Back to EveryPatent.com
United States Patent |
5,108,509
|
Booth
,   et al.
|
April 28, 1992
|
Flushed pigment and a method for making the same
Abstract
A pigment is formed in an aqueous slurry. A mixture of the pigmented slurry
and a vehicle is subjected to high speed, high shear mixing action. The
water is forced out of the solid pigment and replaced by the vehicle
forming bead-like spherical conglomerates. The conglomerates grow into
clusters in the dispersing phase during the mixing process. The clusters
are filtered from the dispersing water phase forming a flushed pigment
which is used for dispersion in ink systems.
Inventors:
|
Booth; John S. (Fall River, MA);
Makuch; Edward W. (N. Wesport, MA)
|
Assignee:
|
Roma Color, Inc. (Fall River, MA)
|
Appl. No.:
|
520462 |
Filed:
|
May 8, 1990 |
Current U.S. Class: |
106/493; 106/410; 106/497; 106/500; 106/504 |
Intern'l Class: |
C08K 005/00 |
Field of Search: |
106/410,493,497,500,504
|
References Cited
U.S. Patent Documents
3844811 | Oct., 1974 | Brynko | 106/493.
|
3980488 | Sep., 1976 | Barrington et al. | 106/497.
|
4194921 | Mar., 1980 | Wheeler et al. | 106/493.
|
4309223 | Jan., 1982 | Rouwhorst et al. | 106/493.
|
4747882 | May., 1988 | Schwartz et al. | 106/500.
|
4765841 | Aug., 1988 | Vinther et al. | 106/493.
|
Primary Examiner: Dixon, Jr.; William R.
Assistant Examiner: Thompson; Willie J.
Attorney, Agent or Firm: Samuels, Gauthier & Stevens
Parent Case Text
This is a divisional of co-pending application Ser. No. 362,979 filed on
Jun. 8, 1989 now U.S. Pat. No. 5,041,163.
Claims
Having described our invention, what we now claim is:
1. A flushed pigment which consists of
discrete agglomerated pigment/vehicle clusters which contain less water by
weight than pigment content thereof and having a specific gravity of
between 0.5 to 0.8 gm/cm.
2. The flushed pigment of claim 1 which contains 5 to less than 50% water
by weight.
3. The flushed pigment of claim 1 wherein the pigment is selected from the
group consisting of CI pigment yellows 12, 13, 14, 17, 83; CI pigment
orange 15, 16 and 34; and CI pigment reds 17, 23, 42, 48 and 57.
4. The flushed pigment of claim 2 wherein the pigment is AAA yellow.
5. The flushed pigment of claim 1 wherein the pigment is selected form the
group consisting of phthalocyanines, quinacridones, dioxazines, perylenes,
indanthrones and vat pigments.
6. The flushed pigment of claim 5 wherein the pigment is phthalocyanine
blue.
7. The pigment of claim 1 wherein the vehicle is selected from the group
consisting of drying, semi-drying, and non-drying oils, litho varnishes,
mineral oils, rosins, esters of dimerized rosins, aliphatic and aromatic
hydrocarbon resins, alkyl-aromatic resins, maleic and fumeric-modified
rosin, phenolic resin, phenolic-modified rosin esters, alkyd resins,
polyolefins, coumarone resins, phthalate esters, castor oil, fish oil,
linseed oil, soy bean oil, gloss varnishes and various heat-set, quick-set
and steam-set vehicle systems.
8. The flushed pigment of claim 1 wherein the vehicle is soy bean oil.
9. The flushed pigment of claim 1 wherein the diameter, Dp, of the clusters
is between 0.1 to 1.0 millimeters.
10. The flushed pigment of claim 1 wherein clusters are formed into a paste
and the pigment to vehicle ratio is between 1:7::7:1 by weight and the
paste has a water content of 5 to 10%.
11. The flushed pigment of claim 10 wherein the ratio is about 1:1.
Description
BACKGROUND OF THE INVENTION
Historically, organic pigments have been made by coupling in a dilute
aqueous slurry. The slurry is then filtered in a filter press to
concentrate the pigment and to form a press cake. The press cake is either
dried to obtain a dry pigment, or "flushed" to transfer the pigment
particles from the aqueous phase to a non-polar oil or resin phase
commonly referred to as a "flushed color". In the resulting flushed color
state, the pigment particles are kept in a paste-like state for ultimate
use in inks or coatings.
Flushing has been carried out for many decades by mixing pigment press cake
with suitable types and quantities of "vehicles" which may for example
comprise an oil, or a solution of one or more resins and other additives
in a solvent. Typically, in the prior art, the transfer is effected by
vigorously kneading the press cake and vehicle until the flushing is
complete. These are generally batch type operations employing sigma-blade
mixers similar to dough mixers or Banbury mixers.
Other prior art techniques also exist. For example, in U.S. Pat. No.
4,309,223, the pigment slurry if forced through a conduit with vehicle
injection. U.S. Pat. No. 3,980,488 teaches partially milling dry pigment
prior to flushing. U.S. Pat. No. 2,378,786 teaches mixing a pigment slurry
with oil, passing the mixture through a colloid mill, which could be
considered equivalent to a homogenizer, followed by passing through a heat
exchanger and de-watering on a heated belt. U.S. Pat. No. 4,747,882
teaches mixing a pigment slurry with an oil to transfer the pigment from
the aqueous phase to the oil.
These processes are very energy and labor intensive. Moreover, the
resulting product or dispersion is often an extremely viscous paste which
must be laboriously removed by manually shovelling or scraping. Flushed
colors may have up to 30-35% by weight pigment, 64.9-69.9% by weight
vehicle, and the remainder water. Most of the water in normal flushed
color is removed by heat and/or vacuum.
Those skilled in the art will readily recognize that transparency is a
highly desirable property of flushed colors During the vigorous kneading
step of conventional flushing processes, considerable heat is generated.
Heat does not adversely affect the transparent properties of red and blue
pigments. However, yellow pigments, particularly AAA yellows, are
extremely heat sensitive and can turn from transparent to opaque as a
result of being subjected to excessive heat. In order to prevent or at
least minimize this problem, the prior art processes employ complex and
expensive cooling techniques. Such techniques are not required in the
process of the present invention because little, if any, heat is
generated.
It will be seen, therefore, that the prior art flushed colors are made by
processes which are labor and energy intensive, and in the cases where
yellow pigment is being produced, such processes are further complicated
by the need for complex and expensive cooling techniques. Once made, the
conventional flushed colors are difficult to process further because of
their extremely high viscosities.
SUMMARY OF THE INVENTION
The present invention is directed to an improved flushed pigment and to a
novel and improved process for making the same. The process of the present
invention may be run at ambient temperatures and requires only relatively
low expenditures of energy and labor as compared to prior art processes.
This is particularly advantageous in the case of heat sensitive yellow
pigments. The flushed pigment of the present invention is easily handled
both before and during the ink manufacturing process.
Broadly, the invention, in one aspect, includes flushing a pigment formed
in an aqueous slurry in a manner such that the vehicle displaces the water
in and surrounding the pigment to form spherical pigment/vehicle
conglomorates which grow into clusters in a dispersing water phase. The
pigment/vehicle clusters are recovered from the dispersing water phase as
a flushed pigment. The clusters have physical properties which are
markedly different and significantly advantageous as compared to the
flushed product of the prior art. For example, the pigment/vehicle
agglomerated clusters are easily separated and recovered from the
dispersing water phase. They also possess a markedly superior rate of
dispersion into ink systems.
In the preferred embodiment of the present invention, a mixture of
pigmented slurry and vehicle is subjected to intense high speed, high
shear mixing action. This action commences flushing of the water from the
pigment, whereby the water is forced out of the solid pigment and replaced
by the vehicle (the pigment is lyophilic with the vehicle), forming
bead-like spherical conglomorites. These conglomorites exhibit a tendency
to grow into clusters in the dispersing phase during the mixing process.
After the flushing has been completed, the mixture in the tank exists in
two phases, namely, the pigment/vehicle agglomerated cluster phase and the
dispersing water phase.
The mixture is then filtered, preferably by being transferred into a
webbed, nylon bag. The free water passes through the bag as filtrate. The
bag retains the pigment/vehicle clusters as a flushed cake made up of the
flushed pigment The flushed cake is washed with water to remove the
remaining soluble salts. The flushed pigment is then ready for use "as is"
for dispersion in ink systems. Alternatively, the mixing can be stopped
and the pigment/vehicle agglomorated clusters allowed to simply float to
the top of the tank. Therefore, the dispersing salt water is displaced by
fresh water by normal decanting and washing processes.
The invention in another aspect is particularly suited for resinated
pigments. After the coupling reaction has been effected in the strike
tank, the pH is raised to between 10.0 to 11.5. The pigment is then
flushed according to the method of the invention at this elevated pH.
After flushing, the pH is lowered to about 6.5-7.0. Flushed pigment
produced by this technique has superior dispersibility in the subsequent
systems in which it is used, has a higher pigment to vehicle loading ratio
and when being formulated in another system for end use, such as an ink
system, the thixotropic properties usually incurred are far less.
The invention in still another aspect comprises the resulting flushed
pigment. The pigment/vehicle clusters assume various forms, including for
example, discrete shapes which can be bead-like or rod-like.
The flushed pigment of the present invention as flushed cake has between 5
to 50% water, usually 5 to 25% water, the remainder being solids,
preferably less water by weight than pigment content. The solids comprise
the pigment/vehicle clusters.
Retained (or bound) water may be removed easily by processing the flushed
cake in a Banbury mixer. Generally, all flushed pigments produced
according to the invention can have the water content easily reduced to 5
to 10%. In this step the flushed cake changes to a paste-like consistency
(similar to molasses). However the dispersion properties are not affected.
The pigment/vehicle ratio may vary between about 7:1::1:7, preferably 1:1
by weight.
The flushed pigment of the present invention, when formulated into an ink
system, disperses remarkably easily as compared to conventional flushed
colors, especially at comparable pigment concentrations.
BRIEF DESCRIPTION OF THE DRAWING
FIG. 1 is a process flow diagram of a system of the invention;
FIG. 2 is a schematic illustration of a submerged mixer, high shear device;
FIG. 3-5 are photomicrographs of flushed pigments made according to the
process of the present invention; and
FIG. 6 is a photomicrograph of a prior art 3A yellow flushed color.
DESCRIPTION OF THE PREFERRED EMBODIMENT
An aqueous slurry of less than 10% and preferably between 5 to 7% solids of
solid organic pigment is thoroughly mixed with an organic vehicle in a
manner such that the organic vehicle is transferred to the solid pigment,
thereby replacing the water in and surrounding the pigment to form
pigment/vehicle conglomorates suspended in water. These conglomorates grow
into clusters which are subsequently separated from the dispersing phase.
Although the preferred embodiment will be described with reference to
slurries of diarylide yellow pigments, such as CI pigment yellow 12, the
invention is also applicable to other organic pigments, resinated or
non-resinated, such as CI pigment yellows 13, 14, 17, 83; CI pigment
orange 15, 16, 34; and CI pigment reds 17, 23, 48, 49, 53, and 57. In
addition to phthalocyanine blue magmas, the process is applicable to other
pigments manufactured by the salt grinding process such as quinacridones,
dioxazines, perylenes, indanthrones, and vat pigments.
Any of the hydrophobic organic vehicles that are commonly used in printing
inks and coating compositions may be employed in the method and
composition of this invention. Such vehicles are represented by drying,
semi-drying, and non-drying oils, litho varnishes, mineral oils, rosins,
dimerized rosins, esters of dimerized rosins, aliphatic and aromatic
hydrocarbon resins, alkyl-aromatic resins, maleic and fumeric-modified
rosin, phenolic resin, phenolic modified rosin esters, alkyd resins,
urethane-modified alkyds, polyolefins, coumarone resins, phthalate esters,
castor oil, fish oil, linseed oil, gloss varnishes and various heat-set,
quick-set and steam-set vehicle systems. A preferred vehicle is soy bean
oil.
Referring to FIG. 1, an aqueous slurry of an AAA yellow pigment is formed
in a strike tank 10 which is provided with a variable speed Post Mixer 12.
The aqueous slurry is preferrably an aqueous unfiltered slurry containing,
by weight, about 5% pigment. The slurry is fed to a mixing tank 14. Five
mixing devices are arranged in the mixing tank 14, These include a
4-bladed paddle mixer 16, such as a variable speed Post Mixer, #804293,
Varidrive Max 57 RPM located off center, an four high speed mixers 18a,
18b and 20a, 20b. The mixers 18a and 18b preferably comprise Hill Mixers,
50 hp with 45.degree. blades, and the mixers 20a and 20b preferably
comprise Hill Mixers, 30 hp with 45.degree. blades. Viewed from above the
mixers are located as follows: at 1 o'clock, 18a; 4 o'clock, 20a; 8
o'clock, 18b and 10 o'clock, 20b. After the flushed pigment is formed, the
mixture is directed from the tank 14 into a suspended filter bag 22, such
as a woven, five ounce, polypropylene sling bag, Stone Container Corp.,
Opalocka, Fla.
A high shear mixer 30 suitable for purposes of the invention is
schematically depicted in FIG. 2. The mixer 30 is adapted to be submerged
in tank 14 and comprises blades 32 received in a cylindrical shroud 34.
The edges of the blades are spaced apart from the inner surface of the
shroud to define a slight gap 36 of from a few mils to 40 mils. High speed
rotation of the blades forces the pigment slurry through gap 36, which
constitutes a high shear zone, with the result that at least a portion of
the pigment is flushed and formed into generally spherical pigment/vehicle
conglomorates. These conglomorates are forced upwardly through conduits
38. Upon discharge from the conduits, they impinge upon a baffle 40 and
flow outwardly into the tank where they begin growing into clusters.
EXAMPLE I
An AAA pigment yellow coupling process is effected in tank 10 by any
conventional process of the type well known in the art. The resulting
pigment is an aqueous slurry 5% by weight AAA yellow pigment, and the
total weight of the slurry is 29,600 pounds, containing 1480 pounds of dry
pigment.
3,330 pounds of soy bean oil is introduced into the 8,000 gallon fiberglass
mixing tank 14. The mixer 16 and the mixers 18a and 18b and 20a and 20b
are all activated. The mixer 16 is run at 14-15 RPM; the mixers 18a and
18b and 20a and 20b are run at 3540 RPM. The slurry is fed at a rate of
about 100 gallons per minute from the tank 10 to the vehicle being
agitated in tank 14. The flow of the slurry and vehicle through the mixers
18-20 effects the flushing of the pigment. Water is displaced from the
pigment by the vehicle. Pigment/vehicle conglomorates are formed and are
dispersed in the water phase where they grow into clusters. The slurry
continues to flow to the tank 14 at the same flow rate until the entire
1480 pounds of the pigment in slurry form is mixed with the vehicle.
The entire mixing/flushing process to form the flushed pigment takes
approximately two hours; including forty five minutes to transfer the
slurry into tank 14 and one hour and fifteen minutes for the subsequent
mixing in the tank 14. At the conclusion of the mixing/flushing process,
the tank 14 contains a two-phase mixture of pigment/vehicle clusters in
water. The final pigment/vehicle ratio by weight can range from 4:9 to
1:1.
A sample is then taken and tested to verify completion of the flushing.
This test entails formulating a sample from tank 14 into an ink and mixing
the ink in a Waring Blender for three (3) minutes. The ink is applied onto
an NIPIRI gauge and when it "runs off" the gauge without "scratches" the
flushing is complete.
The flushed pigment is then transferred to the filter bag 22 where the
water is drained off, leaving a flushed cake of the discrete non-uniform
pigment/vehicle having more than about 5% water, say 15% water. The water
drains from the cake in about ten (10) minutes. The flushed cake is washed
with tap water until all soluble salts are removed. This condition is
determined by a reading of 50 microohms or less on a conductivity meter.
The flushed pigment can be dispersed in a news ink vehicle in approximately
thirty (30) minutes with a Cowles dissolver. In comparison, a prior art
flushed color of the same pigment concentration would take 11/2 to 2 hours
to disperse in the vehicle, followed by one pass through a three roll
mill.
Depending upon the requirements of the ink manufacturer, the flushed
pigment can be shipped in the nylon mesh bags "as is" or additional water
can be removed. If more water is to be removed, the flushed cake is placed
in a Banbury or similar mixer. After five to ten minutes some of the
entrapped water is separated from the flushed cake. The consistency of the
flushed cake turns to a loose paste and the water is decanted from the
paste. At this time the percent water in the paste is 5% or less. Whether
the flushed pigment is used as aggregate or paste does not affect the
dispersibility in inks.
EXAMPLE II
A resinated flushed pigment is formed as described in Example I. After the
pigment has been formed in the strike tank, the pH is raised to between 10
to 11.5 and mixing continues for approximately thirty minutes. The slurry
is then transferred to the mixing tank for flushing. The mixing/flushing
process takes approximately 1 hour. After flushing, the pH is lowered to
6.5-7.0. It is believed raising the pH solvates the resin to allow for a
faster rate of flushing and to achieve a higher pigment loading in the
final pigment/vehicle composition. The final pigment/vehicle ratio by
weight is about 1:1. This flushed pigment can be dispersed in a new ink
vehicle in approximately 15 minutes with a Cowles dissolver. Further, the
flushed pigment of Example I, when dispersed in the new ink vehicle,
experiences thixotropicity within a few minutes. The flushed pigment of
this example does not experience any thixotropicity for several minutes.
Historically, phthalocyanine blue, unlike other organic pigments, is
manufactured by a salt grinding process which requires heavy duty dough
mixers and results in a product called a magma. The magma is then slurried
and passed through a filter press where the ethylene glycol and salts are
removed. The resulting blue press cake is then flushed. All of this can be
avoided by employing the process and equipment described in Example I,
with the result being a superior phthalocyanine blue flushed pigmented
cake.
EXAMPLE III
1632 pounds of soy bean oil is introduced into the tank 14. 27,400 pounds
of an aqueous phthalocyanine blue magma slurry (6% pigment solids) is
pumped into the tank 14 at a rate of 100 gallons per minute while all five
mixers are activated. After completion of pumping of the pigmented magma
slurry into the tank (approximately forty five (45) minutes) agitation of
all mixing equipment is continued for approximately 11/2 to 2 hours. A
sample is taken and evaluated as a finished ink using the test procedure
described above to confirm that the flushing is complete.
The mixture from tank 14 is pumped into the nylon mesh bag 22 while washing
with tap water to remove the soluble salts and ethylene glycol. The
flushed cake contains about 15% water.
In addition to phthalocyanine blue magmas, the process is applicable to
other pigments manufactured by the salt grinding process such as
quinacridones, dioxazines, perylenes, indanthrones, and vat pigments.
The invention has been described with reference to flushing water from a
pigment and replacing the water with vehicle and the recovery of a flushed
pigment in the form of discrete generally spherical clusters.
Depending upon the pigment, the vehicle and the processing conditions, the
clusters may have indiscriminate sizes and shapes. They may be spherical,
non-spherical, rod-like or of any random geometric configuration, uniform
or non-uniform. FIG. 3 is a photomicrograph of flushed pigment clusters in
accordance with the present invention.
FIGS. 4 and 5 are photomicrographs of other pigment clusters of the
invention more clearly illustrating how the spherical conglomorates tend
to agglomerate into various shapes.
FIG. 6 is a photomicrograph of a prior art 3A yellow, specifically, mineral
oil flushed color, 28% toner content.
The pigment clusters of FIG. 3 is flushed pigment made according to the
process described herein and having a composition of 1:1 pigment to
soybean oil in the presence of 20% water. The pigment clusters of FIGS. 4
and 5 are flushed pigments made according to the process disclosed herein
and having the composition of 1:1.5 pigment to heat set vehicle (Nevroz
SS50).
The size of the clusters, based on their second longest dimension, may
range in diameter, Dp, from about 0.1 to 10.0 mm. The shape of the
clusters measured by sphericity, .PHI., may range between 1 to 0.6. For
definitions of diameter, Dp, and sphericity, , see McCabe, W. L. and
Smith, J. C., "Unit Operations of Chemical Engineering", 3rd Ed., pp.
803-804, McGraw Hill Book Company, 1976. The bulk density of the clusters
is between 0.5-0.8 gm/cm.sup.3.
In the practice of the invention, the flow rates for pigmented slurries and
the mixing techniques used will vary depending upon the pigments to be
flushed, the medium for the pigment, the percent solids of pigment, the
pigment/vehicle ratio desired and the vehicle into which the pigment is to
be flushed. Further, the feed to the vehicle may be continuous or
intermittent. During flushing, the vehicle will initially exhibit a slight
uniform tint which will deepen as the flushing continues. The final
appearance of the two phase mixture in the tank should not be streaky or
non-uniform. The test for complete flushing is the NIPIRI gauge. The test
for growth of the pigment/vehicle conglomorates is also visual.
Accordingly, for the above-described reasons, the flow rates and intensity
of mixing requirements will vary based on process conditions.
Further, it has been found advantageous to eliminate surface active agents
(detergents, wetting agents, emulsifiers) and resinators from the coupling
process in the strike tank. These additives are introduced into the strike
tank in prior art processes just prior to the final preciptation step to
enhance the control of the particle size of the pigments and the
dispersibility of the pigments in the press cakes and flushed colors. It
has been discovered that these additives are not necessary for purposes of
the present invention. That is, it has been found that without such
additives, the flushing of the water from the pigment is accomplished more
rapidly. However, the invention may be successfully practiced using these
additives. It has also been found that the flushing of the pigment can be
accomplished more readily when soy bean oil is added to the coupling tank.
Specifically, adding vehicle in an amount of about 10% by weight, based on
weight of pigment in the coupling tank, reduces the time required to flush
in the mixing tank. For Example I, 148 pounds of soy bean oil would be
added in the tank 10 to aid in the flushing process previously described.
If soy bean oil is used in the coupling tank as a preconditioning agent
the vehicle in the mixing tank 14 may be any vehicle previously described
including soy bean oil.
The invention may also be used in producing flushed red pigment. The
process, as with the yellow pigments, is far less energy and labor
intensive than prior art process. Further, the pigments are believed more
readily dispersed in vehicle than prior art red pigments.
A further advantage of the invention is that once the pigment has been
received in the above-described filter bags, a shrink wrapping can be
applied to the bags, thereby enabling them to serve as shipping
containers.
The flushed pigment may be used in heat set inks, oil and aromatic printing
ink systems.
To determine the suitability of pigment vehicle combinations for a
production run, laboratory tests are initially conducted. Listed below are
a series of runs which illustrate the applicability of the process and the
flushed pigments which are suitable for purposes of the invention.
__________________________________________________________________________
Run Dry % Vehicle Water Volume in
Time to
# Pigment Used
Weight
Slurry
used out
flushed pigment
complete flushing
__________________________________________________________________________
1 Pigment yellow 12
400 grams
4.5%-6.5%
Soybean oil
5%-35% 30-40
minutes
(AAA) (900 grams)
2 Pigment yellow 12
400 grams
4.5%-6.5%
Soybean oil
15%-30% 45-60
minutes
(AAA) (400 grams)
3 Pigment yellow 12
400 grams
4.5%-6.5%
Soybean oil
15%-30% 45-65
minutes
(AAA) (400 grams)
4 Pigment yellow 12
400 grams
4.5%-6.5%
Soybean oil
15%-30% 45-60
minutes
(AAA) (400 grams)
5 Pigment yellow 12
400 grams
4.5%-6.5%
Nevchem 140
25%-50% 11/2-2
hours
(AAA) (360 grams)
Magiesol 47
(40 grams)
6 Pigment yellow 12
400 grams
4.5%-6.5%
Nevchem 140
25%-50% 11/2-2
hours
(AAA) (320 grams)
Magiesol 47
(80 grams)
7 Pigment yellow 12
400 grams
4.5%-6.5%
Linseed oil
25%-50% 11/2-2
hours
(AAA) (245 grams)
8 Pigment yellow 12
400 grams
4.5%-6.5%
Whitsol 421
25%-50% 11/2-2
hours
(AAA) (245 grams)
9 Pigment Red 53:1
400 grams
5% Soybean oil
15%-25% 11/2-2
hours
(Red Lake C) (600 grams)
10 Pigment Red 57:1
400 grams
5% Soybean oil
15%-25% 11/2-2
hours
(Lithol Rubine) (600 grams)
11 Pigment Blue 15:3
150 grams
1.5%-3.0%
Soybean oil
15%-30% 11/2-2
hours
(Phthalocyanine blue) (168.75 grams)
12 Pigment Blue 15:3
150 grams
1.5%-3.0%
Soybean oil
5%-15% 11/2-2
hours
(Phthalocyanine blue) (187.5 grams)
__________________________________________________________________________
The above experiments were conducted using a Gifford-Wood Homo Mixer Model
No. IL-69112 and Model No. IL-0957 both at 7500 RPM 1/2 HP available from
Greerco Corp., Hudson, N.H. In each case, the mixer was actuated and the
slurry poured into the agitated vehicle. The Magiesol 47 is a product of
Magie Brothers Oil Company and the Nevchem 140 is a product of Neville
Chemical Company
Top