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United States Patent |
5,087,192
|
Kanome
,   et al.
|
February 11, 1992
|
Roll for forming optical recording medium substrate
Abstract
A forming roll for a substrate used for an optical recording medium
comprises a roll for continuously forming substrates used for optical
recording mediums having preformatting information. Said roll comprises a
roll substrate having on its surface a stamper on which a pattern
corresponding with the preformatting information has been formed, and,
assuming the radius of said roll substrate as "r" mm, the length of said
pattern in the peripheral direction of said roll substrate as "t" mm, they
satisfy the relationship of:
l.times.t.ltoreq.0.1.times.r
(provided that r.gtoreq.l/2.pi.).
Inventors:
|
Kanome; Osamu (Kawasaki, JP);
Sugata; Hiroyuki (Yamato, JP)
|
Assignee:
|
Canon Kabushiki Kaisha (Tokyo, JP)
|
Appl. No.:
|
491291 |
Filed:
|
March 9, 1990 |
Foreign Application Priority Data
Intern'l Class: |
B29C 043/08; B29C 043/46 |
Field of Search: |
425/385,810
264/107,106,284
156/209
|
References Cited
U.S. Patent Documents
1996057 | Apr., 1935 | Buckle | 425/810.
|
2060082 | Nov., 1936 | Johnson et al. | 101/383.
|
2529083 | Nov., 1950 | Keefe | 425/291.
|
3072519 | Jan., 1963 | Salzman | 156/200.
|
3768946 | Oct., 1973 | Matuschke | 425/363.
|
3860473 | Jan., 1975 | Wesen | 156/252.
|
3874836 | Apr., 1975 | Johnson et al. | 425/810.
|
4294782 | Oct., 1981 | Froehlig | 264/1.
|
4836874 | Jun., 1989 | Foster | 156/209.
|
4913858 | Apr., 1990 | Miekka et al. | 264/1.
|
Foreign Patent Documents |
288580 | Oct., 1987 | EP.
| |
2089024 | Jan., 1972 | FR.
| |
Primary Examiner: Hoag; Willard E.
Attorney, Agent or Firm: Fitzpatrick, Cella, Harper & Scinto
Claims
What is claimed is:
1. A forming roll for producing an optical recording medium substrate,
comprising a roll for continuously forming optical recording media
substrates having preformatting information;
wherein said roll comprises a roll substrate having on its surface a
stamper bearing a pattern corresponding with said preformatting
information such the l.times.t.ltoreq.0.1.times.r when r.gtoreq.l/2.pi.
wherein r is the radius of said roll substrate in mm, l is the length of
said pattern along the periphery of said roll substrate in mm and t is the
thickness of said stamper in mm.
2. A forming roll for a substrate used for an optical recording medium
according to claim 1, wherein the length l, of the pattern formed on said
stamper, in the direction perpendicular to the center axis of said roll
substrate ranges from 10 mm to 500 mm.
3. A forming roll for a substrate used for an optical recording medium
according to claim 2, wherein the length l of the pattern formed on said
stamper ranges from 20 mm to 400 mm.
4. A forming roll for a substrate used for an optical recording medium
according to claim 1, wherein the radius "r" of said roll substrate ranges
from 40 mm to 1,000 mm.
5. A forming roll for a substrate used for an optical recording medium
according to claim 4, wherein the radius "r" of said roll substrate ranges
from 50 mm to 500 mm.
6. A forming roll for a substrate used for an optical recording medium
according to claim 1, wherein the thickness "t" of said stamper is not
less than 0.01 mm and not more than 1 mm.
7. A forming roll for a substrate used for an optical recording medium
according to claim 6, wherein the thickness "t" of said stamper is not
less than 0.03 mm and not more than 0.3 mm.
8. A forming roll for a substrate used for an optical recording medium
according to claim 1, wherein said stamper has a pattern corresponding
with an optical disk tracking groove of a spiral form or grooves in the
form of concentric circles.
9. A forming roll for a substrate used for an optical recording medium
according to claim 1, wherein said stamper is fixed on said roll substrate
through an epoxy adhesive.
Description
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a forming roll used for continuously
manufacturing substrates for optical information recording mediums.
2. Related Background Art
Substrates for optical recording mediums have been hitherto prepared by
processes such as the injection process, the 2P process, the casting
process, and the compression process.
In these processes, however, substrates are formed sheet by sheet and hence
a number of apparatus are required in order to prepare the substrates at
high speed and in large quantities, thus making it difficult to prepare
the substrates at a low cost.
On the other hand, processes of continuously preparing substrates used for
optical recording mediums include, for example, a process in which a
thermoplastic resin is made to have temperatures not lower than its
thermal deformation temperature, and which is then extruded, passed
between a pair of forming rolls, and formed into a resin sheet with
uniform thickness, and at the same time, the preformatting information
(e.g., tracking grooves and/or encoded information in the form of readable
marks) on the roll is continuously transferred to the resin sheet. This
process enables high-speed mass production of substrates. As methods of
preparing a forming roll used in such a process, a method is known in
which preformatting information is directly formed on a roll substrate, or
a method in which a thin stamper is stuck on a roll substrate through an
adhesive or the like. Of these methods, the method in which the stamper,
having a preformatting information pattern, is stuck on the roll substrate
can achieve easy production of the substrates for optical recording
mediums. Even when the stamper has been broken, the stamper only may be
replaced with new one, bringing about simplicity in the maintenance of the
substrateforming roll.
In this method, however, the stamper used for forming must be bent after
the shape of the roll surface when it is fixed on the roll, and hence the
pattern on the surface of the stamper used for forming is stretched out,
sometimes resulting in the transfer of a deformed pattern on the surface
of the substrate. In particular, the pattern is stretched in the transport
direction of the resin sheet, resulting in formation of inaccurate
preformatting information on the substrates used for optical recording
mediums. This has brought about the problem of failure of auto tracking
particularly in the case of optical disks rotated at a high speed.
SUMMARY OF THE INVENTION
The present invention was made on account of the above problems, and an
object thereof is to provide a forming roll for a substrate used for an
optical recording medium, which is a roll for continuously forming
substrates used for optical recording mediums having preformatting
information, and has suppressed the deformation of a pattern that
corresponds with the preformatting information put onto a stamper provided
on the surface of a roll substrate.
Another object of the present invention is to provide a forming roll for
forming a substrate used for an optical recording medium, that can always
accurately transfer the preformatting information.
Still another object of the present invention is to provide a process for
preparing an optical recording medium, that enables continuous preparation
of optical recording mediums having accurate preformatting information on
the surfaces of the substrates therefor.
The forming roll for a substrate used for an optical recording medium
according to the present invention is characterized by a roll for
continuously forming substrates used for optical recording mediums having
preformatting information; wherein said roll comprises a roll substrate
having on its surface a stamper on which a pattern corresponding with the
preformatting information has been formed, and, assuming the radius of
said roll substrate as "r" mm, the length of said pattern in the
peripheral direction of said roll substrate as "l" mm, and the thickness
of said stamper as "t" mm, they satisfy the relationship of:
l.times.t.ltoreq.0.1.times.r
(provided that r.gtoreq.l/2.pi.).
The process for preparing an optical recording medium according to the
present invention is also characterized by comprising continuous steps of;
melting a resin and extruding the molten resin to form a resin sheet;
pressing said resin sheet, before it cures, between a substrate-forming
roll and a roll disposed opposingly to said substrate-forming roll, to
transfer preformatting information to said resin sheet; and
forming a recording layer containing an organic coloring matter by coating,
on the surface of said resin sheet on which the preformatting information
has been formed;
said substrate-forming roll comprising a roll substrate having on its
surface a stamper on which a pattern corresponding with the preformatting
information has been formed; and, assuming the radius of said roll
substrate as r mm, the length of said pattern in the peripheral direction
of said roll substrate as l mm, and the thickness of said stamper as t mm,
they satisfying the relationship of:
l.times.t.ltoreq.0.1.times.r
(provided that r.gtoreq.l/2.pi.).
Namely, according to the present invention, the product of the thickness
"t" of the stamper and the length "l" of the transfer pattern is set to be
not more than 0.1 time the radius "r" of the roll substrate. This enables
suppression of the deformation of the pattern on the surface of the
stamper when the stamper is fixed on the surface of the roll substrate.
Thus, optical recording mediums having accurate preformatting information
can be continuously prepared.
BRIEF DESCRIPTION OF THE DRAWINGS
FIGS. 1A and 1B are a diagrammatic perspective view and a diagrammatic
cross section, respectively, of an embodiment of the substrate-forming
roll according to the present invention.
FIG. 2 is a diagrammatic cross section to illustrate an embodiment of an
apparatus for preparing substrates used for optical recording mediums, in
which the substrate-forming roll of the present invention is used.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
The present invention will be described below in detail with reference to
the accompanying drawings.
FIGS. 1A and 1B are a schematic perspective view and a cross section,
respectively, that illustrate an embodiment of the roll for forming a
substrate used for an optical recording medium according to the present
invention (hereinafter "substrate-forming roll"). In FIGS. 1A and 1B, the
substrate-forming roll of the present invention comprises stampers 1a to
1f serving as forming members, provided on the surface of a
mirror-finished roll substrate 2. The letter symbol "r" is the radius of
the roll; "l", the length of a transfer pattern in the direction
perpendicular to the center axis of the roll substrate 2; and "t", the
thickness of the stamper. In the substrate-forming roll of the present
invention, the radius r (mm) of the roll, the length l (mm) of the
transfer pattern on the stamper and the thickness t (mm) of the stamper
may preferably satisfy the condition represented by the following
relationship (I).
l.times.t.ltoreq.0.1.times.r (I)
The numeral 10 denotes a region of a preformatting information pattern
formed on the stamper.
The amount of deformation on the surface of the stamper, i.e., the strain
of the pattern corresponding with the preformatting information formed on
the stamper can be minimized when the roll substrate 2 and stampers 1a to
1f satisfy the condition represented by the above relationship (I). For
example, the stretch of a pattern in the direction perpendicular to the
center axis of the roll substrate 2 can be suppressed to 100 .mu.m or
less. Hence, it is possible to continuously prepare substrates used for
optical recording mediums having accurate preformatting information, and
it is therefore possible to obtain optical recording mediums free from
tracking errors and having high quality.
A hitherto commonly known method can be used as the method of preparing the
stampers 1a to 1f used in the substrate-forming roll of the present
invention. For example, the stamper can be obtained by coating a photo
resist on a mirror-finished glass base, and forming a resist pattern
having the preformatting information (e.g., tracking grooves and/or
encoded information in the form of readable marks) by exposure using a
laser cutting machine and development, followed by sputtering of, for
example, Ni on the surface for the electroconduction treatment, and
thereafter electroforming to increase the thickness of the nickel film to
a given thickness, which nickel film is then subjected to grinding and
shape processing, and subsequently removed from the glass base and
cleaned.
Alternatively, a thin glass sheet is coated with a photo resist, which is
exposed by laser cutting and developed to form a resist pattern, which is
then subjected to dry etching so that a pattern corresponding with the
preformatting information may be directly cut in the glass sheet. This may
be used as the stamper.
The thickness "t" of each stamper 1a to 1f may vary depending on the radius
"r" of the roll substrate used and the length "l" of the transfer pattern,
but may usually be not more than 1 mm, and particularly preferably from
0.03 to 0.3 mm.
In the present invention, the pattern of preformatting information formed
on the stamper refers to, for example, tracking grooves used for optical
disks or optical cards, which grooves may be spiral, concentrically
circular, or parallel, and have a width of from 0.5 .mu.m to 2 .mu.m, a
pitch of 1.0 .mu.m to 5 .mu.m and a depth of from 200 .ANG. to 5,000
.ANG., in approximation. It may also refer to tracking grooves used for
optical disks or optical cards, which grooves may be spiral,
concentrically circular, or parallel, and have a width of from 2 .mu.m to
5 .mu.m, a pitch of 8 .mu.m to 15 .mu.m and a depth of from 200 .ANG. to
5,000 .ANG., in approximation. It may further refer to a pattern
corresponding with encoded information such as address pits.
In the present invention, the length "l" of the pattern on the stamper may
vary depending on the optical recording medium to be prepared and also
depending on the manner by which the stamper is fitted to the roll
substrate 2, but the pattern may usually be formed with a length of from
10 mm to 500 mm, and particularly from 20 mm to 400 mm.
Rolls made of, for example, chromium-plated steel or nickel-plated steel
can be used as the mirror-finished roll substrate 2 on which the stampers
are fitted.
The radius "r" of the roll substrate 2 may vary depending on the length "l"
of the pattern on the stamper, but may usually be from 40 mm to 1,000 mm,
and particularly from 50 mm to 500 mm. The roll substrate is so formed
that the radius "r" is not less than l/2 .pi..
Methods of fitting the stampers to the surface of the mirror-finished roll
substrate include a method in which the former is adhered to the latter
using a heat resistant adhesive, for example, an epoxy adhesive, a
polyimide adhesive and a silicone adhesive. The stampers may also be
adhered using a low-melting metal. They may also be fitted by a mechanical
means such as screw fixing.
Methods of continuously forming the substrates for optical recording
mediums by the use of the substrate-forming roll of the present invention
include, for example, a method comprising the steps of melting a
thermoplastic resin and extruding the molten resin, and pressing the
resin, before it cures, using the substrate-forming roll to effect the
transfer of the preformatting information.
FIG. 2 is a diagrammatic cross section to illustrate an embodiment of a
precess for preparing substrates used for optical recording mediums, in
which the substrate-forming roll of the present invention is used.
In the present invention, resin pellets fed into an extruder 11 are first
heated and melted in a barrel of the extruder 11, pressed forward by a
screw provided inside the extruder, and then formed into a sheet through a
T-die 12. In order to enable accurate transfer of the preformatting
information, the T-die may preferably be so disposed that a resin sheet 6
is extruded to the gap between substrate-forming roll 4 and a
mirror-finished roll 3.
Next, the resin sheet extruded from the T-die is pressed between the
substrate-forming roll 4 and the mirror-finished roll 3, and thus the
preformatting information is transferred. Here, the resin sheet 2 may
preferably be almost in a molten state. This is because the resin can
thereby be sufficiently pressed into the uneven surfaces of the stampers
and hence fine patterns can be accurately transferred. For this reason,
the T-die may preferably be kept heated to a temperature as high as
possible so far as the resin may not burn or scorch, and may preferably be
heated to a glass transition temperature of the resin (hereinafter
"Tg")+110.degree. C. to Tg+200.degree. C., and particularly Tg+130.degree.
C. to Tg+190.degree. C. In the case of polycarbonate resins, for example,
it may preferably be heated to from 260.degree. C. to 340.degree. C.,
particularly from 280.degree. C. to 330.degree. C., and more particularly
from 290.degree. C. to 320.degree. C. In addition, when the resin sheet is
cooled between the T-die and substrate-forming foll, the preformatting
information may not be satisfactorily transferred, tending to cause double
refraction. The distance between the T-die and the point at which the
resin sheet is pressed between the substrate-forming roll 4 and the first
mirror-finished roll 3 may preferably be 20 cm or less, particularly 15 cm
or less, and more particularly 10 cm or less. The surrounding atmosphere
may preferably be kept at a temperature of 60.degree. C. or higher.
The apparatus may also preferably have the constitution of vertical
extrusion as FIG. 2 shows, where the resin sheet is pressed between the
rolls at the point vertically beneath the T-die so that the resin sheet
can be extruded exactly to that point. This is because the vertical
extrusion enables more exact extrusion, than horizontal extrusion, of the
resin sheet to the point it is pressed between the rolls since the resin
is nearly in a molten state.
The substrate-forming roll 4 and mirror-finished rolls 3 and 5 may have
temperatures commonly used in extrusion of resin sheets, i.e.,
temperatures of from 100.degree. C. to 150.degree. C.
The resin sheet serving as the substrate used for the optical recording
medium may have a thickness which may be varied by changing the distance
between the mirror-finished rolls 3 and 5. However, in view of the
advantages that little strain may be produced inside the resin sheet and
the uneven (land-and-groove) preformat on the substrate-forming roll can
be transferred with good performance, the resin sheet may preferably have
a thickness of from 0.2 mm to 2.0 mm, and particularly from 0.4 mm to 1.5
mm. The rolls 3, 4 and 5, determining the thickness of this sheet, are so
set as to be as parallel as possible to each other in order to prevent the
irregularities in sheet thickness that may cause errors in recording and
reproduction. Stated specifically, assuming as .theta. the angle formed by
the axis of each roll, it is preferred that tan .theta. is
5.times.10.sup.-3 or less, and particularly 1.times.10.sup.-3 or less.
The double refraction of the resin sheet brings about a great difficulty
when an energy beam used for the recording and reproduction is made
incident from the substrate side. Hence, the double refraction of the
resin sheet should preferably be controlled to be 50 nm or less,
particularly 30 nm or less, more particularly 20 nm or less, and most
particularly 15 nm or less, per single pass in terms of the wavelength of
light used for the recording and/or reproduction.
Subsequently, a recording layer 7 capable of recording and/or reproducing
information by the action of light is formed on the resin sheet having the
preformatting information obtained in the way as described above.
When the recording layer is formed by coating on the resin sheet, the resin
sheet may preferably have a flatness of 10 mm or less, usually 5 mm or
less, particularly 3 mm or less, and more particularly 1 mm or less.
Incidentally, in order to decrease the double refraction and improve the
flatness, of the resin sheet, the amount of extrusion to form the resin
sheet may preferably be accurately controlled. It is also preferred to
cause no tension to be applied to, and no sag to be produced in, the resin
sheet in the course of the formation of the preformatting information.
This can be achieved by adjusting the rotational speeds of the
substrate-forming roll 4 and the third roll mirror-finished roll 5.
Assuming the rotational speed of the substrate-forming roll as
.omega..sub.4, and the rotational speed of the mirror-finished roll 5 as
.omega..sub.5, the speed ratio .omega..sub.4 /.omega..sub.5 of the
rotational speeds (peripheral speeds) of the rolls may preferably be
1.0<.omega..sub.4 /.omega..sub.5 .ltoreq.1.004, particularly
1.001<.omega..sub.4 /.omega..sub.5 .ltoreq.1.003, and more particularly
1.001<.omega..sub.4 /.omega..sub.5 .ltoreq.1.0025.
When .omega..sub.4 /.omega..sub.5 is 1 or less, a tension is applied to the
resin sheet to cause the double refraction, resulting in unsatisfactory
transfer of the preformatting information. On the other hand, when
.omega..sub.4 /.omega..sub.5 is more than 1.004, the double refraction may
be reduced but the flatness of the resin sheet is lowered and the resin
sheet tends to slip on the substrate-forming roll, resulting in a lowering
of the transfer accuracy of the preformatting information.
As to the delivery speed of the resin sheet, the resin sheet may preferably
be delivered at a speed that may not cause the resin to cure before
formation of the preformatting information and further may not result in
uneven transfer of the preformatting information. On the other hand, in
the course of the coating consecutively carried out to form the recording
layer on the resin sheet, the delivery speed of the resin sheet may
preferably be controlled to a speed that enables formation of the
recording layer with an always uniform thickness. In this regard, stated
specifically as the speed that enables accurate transfer of the
preformatting information and also enables uniform formation of the
recording layer, the delivery speed of the resin sheet may preferably
range from 0.3 m/min to 10 m/min, particularly from 0.5 m/min to 5 m/min,
and more particularly from 1 m/min to 4 m/min.
As coating methods to form the recording layer, methods such as roll
coating, gravure coating, curtain coating, spray coating, dip coating, bar
coating, and blade coating may be used.
The recording layer formed here may preferably have a thickness ranging
from 500 .ANG. to 5000 .ANG.. A drying step to remove a solvent is usually
provided after the coating step for the recording layer. In the present
invention, however, the step of drying the recording layer can be omitted
or simplified if a solution of recording layer materals is applied after
the preformatting information of the resin sheet to which the
preformatting information has been transferred is fixed and before cooled
to room temperature. The whole step can thus be more simplified.
Even in such an instance, however, the recording layer may preferably be
formed by coating after the surface temperature of the resin sheet which
has been extruded and on which the preformatting information has been
formed has become not higher than 50.degree. C., and particularly not
higher than 40.degree. C. This is because there is a possibility of
formation of cracks on the surface of the substrate because of the solvent
in the coating solution for the recording layer.
As resins used as materials for the substrate, thermoplastic resins having
a high transmission to the light used for recording and reproduction are
preferred, including, for example, acrylic resins, polyester resins,
polycarbonate resin, vinyl resins, polysulfone resins, polyolefin resins,
and cellulose resins.
The organic coloring matter used in the recording layer may preferably show
a great difference in reflectance to energy beams of reproducing light,
between the pits, serving as recorded areas, and the unrecorded areas. For
carrying out recording, it may also preferably have a great absorption in
the wavelength region of recording light. It may still also preferably
require a smaller energy necessary for causing changes in reflectance as a
result of irradiation with energy beams. It may further preferably cause
changes in reflectance with difficulty, at the recorded areas (pits, etc.)
and unrecorded areas.
Such a coloring matter includes, for example, anthraquinone derivatives
(particularly those having an indanthrene skeleton), dioxazine compounds
and derivatives thereof, triphenodithiazine compounds, phenanthrene
derivatives, cyanine compounds, merocyanine compounds, pyrylium compounds,
xanthene compounds, triphenylmethane compounds, croconium coloring
matters, azo coloring matters, crocones, azines, indigoids, polymethine
coloring matters, azulenes, squarilium derivatives, sulfur dyes, and metal
dithiolato complexes.
These coloring matters may also be mixed with a stabilizer. Such
stabilizers include various types of metal chelate compounds, in
particular, those comprising a multidentate ligand having a central metal
such as Zn, Cu, Ni, Cr, Co, Mn, Pd or Zr, as exemplified by tetradentate
ligands having N.sub.4, N.sub.2 O.sub.2, N.sub.2 S.sub.2, S.sub.4, O.sub.2
S.sub.2, O.sub.4, etc., or a combination of these, as well as various
types of aromatic amines or diamines, nitrogen-containing aromatics, and
onium salts thereof as exemplified by aminium salts, diimonium salts,
pyridinium salts, imidazolinium salts, and quinolium salts. Pyrylium salts
or the like which are salts of oxygen-containing aromatics may also be
used. These stabilizers can be used in combination of plural ones.
The above various stabilizers are selected taking account of the
compatibility with the above organic coloring matters and solvents used.
The stabilizer may preferably be added in an amount of from 1 wt. % to 50
wt. % based on the organic coloring matter. In particular, when added in
an amount of from 10 wt. % to 30 wt. %, the lowering of sensitivity can be
small and the effect as the stabilizer can be high.
The solvent used in dissolving the above organic coloring matter and
stabilizer may preferably be such one that does not attack the resin
sheet. For example, there can be used diacetone alcohol, cellosolve,
1-methoxy-2-propanol, and mixed solvents composed of any of the above
solvents to which a halogenated solvent has been added in a small amount.
The sheet-like optical recording medium prepared in this way is then cut or
punched out to be formed into individual optical disks or optical cards.
Incidentally, in the present invention, the step of forming a protective
member on the surface at which the recording layer has been formed and the
step of cutting the optical recording medium sheet having the recording
layer and the protective member may be continuously provided subsequent to
the forming of the recording layer. This is particularly effective in view
of the advantages that dust can be almost completely prevented from
invading the optical recording mediums, and more highly reliable optical
recording mediums can be obtained.
As having been described above, in the substrate-forming roll and the
process for preparing the optical recording medium according to the
present invention, the substrate-forming roll used in continuously
producing the substrates for optical recording mediums is formed in such a
manner that relationship between the radius "r" mm of the roll substrate,
the length "l" mm of the transfer pattern of the stamper, and the
thickness "t" mm of the stamper is so set as to be
l.times.t.ltoreq.0.1.times.r. Thus, it has become possible to transfer the
pattern of the stamper used for the forming, free from deformation, to the
substrate with good accuracy. This has also made it possible to decrease a
fraction defective in the forming of substrates, and to manufacture
optical recording mediums free from tracking errors or the like and having
a high quality, at a low cost.
In particular, the present invention can be remarkably effective in
continuously manufacturing such optical disks that are rotated at a high
speed of, for example, from 1,000 rpm to 3,600 rpm, and particularly from
1,800 rpm to 3,600 rpm, at the time of recording and reproduction.
EXAMPLES
The present invention will be described below in greater detail by giving
Examples.
EXAMPLE 1
Optical recording mediums were continuously prepared using a
substrate-forming roll comprising a stamper made of nickel and a roll
substrate made of nickel-plated steel, where the length "l" of a transfer
pattern was 86 mm, the thickness "t" of the stamper was 0.1 mm and the
radius "r" of the roll substrate was 100 mm. The relationship of these is:
l.times.t=86.times.0.1=8.6,
0.1r=0.1.times.100=10.0,
8.6=l.times.t<0.1r=10.0,
satisfying the condition in the equation (I). On the stamper, a pattern
corresponding with a track groove of a spiral form was formed in the
region defined between an inner diameter of 46 mm and an outer diameter of
82 mm. Two sheets of this stamper were stuck on the above roll substrate,
using an epoxy adhesive (trade name: TE-1710; a product of Toray
Industries, Inc.). A substrate-forming roll was thus prepared.
Using the resulting substrate-forming roll, an apparatus for preparing
optical disks, as shown in FIG. 2, was set up.
Polycarbonate (number average molecular weight: 35,000; trade name: Panlite
L-1250; a product of Teijin Chemicals Ltd.) was used as the resin pellet
for forming a substrate material
The temperature of the T-die 12 was set to be 295.degree. C.; the extrusion
width, 200 mm, the diameters and thicknesses of the substrate-forming roll
4 and the mirror-finished rolls 3 and 5, each 300 mm in diameter and 400
mm in length; and the distance between the substrate-forming roll 4 and
mirror-finished roll 3 and the distance between the substrate-forming roll
4 and mirror-finished roll 5, each 1.20 mm. The rotational speeds
.omega..sub.4 and .omega..sub.3 of the substrate-forming roll 4 and
mirror-finished roll 3 were made equal. The ratio .omega..sub.4
/.omega..sub.5 of the rotational speed of the roll 4 (.omega..sub.4) to
the rotational speed of the roll 5 (.omega..sub.5) was set to be 1.004.
The distance between the T-die and the point at which the resin sheet is
pressed between the substrate-forming roll 4 and the mirror-finished roll
3 was set to be 7.5 cm, and the resin sheet was delivered at a speed of 2
m/min.
In this way, a resin sheet to be formed into substrates for optical
recording mediums and to which 100 patterns for optical disks were
transferred was obtained. Next, in respect of the patterns for optical
disks, transferred to the resin sheet, the amount of stretch of the outer
diameter of each track groove in the direction of extrusion was measured
to reveal that it ranged from 34 to 73 .mu.m.
Subsequently, using a diacetone alcohol solution containing 3 wt. % of a
polymethine coloring matter (trade name: IR-820; a product of Nippon
Kayaku Co., Ltd.) as a recording layer coating solution 8, the solution
was applied to the pattern-formed surface of the resin sheet so as to give
a dry coating thickness of 1,000 .ANG.. After the coating thus formed was
dried, the resulting resin sheet was cut into dougnuts of 15 mm in inner
diameter and 86 mm in outer diameter each. One hundred (100) sheets of
optical disks were thus prepared.
On each of the optical disks thus obtained, reproduction was carried out
using an optical disk drive (trade name: 0MS1000 Type 3; manufactured by
Nakamichi K.K.; number of revolutions: 1,800 rpm; wavelength of
reproducing light: 830 nm). As a result, no tracking servo error occurred
at all.
EXAMPLE 2
Optical recording mediums were continuously prepared using a
substrate-forming roll comprising a stamper made of nickel and a roll
substrate made of chromium-plated steel, where the length "l" of a
transfer pattern was 130 mm, the thickness "t" of the stamper was 0.1 mm
and the radius "r" of the roll substrate was 150 mm. The relationship of
these is:
l.times.t=13<15=0.1 r,
satisfying the condition in the equation (I).
A pattern on the stamper corresponded with a track groove of a spiral form
with a pitch of 1.6 .mu.m. The ratio of a land to a groove was 1. The
pattern was formed in the region defined between an inner diameter of 58
mm and an outer diameter of 122 mm. Three sheets of this stamper were
adhered to the surface of a mirror-finished roll substrate of 150 mm in
radius, made of chromium-plated steel, in the same manner as in Example 1.
A substrate-forming roll was thus prepared. Using the resulting
substrate-forming roll, 100 patterns for optical disks were transferred to
the resin sheet in the same manner as in Example 1. In respect of each
optical disk, the amount of stretch of the outer diameter of the track
groove in the direction of extrusion was measured to reveal that it ranged
from 38 to 77 .mu.m.
Subsequently, in the same manner as in Example 1, a recording layer was
formed, 100 sheets of optical recording mediums were thus prepared, and
reproduction was carried out using the optical disk drive. As a result, no
tracking servo error occurred at all.
COMPARATIVE EXAMPLE 1
Example 1 was repeated to prepare optical recording mediums, except that
the thickness of the stamper was set to be t=0.15 mm. The relationship is:
l.times.t=86.times.0.15=12.9,
0.1.times.r=0.1.times.100=10.0,
l.times.t<0.1r,
thus not satisfying the condition in the equation (I).
In respect of 100 patterns for optical disks, transferred to the resin
sheet using the above substrate-forming roll, the amount of stretch of the
outer diameter in the direction of extrusion of the resin sheet was
measured to reveal that it ranged from 100 to 142 .mu.m. Next, on the
optical disks prepared, reproduction was carried out using the optical
disk drive. As a result, tracking servo errors occurred in all the optical
disks.
COMPARATIVE EXAMPLE 2
Example 2 was repeated to prepare a substrateforming roll, except that the
radius "r" of the roll substrate 2 was set to be 100 mm. Using this
substrate-forming roll, Example 2 was further repeated to prepare optical
recording mediums, except that rolls of 200 mm in diameter were used as
the mirror-finished rolls 3 and 5. Here, in respect of the patterns for
optical disks, transferred to the resin sheet, the amount of stretch of
the outer diameter of the pattern was revealed to range from 105 .mu.m to
161 .mu.m. Next, on the optical disks prepared, reproduction was carried
out using the optical disk drive. As a result, tracking errors occurred in
all the optical disks.
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