 3
according to the present invention. Table II shows types of materials for
various test pieces A to F in FIG. 9.
TABLE II
______________________________________
Test piece
Type of material
______________________________________
A Industrial pure titanium (.alpha.-type)
type titanium alloy) (.alpha. + .beta.
C Ti--15Mo--5Zr--3Al (.beta.-type titanium alloy which
is a conventional material)
type WC particle-dispersed Ti--6Al--4V (.alpha. + .beta.
titanium alloy)
E Material according to the invention
(as described above)
F High-Cr iron-based sintered material
______________________________________
The slide test was conducted in a chip-on-disc style, and test conditions
were as follows: The material of a disk was a structural steel (JIS SCM
420H) carburized; slide rate . . . 7.5 m/sec.; load . . . increased at 10
kg/min from 0 to 300 kg f; lubricating oil . . . trade name 10W-30, ultra
U, made by Shows Shell Petroleum, Co., Ltd.; and amount of lubricating oil
supplied . . . 11 cc/min (at room temperature).
The limiting (critical) baking load was determined by finding a load when
the text piece was baked in response to increase of the above-described
load.
As apparent from FIG. 9, the limiting baking load is equal to or more than
300 kg f in the present invention which corresponds to that of the
conventional high-Cr iron-based sintered material.
For the locally melting alloying process, it is possible to use a pre-place
process in which a powder is previously placed on that portion 2.sub.0 of
the blank 1.sub.0 which corresponds to the slipper surface.
The present invention is also applicable to a titanium made structural
member.
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